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The development of platinum-coordinated polyoxometalates for molecular-level utilization of platinum

Research Project

Project/Area Number 23550150
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionShizuoka University

Principal Investigator

KATO Chika  静岡大学, 理学(系)研究科(研究院), 准教授 (00360214)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsポリオキソメタレート / 白金(II)錯体 / 合成 / 構造解析 / 可視光応答型触媒 / 水 / 水素 / 白金 / 光触媒 / 可視光 / 酸化チタン / エオシンY / 光触媒反応 / メタノール / 水素発生 / 助触媒 / 単結晶X線構造解析 / 光増感剤
Research Abstract

Platinum and its derivatives, e.g., alloys, oxides, organometallics, and inorganic compounds, have attracted considerable attention due to their efficient physical and chemical properties. Since platinum is an imperative metal for catalysts, electronics, and pharmaceutical compounds, numerous studies on the syntheses, properties, and activities of various platinum compounds have been reported; however, there is still a need for improved properties and activities. In this study, some novel platinum compounds were synthesized by using Keggin-type lacunary polyoxometalates. In addition, the photocatalytic performances of platinum-coordinated polyoxometalates were investigated for hydrogen evolution from water under visible light irradiation in the presence of titanium dioxide or Eosin Y.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (26 results)

All 2014 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (16 results) Remarks (4 results)

  • [Journal Article] Remarkable Influence of Structures around Rhenium(V) Centers Constructed in Polyoxotungstates for Methanol Dehydro- genation under Visible Light Irradiation2014

    • Author(s)
      Chika Nozaki Kato, Ryuta Nakayama, Shota Hattori, Hidekuni Amano, Yuki Makino
    • Journal Title

      British Journal of Applied Science & Technology

      Volume: 4

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and Molecular Structures of Monomeric and Hydrogen-Bonded Dimeric Dawson-Type Tri-Aluminum-Substituted Polyoxotungstates Derived under Acidic and Basic Conditions2014

    • Author(s)
      Chika Nozaki Kato, Toshifumi Kashiwagi, Wataru Unno, Miyuki Nakagawa, Hidemitsu Uno
    • Journal Title

      Inorganic Chemistry

      Volume: 53 Pages: 4824-4832

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable Influence of Structures around Rhenium (V) Centers Constructed in Polyoxotungstates for Methanol Dehydrogenation under Visible Light Irradiation2014

    • Author(s)
      Chika Nozaki Kato, Ryuta Nakayama, Shota Hattori, Hidekuni Amano, Yuki Makino
    • Journal Title

      British Journal of Applied Science & Technology

      Volume: 4 Pages: 2302-2319

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and Molecular Structures of Monomeric and Hydrogen-Bonded Dimeric Dawson-Type Trialuminum-Substituted Polyoxotungstates Derived under Acidic and Basic Conditions2014

    • Author(s)
      Chika Nozaki Kato, Toshifumi Kashiwagi, Wataru Unno, Miyuki Nakagawa, Hidemitsu Uno
    • Journal Title

      Inorganic Chemistry

      Volume: 53 Issue: 10 Pages: 4824-4832

    • DOI

      10.1021/ic402650g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Diplatinum(II)-coordinated Polyoxotungstate : Synthesis, Molecular Structure, and Photocatalytic Performance for Hydrogen Evolution from Water under Visible-light Irradiation2012

    • Author(s)
      Chika Nozaki Kato, Yusuke Morii, Shota Hattori, Ryuta Nakayama, Yuki Makino, Hidemitsu Uno
    • Journal Title

      Dalton Transactions

      Volume: 41 Pages: 10021-10027

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diplatinum(II)-coordinated Polyoxotungstate: Synthesis, Molecular Structure, and Photocatalytic Performance for Hydrogen Evolution from Water under Visible-light Irradiation2012

    • Author(s)
      Chika Nozaki Kato, Yusuke Morii, Shota Hattori, Ryuta Nakayama, Yuki Makino, Hidemitsu Uno
    • Journal Title

      Dalton Transactions

      Volume: 41 Issue: 4 Pages: 10021-10027

    • DOI

      10.1039/c2dt32107f

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] ビピリジル白金(II)種配位ポリオキソメタレートの合成とキャラクタリゼーション2014

    • Author(s)
      伊原悠輝・加藤知香
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2014-03-28
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 白金およびアルミニウムサイトを有するポリオキソメタレートとエオシンYを用いた可視光照射下での水からの水素発生2014

    • Author(s)
      服部祥太・森井裕介・加藤知香
    • Organizer
      第113回触媒討論会
    • Place of Presentation
      ロワジールホテル豊橋(愛知県)
    • Year and Date
      2014-03-26
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 単核および二核レニウム(V)サイトを有するポリオキソメタレートの合成と可視光照射下での光触媒特性2013

    • Author(s)
      中山竜太・服部祥太・天野日出邦・森井裕介・加藤知香
    • Organizer
      第44回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      静岡大学(静岡県)
    • Year and Date
      2013-11-03
    • Related Report
      2013 Final Research Report
  • [Presentation] ケギン型白金(II)種配位ポリオキソメタレートのエオシンY共存下での光触媒特性2013

    • Author(s)
      服部祥太・森井裕介・加藤知香
    • Organizer
      第44回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      静岡大学(静岡県)
    • Year and Date
      2013-11-03
    • Related Report
      2013 Final Research Report
  • [Presentation] ドーソン型アルミニウム三置換ポリオキソメタレートの分子構造に対するpH依存性2013

    • Author(s)
      柏木俊郁・中川美幸・加藤知香
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Year and Date
      2013-11-02
    • Related Report
      2013 Final Research Report
  • [Presentation] ケギン型アルミニウムおよびマグネシウム一置換ポリオキソメタレートの合成と化学的刺激による分子構造変化2013

    • Author(s)
      鵜飼奈美・海野航・柏木俊郁・牧野裕輝・加藤知香
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Year and Date
      2013-11-02
    • Related Report
      2013 Final Research Report
  • [Presentation] ケギン型二核白金(II)種配位ポリオキソメタレート混合酸化チタンを光触媒とした可視光照射下での水からの水素発生2013

    • Author(s)
      森井裕介・服部祥太・中山竜太・加藤知香
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2013-03-26
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] シスプラチンを出発錯体としたドーソン型白金(II)種配位ポリオキソメタレートの合成と溶液中での安定性の検討2012

    • Author(s)
      服部祥太・森井裕介・加藤昌央・加藤知香
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2012-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] ケギン型白金(II)種配位ポリオキソメタレートの分子構造と光触媒特性2012

    • Author(s)
      森井裕介・服部祥太・中山竜太・牧野裕輝・加藤知香
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2012-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] シスプラチンを用いたケギン型二核白金(II)種配位ポリオキソメタレートの合成およびキャラクタリゼーション2011

    • Author(s)
      森井裕介・加藤昌央・加藤知香
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Year and Date
      2011-09-18
    • Related Report
      2013 Final Research Report 2011 Research-status Report
  • [Presentation] 単核および二核レニウム(V)サイトを有するポリオキソメタレートの合成と可視光照射下での光触媒特性

    • Author(s)
      中山竜太・服部祥太・天野日出邦・森井裕介・加藤知香
    • Organizer
      第44回中部化学関係学協会支部連合秋季大会 (浜松)
    • Place of Presentation
      静岡大学(静岡県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ケギン型白金 (II) 種配位ポリオキソメタレートのエオシンY共存下での光触媒特性

    • Author(s)
      服部祥太・森井裕介・加藤知香
    • Organizer
      第44回中部化学関係学協会支部連合秋季大会 (浜松)
    • Place of Presentation
      静岡大学(静岡県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ドーソン型アルミニウム三置換ポリオキソメタレートの分子構造に対するpH依存性

    • Author(s)
      柏木俊郁・中川美幸・加藤知香
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ケギン型アルミニウムおよびマグネシウム一置換ポリオキソメタレートの合成と化学的刺激による分子構造変化

    • Author(s)
      鵜飼奈美・海野航・柏木俊郁・牧野裕輝・加藤知香
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] シスプラチンを出発錯体としたドーソン型白金(II)種配位ポリオキソメタレートの合成と溶液中での安定性の検討

    • Author(s)
      服部祥太・森井裕介・加藤昌央・加藤知香
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Related Report
      2012 Research-status Report
  • [Presentation] ケギン型二核白金(II)種配位ポリオキソメタレートの分子構造と光触媒特性

    • Author(s)
      森井裕介・服部祥太・中山竜太・牧野裕輝・加藤知香
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.ipc.shizuoka.ac.jp/~sckatou/index.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 加藤研究室

    • URL

      http://www.ipc.shizuoka.ac.jp/~sckatou/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 加藤研究室

    • URL

      http://www.ipc.shizuoka.ac.jp/~sckatou/index.html

    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.ipc.shizuoka.ac.jp/~sckatou/index.html

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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