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Development of new photochromic material using regular structural change in the single molecule as materials

Research Project

Project/Area Number 23550169
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionYonago National College of Technology

Principal Investigator

TANIFUJI NAOKI  米子工業高等専門学校, その他部局等, 准教授 (80423549)

Co-Investigator(Kenkyū-buntansha) YOSHIKAWA Hirofumi  名古屋大学, 大学院理学研究科, 助教 (60397453)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsフォトクロミズム / ジアリールエテン / ソルバトクロミズム / チオフェン / 量子収率 / メソポーラスシリカ / 分子機械
Research Abstract

We synthesized novel photochromic molecules whose physical properties are induced by structural changes of diarylethene. This molecule exhibited photochromism due to newly introduced condensed thiohene rings. In addition, we prepared nanocomposite materials between inorganic mesoporous silica and diarylethene. As a result, we found that absorption bands of diarylethene molecules included in mesoporous silica are red-shifted as pore-size of mesoporous silica decreases.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (37 results)

All 2014 2013 2012 2011 Other

All Journal Article (14 results) (of which Peer Reviewed: 12 results) Presentation (15 results) (of which Invited: 1 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (4 results) (of which Overseas: 1 results)

  • [Journal Article] Storage of an electric field for photocurrent generation in ferroelectric-functionalized organic devices2014

    • Author(s)
      L. Hu, S. Dalgleish, M. M. Matsushita, H. Yoshikawa, and K. Awaga
    • Journal Title

      Nat. Commun.

      Volume: 5

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced capacitor effects in polyoxometalate/graphene nanohybrid materials; a synergetic approach to high performance energy storages2014

    • Author(s)
      Keita Kume, Naoya Kawasaki, Heng Wang, Tetsuya Yamada, Hirofumi Yoshikawa and Kunio Awaga
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 11 Pages: 3801-3807

    • DOI

      10.1039/c3ta14569g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機ジスルフィドポリマーの合成とリチウム二次電池用正極活物質としての応用2013

    • Author(s)
      谷藤尚貴
    • Journal Title

      次世代蓄電池の最新技術と性能評価

      Pages: 109-113

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Electric double layers allow for opaque electrodes in high performance organic optoelectronic devices2012

    • Author(s)
      B. Li, S. Dalgleish, Y. Miyoshi, H. Yoshikawa, M. M. Matsushita, and K. Awaga
    • Journal Title

      App. Phys. Lett.

      Volume: 101 Issue: 17 Pages: 173302-173302

    • DOI

      10.1063/1.4762823

    • NAID

      120006795659

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Utilizing Photocurrent Transients for Dithiolene-Based Photodetection : Stepwise Improvements at Communications Relevant Wavelengths2012

    • Author(s)
      S. Dalgleish, M. M. Matsushita, L. Hu, B. Li, H. Yoshikawa, and K. Awaga
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Issue: 30 Pages: 12742-12750

    • DOI

      10.1021/ja304228c

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Highly efficient organic optoelectronic conversion induced by electric double layers in ionic liquids2012

    • Author(s)
      Bo Li, 他6名
    • Journal Title

      Applied Physics Letters

      Volume: 100 Issue: 16 Pages: 163304-163304

    • DOI

      10.1063/1.3697988

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] リチウム二次電池材料を志向した有機ジスルフィドポリマーの合成2012

    • Author(s)
      谷藤尚貴
    • Journal Title

      ケミカルエンジニヤリング

      Volume: 57 Pages: 606-613

    • Related Report
      2012 Research-status Report
  • [Journal Article] In operando XAFS Studies of Polyoxometalate Molecular Cluster Batteries: Polyoxometalates as Electron Sponges2012

    • Author(s)
      H. Wang, S. Hamanaka, Y. Nishimoto, S. Irle, T. Yokoyama, H. Yoshikawa and K. Awaga
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 10 Pages: 4918-4924

    • DOI

      10.1021/ja2117206

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 新規水質浄化材料の探索試験から見出された鳥類卵殻の有機色素吸着特性2011

    • Author(s)
      谷藤尚貴,清水香穂,鐘撞千秋,洞田璃茉,遠藤茉侑,清水章皓
    • Journal Title

      日本高専学会誌

      Volume: 16 Pages: 109-114

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] チオスルホン酸エステルとジスルフィドの無溶媒合成と反応機構2011

    • Author(s)
      谷藤尚貴,寺本絵里子,山本耕平
    • Journal Title

      日本高専学会誌

      Volume: 16 Pages: 105-108

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption Properties of Organic Dye at Bird’s Egg-Shell Responsible for Screening Tests of New Water Purification Materials2011

    • Author(s)
      谷藤尚貴
    • Journal Title

      日本高専学会誌

      Volume: 16 Pages: 109-114

    • NAID

      110008686642

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] No Solvent Synthesis and Reaction Mechanism of Thiosulfionic Acid S-Ester and Disulfides2011

    • Author(s)
      谷藤尚貴
    • Journal Title

      日本高専学会誌

      Volume: 16 Pages: 105-108

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nanohybridization of Polyoxometalate Clusters and Single-Wall Carbon Nanotubes : Applications in Molecular Cluster Batteries2011

    • Author(s)
      河崎直也
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 50 Issue: 15 Pages: 3471-3474

    • DOI

      10.1002/anie.201007264

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] In-situ XAFS studies of Mn12 molecular cluster batteries: super-reduced Mn12 clusters in solid-state electrochemistry2011

    • Author(s)
      Heng Wang
    • Journal Title

      Chem. Asian J.

      Volume: 6 Pages: 1074-1079

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] メソポーラスシリカ粉末のジアリールエテン吸着とその光化学特性2013

    • Author(s)
      萩野大輔,宮川龍馬,谷藤尚貴
    • Organizer
      第19回日本高専学会年会
    • Place of Presentation
      高知高専
    • Year and Date
      2013-08-31
    • Related Report
      2013 Final Research Report
  • [Presentation] メソポーラスシリカ薄膜への機能性有機分子導入2012

    • Author(s)
      成田貴光,清水香穂,谷藤尚貴
    • Organizer
      第2回化学フェスタ
    • Place of Presentation
      東京工業大学
    • Year and Date
      2012-10-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 卵殻膜を活用した光機能性材料の開発2012

    • Author(s)
      谷藤尚貴,清水香穂,渡邉健太
    • Organizer
      廃棄物資源循環学会研究発表会
    • Place of Presentation
      仙台国際センター
    • Related Report
      2012 Research-status Report
  • [Presentation] メソポーラスシリカ薄膜への機能性有機分子導入2012

    • Author(s)
      成田貴光・清水香穂・谷藤尚貴
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 卵殻膜を活用した光機能性材料開発2012

    • Author(s)
      谷藤尚貴
    • Organizer
      資源の循環利用を考えるシンポジウム
    • Place of Presentation
      とりぎん文化会館
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] トリエチルシリルエチル基を保護基に用いたジスルフィド化合物の合成と応用2011

    • Author(s)
      原聡,村尾彰郁,山本耕平,谷藤尚貴
    • Organizer
      第17回日本高専学会年会
    • Place of Presentation
      鈴鹿高専
    • Year and Date
      2011-08-27
    • Related Report
      2013 Final Research Report
  • [Presentation] 一分子中の混成軌道を光スイッチングとして材料化する試み2011

    • Author(s)
      清水香穂,清水章皓,岸本麻穂,谷藤尚貴
    • Organizer
      第17回日本高専学会年会
    • Place of Presentation
      鈴鹿高専
    • Year and Date
      2011-08-27
    • Related Report
      2013 Final Research Report
  • [Presentation] チオスルホン酸エステルと機能性ジスルフィド材料の無溶媒合成2011

    • Author(s)
      山本耕平
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 1,4-求核付加を用いた1,3-O,S 構造を有するジスルフィド誘導体の合成2011

    • Author(s)
      岸本麻穂
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 一分子中の混成軌道を光スイッチングとして材料化する試み2011

    • Author(s)
      清水香穂
    • Organizer
      日本高専学会第17回年会
    • Place of Presentation
      鈴鹿高専
    • Related Report
      2011 Research-status Report
  • [Presentation] 無溶媒条件を用いたジスルフィド,チオスルホン酸エステルの合成と機能性材料への応用2011

    • Author(s)
      谷藤尚貴
    • Organizer
      第38回有機典型元素化学討論会
    • Place of Presentation
      石川県立音楽堂邦楽ホール
    • Related Report
      2011 Research-status Report
  • [Presentation] 卵殻膜の機能を活用した燃料電池の開発

    • Author(s)
      谷藤尚貴
    • Organizer
      農芸化学会2014年次大会
    • Place of Presentation
      明治大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] メソポーラスシリカ粉末のジアリールエテン吸着とその光化学特性

    • Author(s)
      萩野大輔
    • Organizer
      日本高専学会第19回年会
    • Place of Presentation
      高知高専
    • Related Report
      2013 Annual Research Report
  • [Presentation] メソ多孔質粉体細孔内におけるフォトクロミック分子の光反応挙動

    • Author(s)
      萩野大輔
    • Organizer
      第19回高専シンポジウム
    • Place of Presentation
      久留米高専
    • Related Report
      2013 Annual Research Report
  • [Presentation] メソ多孔質粉体細孔内におけるフォトクロミック分子の光反応挙動

    • Author(s)
      萩野大輔
    • Organizer
      第3回サイエンス・インカレ
    • Place of Presentation
      幕張メッセ
    • Related Report
      2013 Annual Research Report
  • [Book] 次世代蓄電池の【最新】材料技術と性能評価2013

    • Author(s)
      谷藤尚貴, 他
    • Publisher
      技術情報協会
    • Related Report
      2013 Final Research Report
  • [Book] フォトクロミズムの新展開と光メカニカル機能材料2011

    • Author(s)
      谷藤尚貴, 他
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Final Research Report
  • [Book] フォトクロミズムの新展開(分担執筆)2011

    • Author(s)
      谷藤 尚貴
    • Total Pages
      337
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.yonago-k.ac.jp/material/staff/tanifuji/index.html

    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 卵殻膜を用いた褐変又は色素沈着抑制方法、卵殻膜を用いた褐変又は色素沈着抑制剤、色素が吸着した卵殻膜、及び色素が吸着した卵殻膜粉末2013

    • Inventor(s)
      谷藤尚貴
    • Industrial Property Rights Holder
      国立高専機構
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-226494
    • Filing Date
      2013-10-31
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] フォトクロミック分子担持体、およびその製造方法2011

    • Inventor(s)
      谷藤尚貴
    • Industrial Property Rights Holder
      (独)国立高等専門学校機構
    • Industrial Property Rights Type
      特許
    • Patent Publication Number
      2012-229295
    • Filing Date
      2011-04-25
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] フォトクロミック分子担持体, およびその製造方法2011

    • Inventor(s)
      谷藤尚貴
    • Industrial Property Rights Holder
      谷藤尚貴
    • Industrial Property Number
      2011-096831
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] ジスルフィドポリマーの製造方法及びジスルフィドコポリマー2011

    • Inventor(s)
      谷藤尚貴
    • Industrial Property Rights Holder
      谷藤尚貴
    • Industrial Property Number
      2011-098185
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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