Chemical transformations promoted by carbon-based nanocavity materials
| Project/Area Number |
23550178
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 物質変換触媒 / ナノカーボン / ホスト材料 / 機能性触媒 |
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| Research Abstract |
This research aims to develop novel chemical transformations promoted by carbon-based nano cavity materials which are prepared by multiple cage scission -reactions of [60]fullerene. We have focused on (1) activations and chemical transformations of the trapped molecules inside nano cavities and (2) chemical transformations based on the unusual reactivity characteristic of nano cavity materials, especially around the opening moieties (orifices). In respect to the latter, oxidative dimerization reactions of benzylamines proceed in the presence of catalytic amount of a cavity material and the corresponding imines are obtained in good yields.
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Report
(4 results)
Research Products
(4 results)
