The development of platinum-coordinated polyoxometalates for molecular-level utilization of platinum
| Project/Area Number |
23550150
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Shizuoka University |
|---|
Principal Investigator |
KATO Chika 静岡大学, 理学(系)研究科(研究院), 准教授 (00360214)
|
|---|
| Project Period (FY) |
2011 – 2013
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
|---|
| Keywords | ポリオキソメタレート / 白金(II)錯体 / 合成 / 構造解析 / 可視光応答型触媒 / 水 / 水素 / 白金 / 光触媒 / 可視光 / 酸化チタン / エオシンY / 光触媒反応 / メタノール / 水素発生 / 助触媒 / 単結晶Ｘ線構造解析 / 光増感剤 |
|---|
| Research Abstract |
Platinum and its derivatives, e.g., alloys, oxides, organometallics, and inorganic compounds, have attracted considerable attention due to their efficient physical and chemical properties. Since platinum is an imperative metal for catalysts, electronics, and pharmaceutical compounds, numerous studies on the syntheses, properties, and activities of various platinum compounds have been reported; however, there is still a need for improved properties and activities. In this study, some novel platinum compounds were synthesized by using Keggin-type lacunary polyoxometalates. In addition, the photocatalytic performances of platinum-coordinated polyoxometalates were investigated for hydrogen evolution from water under visible light irradiation in the presence of titanium dioxide or Eosin Y.
|
Report
(4 results)
Research Products
(26 results)
