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The clarification of mechanism of the selectivity and recovery of trivalent cation of new separation materials loaded solvent extraction reagent.

Research Project

Project/Area Number 23550091
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Analytical chemistry
Research InstitutionTokyo Gakugei University

Principal Investigator

KOKUSEN Hisao  東京学芸大学, 教育学部, 教授 (10251571)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsガリウム / インジウム / 新規分離材 / イオン交換 / 溶媒抽出 / Ga3+ / In3+ / 相互分離 / 負二価六座配位子 / 機能性分離材 / Ga / In / 分離能 / 3価陽イオン / 分離機構 / 多座配位子
Research Abstract

The alkyl chain was introduced to the surface of silica gel. The new separation material which is loaded N,N-Bis-(2-hydroxyphenylmethyl)-N,N-bis(2- pyridylmethyl)-1.2-ethanediamine on the surface of silica gel was synthesized. The selectivity of metal ions was improved compared with the solvent extraction method when the Ga3+ and In3+ metal ions were separated from acidic solution using new separation material. The separation material was synthesized using silicate which had different length, and it was researched to the adsorption mechanism of Ga3+ and In3+ ions. As a result, it was understood that the relation is not seen in a pore size and the selectivity. The adsorption of Ga3+ and In3+ have been researched as an applied research. As a result, the adsorption mechanism of Ga3+ and In3+ from aqueous solution was similar to the solvent extraction system using C18g separation material, and different to use C12g separation material.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (22 results)

All 2014 2013 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (18 results) (of which Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Liquid -liquid Extraction of Divalent Transition Metal Ions with a Novel Bis-β-ketoester Extraction Reagent2014

    • Author(s)
      Satoshi Ohmuro, Hiromasa Kishi, Nobutoshi Yoshihara, Hisao Kokusen
    • Journal Title

      Talanta

      Volume: 128巻 Pages: 102-108

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption properties of modified banana fiber to transition metal ions2014

    • Author(s)
      Tetsuto KAJIYAMA , Shohei SAKAI , Jun INOUE and Hisao KOKUSEN
    • Journal Title

      Journal of Ion Exchange

      Volume: 25巻 Pages: 155-159

    • NAID

      130004845681

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Liquid - liquid Extraction of Divalent Transition Metal Ions with a Novel Bis-β-ketoester Extraction Reagent2014

    • Author(s)
      Satoshi Ohmuro, Hiromasa Kishi, Nobutoshi Yoshihara, Hisao Kokusen
    • Journal Title

      Talanta

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] ビスβ-ケトエステル型負 2価4座配位子の金属イオン捕集挙動2013

    • Author(s)
      國仙久雄
    • Organizer
      金沢工業大学生活環境研究会
    • Year and Date
      2013-12-07
    • Related Report
      2013 Final Research Report
  • [Presentation] Hexane-1,6-diyl bis(4,4,4-trifluoro-3-oxobutanoate)を用いた二価遷移金属の抽出機構2013

    • Author(s)
      大室智史,岸寛昌,松本麻衣子,吉原伸敏,國仙久雄
    • Organizer
      第32回溶媒抽出討論会
    • Year and Date
      2013-11-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Diethyl 1,6-hexanediyl dimalonateを用いた金属イオン捕集における二相間分配機構の検討2013

    • Author(s)
      大室智史,岸寛昌,吉原伸敏,國仙久雄
    • Organizer
      日本分析化学会第62年会
    • Year and Date
      2013-09-10
    • Related Report
      2013 Final Research Report
  • [Presentation] β-diketone吸着担持型新規分離材による二価遷移金属イオンの捕集挙動2013

    • Author(s)
      大室智史,岸寛昌,吉原伸敏,國仙久雄
    • Organizer
      第73回分析化学討論会
    • Year and Date
      2013-05-18
    • Related Report
      2013 Final Research Report
  • [Presentation] β-diketone吸着担持型新規分離材による二価遷移金属イオンの捕集挙動2013

    • Author(s)
      大室智史,岸寛昌,吉原伸敏,國仙久雄
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      北海道大学水産学部(北海道函館市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Diethyl 1,6-hexanediyl dimalonateを用いた金属イオン捕集における二相間分配機構の検討2013

    • Author(s)
      大室智史,岸寛昌,吉原伸敏,國仙久雄
    • Organizer
      日本分析化学会第62年会
    • Place of Presentation
      近畿大学(大阪府東大阪市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Hexane-1,6-diyl bis(4,4,4-trifluoro-3-oxobutanoate)を用いた二価遷移金属の抽出機構2013

    • Author(s)
      大室智史,岸寛昌,松本麻衣子,吉原伸敏,國仙久雄
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学(愛知県名古屋市千種区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ビスβ-ケトエステル型負2価4座配位子の金属イオン捕集挙動2013

    • Author(s)
      國仙久雄
    • Organizer
      金沢工業大学生活環境研究会
    • Place of Presentation
      金沢工業大学(石川県野々市市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] H2Clbbpenと2座配位子を用いた希土類金属イオンの溶媒抽出2012

    • Author(s)
      大室智史,和賀井孝,久保埜公二,平山直樹,大島俊一,國仙久雄
    • Organizer
      第31回溶媒抽出討論会
    • Year and Date
      2012-11-16
    • Related Report
      2013 Final Research Report
  • [Presentation] 溶媒抽出試薬をシリカゲルの吸着担持した分離材によるGa 3+およびIn 3+の吸着挙動2012

    • Author(s)
      牧野里美,飯山真充,川野伸一,國仙久雄
    • Organizer
      日本分析化学会第61年会
    • Year and Date
      2012-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] H2salprpi誘導体を吸着担持させた新規分離材による2価遷移金属イオンの吸着挙動2012

    • Author(s)
      大室智史,高瀬周平,飯山真充,川野伸一,久保埜公二,國仙久雄
    • Organizer
      日本分析化学会第61年会
    • Year and Date
      2012-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Investigation of hydrogen peroxide decomposition to improve the understanding of a reaction2012

    • Author(s)
      Erina Yatani, Satoshi Ohmuro, Hisao Kokusen
    • Organizer
      22nd International Conference on Chemistry Education
    • Year and Date
      2012-07-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 表面修飾したシリカゲルに抽出試薬を吸着担持した分離材の錯生成吸着機構2012

    • Author(s)
      大室智史,飯山真充,梶山哲人,國仙久雄
    • Organizer
      第72回分析化学討論会
    • Year and Date
      2012-05-19
    • Related Report
      2013 Final Research Report
  • [Presentation] 溶媒抽出用試薬をシリカゲルに吸着担持した分離材によるGa3+およびIn3+の吸着挙動2012

    • Author(s)
      牧野里美、飯山真充、川野伸一、國仙久雄
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学(石川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 表面修飾したシリカゲルに抽出試薬を吸着担持した分離材の錯生成吸着機構2012

    • Author(s)
      大室智史、飯山真充、梶山哲人、國仙久雄
    • Organizer
      日本分析化学会第72回分析化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県)
    • Related Report
      2012 Research-status Report
  • [Presentation] H2ClbbpenでGaとInイオンを抽出した際の対イオンの効果2011

    • Author(s)
      和賀井孝,飯山真充,梶山哲人,國仙久雄
    • Organizer
      日本イオン交換学会,日本溶媒抽出学会第27回日本イオン交換研究発表会第30回溶媒抽出討論会
    • Year and Date
      2011-11-25
    • Related Report
      2013 Final Research Report
  • [Presentation] H2bbpen誘導体のアルカリ土類金属錯体の構造と選択性2011

    • Author(s)
      和賀井孝,江川祐樹,生尾光,飯山真充,梶山哲人,國仙久雄
    • Organizer
      日本イオン交換学会,日本溶媒抽出学会第27回日本イオン交換研究発表会第30回溶媒抽出討論会
    • Year and Date
      2011-11-25
    • Related Report
      2013 Final Research Report
  • [Presentation] H2ClbbpenでGaとInイオンを抽出した際の対イオンの効果2011

    • Author(s)
      和賀井孝、飯山真充、梶山哲人、國仙久雄
    • Organizer
      第30回日本溶媒抽出討論会
    • Place of Presentation
      シーガイア(宮崎県)
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] 金属イオン捕集材

    • Inventor(s)
      梶山哲人國仙久雄
    • Industrial Property Rights Holder
      地方独立行政法人東京都立産業技術研究センター
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-215877
    • Related Report
      2013 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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