Development of visible light responsive hybrid catalyst and application to energy and molecular transformation
| Project/Area Number |
23550125
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | ビタミンB12 / 酸化チタン / ヒドリド錯体 / 水素発生 / アルケン還元 / 可視光 / ハイブリッド / 界面錯体 / 可視光応答 / 脱塩素化反応 / コバルト錯体 / 可視光応答性 / ゾル-ゲル反応 / 高耐久性 |
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| Research Abstract |
The vitamin B12-TiO2 hybrid catalyst mediated the H2O reduction to form hydrogen under UV light irradiation (1 turnover number per hour). The catalyst also mediated alkene reductions, such as styrene derivatives and alkylacrylates (maximum 100 turnover number per hour), under mild conditions; i.e., room temperature, ordinary pressure, and water or alcohol solvent. We also succeeded in development of visible light responsive vitamin B12-TiO2 hybrid catalytic system using a catechol modified TiO2 which showed surface charge transfer band in the visible region.
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Report
(4 results)
Research Products
(51 results)
