Optimization of photochemical reactions in ionic liquids using structural analyses with synchrotron light
| Project/Area Number |
23550098
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
Ishioka Toshio 九州大学, 総合理工学研究科(研究院), 助教 (60304838)
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| Project Period (FY) |
2011-04-28 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 光増感反応 / 小角X線散乱 / ポルフィリン / イオン液体 / 一重項酸素 |
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| Outline of Final Research Achievements |
This research work is aimed to achieve high performance photosensitized reactions in ionic liquids using the structural analyses with synchrotron radiation. During research activities in five years, various combinations of porphyrins as photosensitizers and ionic liquids were measured with a temperature controlling system. Small-angle X-ray diffraction data showed that disk-like aggregated species were present with rotation diameter of 10 nm and 2 nm thickness when photosensitized reaction rate was higher than other combinations.
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Report
(6 results)
Research Products
(12 results)
