| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
|---|
| Research Abstract |
The transparent ionic liquid gels consisting of emissive ionic liquid (PFCP-IL) having pentafuluorocyclophosphazene moiety and poly(methyl methacrylate) (PMMA) or polyvinyl chloride (PVC) were prepared. We found that when the gels were heated and then cooled to room temperature, the intensity of emission from PFCP-IL in them at room temperature was enhanced than that of original one. We call the phenomena "thermally induced emission enhancement". We clarified that the mechanism of thermally induced emission enhancement can be attributed to the aggregation of PFCP-IL in polymer chains. Based on the obtained mechanism, we succeeded in the preparation of four kinds of gels showing the emission enhancement at a heat temperature of 10 cetigrade temperature interval from 90 cetigrade temperature to 120 cetigrade temperature . These gels can be expected to an application as an emission sensor for monitoring heat temperature of materials.
|
