Development of Highly Electron-poor Phosphine for Highly Active Catalytic Reaction
| Project/Area Number |
23550124
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Iwate University (2012-2013)
Okayama University (2011) |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2011 – 2013
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
|
|---|
| Keywords | ホスフィン配位子 / フッ素 / 電子不足な配位子 / 金属錯体触媒 / 高活性化 / ホスフィン / 配位子 / 高活性触媒 / パラジウム / ロジウム / クロスカップリング / 不斉触媒 / 電子不足配位子 / 触媒活性 / 電子不足 / 1,2-付加反応 / 不斉アリール化 / 不斉配位子 |
|---|
| Research Abstract |
Chiral phosphine ligands have been playing a significant role in both steric and electronic adjustment of transition metal-catalyzed reactions. We developed the novel ligand bearing BFPy groups, which showed highly electron-poor nature surpassing that of C6F5-containing phosphine ligand. The BFPy phosphine ligand accelerated the Rh and Pd-catalyzed reactions including asymmetric catalytic reactions. The catalytic activities exceeded the authentic catalytic reactions.
|
Report
(4 results)
Research Products
(34 results)
