| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Research Abstract |
The purpose of this study is to develop a neurotransmitter response on near-infrared spectroscopy using (.beta.-diketonato) ruthenium complexes. To realize this objective, a naphthylboronic acid-coordinated (.beta.-diketonato)ruthenium complex has been designed and synthesized. This metal complex was evaluated with electrochemistry and electronic spectra. The results revealed that this complex exhibited a near-infrared absorption band and a sugar recognition function in 80% water – 20% acetonitrile solution. Moreover, the dopamine recognition function of the supramolecular chromogenic probe/cyclodextrin complex was evaluated from their UV-Vis or fluorescence spectra in aqueous solution.
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