| Budget Amount *help |
¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
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| Research Abstract |
This study was carried out to develop a metal-free immortal polymerization of epoxide and to synthesize various kinds of functional polymers as its applications. Specific conclusions are as follows;
1) The metal-free immortal polymerization of epoxide was successfully developed by using commercially available tetra-n-butylammonium fluoride as an initiator. 2) Various kinds of functional polymers such as amphiphilic block copolymers, end-functional polymers, and branched polymers were facilely synthesized by this metal-free immortal polymerization.
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