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Formation and characterization of organogels showing a red emission triggered by complexation.

Research Project

Project/Area Number 23550157
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

TSUGE Akihiko  九州工業大学, 工学(系)研究科(研究院), 教授 (80179986)

Co-Investigator(Kenkyū-buntansha) KITAMURA Mitsuru  九州工業大学, 大学院工学研究院, 准教授 (10313199)
Co-Investigator(Renkei-kenkyūsha) MORIGUCHI Tetsuji  九州工業大学, 大学院工学研究院, 助教 (40243985)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsゲル / 赤色発光 / ゲル 米国 欧州
Research Abstract

In this research formation of organogels showing a strong red emission triggered by complexation has been done. We have prepared the ligands having the urea units and then complexed these ligands with a europium metal. We have found out that the complexes can form the organogels exhibiting a strong red emission depending solvents used. The ligands having two long alkyl chains show the gelation ability as well as their complexes. Interestingly the ligands having three long alkyl chains show weak gelation ability even after complexation.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (10 results)

All 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (7 results)

  • [Journal Article]2013

    • Author(s)
      Tsuge, A.; Yakeya, D.; Sakura, K.; Moriguchi, T.; Kaneko, D.; Kanyama, T.; Kawahara, T. Araki, K.
    • Journal Title

      Chem. Lett.

      Volume: 42 Pages: 263-265

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Luminescent Organogels from the Europium-based Complexes2013

    • Author(s)
      Akihiko Tsuge, Daisuke Yakeya, Katsuhiko Sakura, Tetsuji Moriguchi, Daisaku Kaneko
    • Journal Title

      Chem.Lett.

      Volume: 42 Issue: 3 Pages: 263-265

    • DOI

      10.1246/cl.2013.263

    • NAID

      10031155774

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Organogelators Derived from [3.3]Metacyclophane Skeleton with a Urea Unit2012

    • Author(s)
      Akihiko Tsuge, Ryuichiro Matsushita, Katsuhiko Sakura, Tetsuji Moriguchi, Koji Araki
    • Journal Title

      Chem.Lett

      Volume: 41 Pages: 485-487

    • NAID

      10030619322

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] クマリン骨格を有するゲル化剤の合成とその発光ゲル化剤としての特性に関する研究2014

    • Author(s)
      木登直弥、森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第94春季年会
    • Related Report
      2013 Final Research Report
  • [Presentation] クマリン骨格を有するゲル化剤の合成とその発光ゲル化剤としての特性に関する研究2014

    • Author(s)
      木登直弥,森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] アミノ酸骨格を有する赤色発光型ユーロピウム錯体のゲル化挙動に関する研究2013

    • Author(s)
      池田脩、森口哲次、荒木孝司、柘植顕彦
    • Organizer
      第7回有機π電子シンポジウム
    • Place of Presentation
      高崎
    • Related Report
      2013 Final Research Report
  • [Presentation] 赤色発光型ユーロピウム錯体を用いたゲル化剤の開発2013

    • Author(s)
      池田脩、森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2013 Final Research Report
  • [Presentation] アミノ酸骨格を有する赤色発光型ユーロピウム錯体のゲル化挙動に関する研究2013

    • Author(s)
      池田脩、森口哲次、荒木孝司、柘植顕彦
    • Organizer
      第7回有機π電子系シンポジウム
    • Place of Presentation
      高崎ヴューホテル
    • Related Report
      2013 Annual Research Report
  • [Presentation] 赤色発光型ユーロピウム錯体を用いたゲル化剤の開発2013

    • Author(s)
      池田脩、森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 赤色発行ユーロピウム錯体のゲル化挙動に関する研究

    • Author(s)
      焼谷大輔、森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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