Synthesis of macrocycles using bis(carbonylamino)pyridine unit
| Project/Area Number |
23550140
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Seikei University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
|
| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 大環状化合物 / アミド結合 |
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| Research Abstract |
4-Substituted 2,6-diaminopyridine was prepared, and condensation reaction of this compound with terephthaloyl chloride was studied for the synthesis of macrocycles. When the reaction was carried out in 1,4-dioxane at 50 degree with N-ethyldiisopropylamine as a base, the oligomers with moderate molecular weight were obtained. Separation of the crude products afforded the products with desired molecular weight.
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Report
(4 results)
Research Products
(33 results)
