Formation and characterization of organogels showing a red emission triggered by complexation.

• Project/Area Number: 23550157
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: Kyushu Institute of Technology
• Principal Investigator: TSUGE Akihiko 九州工業大学, 工学(系)研究科(研究院), 教授 (80179986)
• Co-Investigator(Kenkyū-buntansha): KITAMURA Mitsuru 九州工業大学, 大学院工学研究院, 准教授 (10313199)
• Co-Investigator(Renkei-kenkyūsha): MORIGUCHI Tetsuji 九州工業大学, 大学院工学研究院, 助教 (40243985)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000); Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
• Keywords: ゲル / 赤色発光 / ゲル 米国 欧州

Research Abstract

In this research formation of organogels showing a strong red emission triggered by complexation has been done. We have prepared the ligands having the urea units and then complexed these ligands with a europium metal. We have found out that the complexes can form the organogels exhibiting a strong red emission depending solvents used. The ligands having two long alkyl chains show the gelation ability as well as their complexes. Interestingly the ligands having three long alkyl chains show weak gelation ability even after complexation.

Research Products

• [Journal Article] (2013)
  • Author(s): Tsuge, A.; Yakeya, D.; Sakura, K.; Moriguchi, T.; Kaneko, D.; Kanyama, T.; Kawahara, T. Araki, K.
  • Journal Title: Chem. Lett. Volume: 42 Pages: 263-265
  • Peer Reviewed
• [Journal Article] Formation of Luminescent Organogels from the Europium-based Complexes (2013)
  • Author(s): Akihiko Tsuge, Daisuke Yakeya, Katsuhiko Sakura, Tetsuji Moriguchi, Daisaku Kaneko
  • Journal Title: Chem.Lett. Volume: 42 Issue: 3 Pages: 263-265
  • DOI: 10.1246/cl.2013.263
  • NAID: 10031155774
  • Peer Reviewed
• [Journal Article] Organogelators Derived from [3.3]Metacyclophane Skeleton with a Urea Unit (2012)
  • Author(s): Akihiko Tsuge, Ryuichiro Matsushita, Katsuhiko Sakura, Tetsuji Moriguchi, Koji Araki
  • Journal Title: Chem.Lett Volume: 41 Pages: 485-487
  • NAID: 10030619322
  • Peer Reviewed
• [Presentation] クマリン骨格を有するゲル化剤の合成とその発光ゲル化剤としての特性に関する研究 (2014)
  • Author(s): 木登直弥、森口哲次、荒木孝司、柘植顕彦
  • Organizer: 日本化学会第94春季年会
• [Presentation] クマリン骨格を有するゲル化剤の合成とその発光ゲル化剤としての特性に関する研究 (2014)
  • Author(s): 木登直弥，森口哲次、荒木孝司、柘植顕彦
  • Organizer: 日本化学会第９４春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] アミノ酸骨格を有する赤色発光型ユーロピウム錯体のゲル化挙動に関する研究 (2013)
  • Author(s): 池田脩、森口哲次、荒木孝司、柘植顕彦
  • Organizer: 第7回有機π電子シンポジウム
  • Place of Presentation: 高崎
• [Presentation] 赤色発光型ユーロピウム錯体を用いたゲル化剤の開発 (2013)
  • Author(s): 池田脩、森口哲次、荒木孝司、柘植顕彦
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学
• [Presentation] アミノ酸骨格を有する赤色発光型ユーロピウム錯体のゲル化挙動に関する研究 (2013)
  • Author(s): 池田脩、森口哲次、荒木孝司、柘植顕彦
  • Organizer: 第７回有機π電子系シンポジウム
  • Place of Presentation: 高崎ヴューホテル
• [Presentation] 赤色発光型ユーロピウム錯体を用いたゲル化剤の開発 (2013)
  • Author(s): 池田脩、森口哲次、荒木孝司、柘植顕彦
  • Organizer: 日本化学会第９３春季年会
  • Place of Presentation: 立命館大学
• [Presentation] 赤色発行ユーロピウム錯体のゲル化挙動に関する研究
  • Author(s): 焼谷大輔、森口哲次、荒木孝司、柘植顕彦
  • Organizer: 日本化学会第９２春季年会
  • Place of Presentation: 慶応大学