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Synthesis and Properties of Novel Cleavable Surfactants Usable in Seawater

Research Project

Project/Area Number 23550184
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental chemistry
Research InstitutionOsaka Municipal Technical Research Institute

Principal Investigator

ONO DAISUKE  地方独立行政法人大阪市立工業研究所, 生物・生活材料研究部, 研究室長 (30416317)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords両親媒性化合物 / 界面活性剤 / 化学分解性 / ジオキソラン / 二疎水基型 / 海水 / 非イオン / 糖 / 二疎水鎖型
Research Abstract

The marine pollution with the oil spill becomes the big environmental problem. The development of the oil spill treatment agent with good biodegradability has become desired. We have been investigating the preparation and properties of cleavable surfactants which are designed to decompose into non-surface active species under mild conditions. We have mentioned that the cleavable moiety (noncyclic acetal group, 1,3-dioxolane ring or ester) had a positive effect on the various surface-active properties. In this work, double-chain cleavable nonionic surfactants bearing a 1,3-dioxolane ring or ester were prepared from diethyl tartrate. A sucrose was used as hydrophilic group. We clarified that they have good surface-active properties in seawater, and the decomposition function in acid water. The biodegradabilities of these cleavable surfactants after 28 days were more than 60 % by an oxygen consumption method with activated sludge. We evaluated the biodegradation of heavy oil.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (18 results)

All 2013 2012 2011 Other

All Presentation (15 results) Remarks (3 results)

  • [Presentation] 糖を親水基とした化学分解性界面活性剤の合成と物性2013

    • Author(s)
      小野大助、西田祐子、川野真太郎、佐藤博文、靜間基博、益山新樹
    • Organizer
      第52回日本油化学会年会
    • Year and Date
      2013-09-04
    • Related Report
      2013 Final Research Report
  • [Presentation] 固相単体を用いたエチレンオキシド鎖を親水部に有するノニオン界面活性剤の鎖長制御合成2013

    • Author(s)
      稲本正、小野大助、靜間基博、川野真太郎、川崎英也、荒川隆一、佐藤博文
    • Organizer
      第52回日本油化学会年会
    • Year and Date
      2013-09-04
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis and Properties of Novel Chemocleavable Surfactants Bearing a Sucrose Derived from Diethyl Tartrate2013

    • Author(s)
      Daisuke Ono, Yuko Nishida, Hirofumi Sato, Motohiro Shizuma, Araki Masuyama
    • Organizer
      104th AOCS Annual Meeting & Expo
    • Year and Date
      2013-04-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 単一のエチレンオキシド鎖長を有する界面活性剤の合成と物性評価2013

    • Author(s)
      稲本正、佐藤博文、靜間基博、小野大助、川崎英也、荒川隆一
    • Organizer
      日本化学会第93春期年会
    • Year and Date
      2013-03-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 鎖長制御されたEO鎖を有する界面活性剤の物性2012

    • Author(s)
      稲本正、小野大助、靜間基博、川崎英也、荒川隆一、佐藤博文
    • Organizer
      日本油化学会フレッシュマンサミット
    • Place of Presentation
      OSAKA
    • Year and Date
      2012-11-11
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis and Properties of Chemocleavable Nonionic Surfactants Derived from Diethyl Tartrate2012

    • Author(s)
      D. Ono, T. Nakagawa, H. Sato, M. Shizuma, A. Masuyama
    • Organizer
      World Congress on Oleo Science and 29th ISF Congress-JOCS/AOCS/KOCS/ISF Joint Meeting
    • Year and Date
      2012-10-02
    • Related Report
      2013 Final Research Report
  • [Presentation] ラクトビオン酸由来新規界面活性剤の合成と機能2011

    • Author(s)
      上野龍馬、小林正治、益山新樹、小野大助
    • Organizer
      日本油化学会フレッシュマンサミット
    • Place of Presentation
      OSAKA
    • Year and Date
      2011-11-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis and Properties of Novel Chemocleavable Surfactants Bearing a Sucrose Derived from Diethyl Tartrate

    • Author(s)
      小野大助、西田祐子、佐藤博文、靜間基博、益山新樹
    • Organizer
      104th AOCS Annual Meeting & Expo
    • Place of Presentation
      Palais des Congres de Montreal(カナダ、モントリオール)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 糖を親水基とした化学分解性界面活性剤の合成と物性

    • Author(s)
      小野大助、西田祐子、川野真太郎、佐藤博文、靜間基博、益山新樹
    • Organizer
      第 52 回日本油化学会年会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Properties of Chemocleavable Nonionic Surfactants Derived from Diethyl Tartrate

    • Author(s)
      D. Ono, T. Nakagawa, H. Sato, M. Shizuma, A. Masuyama
    • Organizer
      日本油化学会、アメリカ油化学会、韓国油化学会
    • Place of Presentation
      アルカス佐世保(長崎県佐世保市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Identification of Biodegradation Products of High-Molecular-Weight Perfluorinated Compounds Using Two-Dimensional Liquid Chromatography/High-Resolution Mass Spectrometry

    • Author(s)
      A. Yamamoto, H. Hisatomi, D. Ono, S. Takemine, M. Kitagawa, H. Kawasaki, R. Arakawa
    • Organizer
      International Mass Spectrometry Foundation
    • Place of Presentation
      京都国際会議場(京都市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Identification of Biodegradation Products of Highly Fluorinated Products Using (Two-Dimensional) Liquid Chromatograph coupled with High-Resolution Mass Spectrometer

    • Author(s)
      Yamamoto A, Hisatomi H, Ono D, Kitagawa M, Kawasaki H, Arakawa R
    • Organizer
      Dioxin20xx (International Dioxin Symposium)
    • Place of Presentation
      Cairns Convention Centre (Australia)
    • Related Report
      2012 Research-status Report
  • [Presentation] 単一のエチレンオキシド鎖長を有する界面活性剤の合成と物性評価

    • Author(s)
      稲本 正、佐藤 博文、靜間 基博、小野大助、川崎 英也、荒川 隆一
    • Organizer
      日本化学会
    • Place of Presentation
      立命館大学(滋賀県草津市)
    • Related Report
      2012 Research-status Report
  • [Presentation] ラクトビオン酸由来新規界面活性剤の合成と機能

    • Author(s)
      上野龍馬、小林正治、益山新樹、小野大助
    • Organizer
      日本油化学会フレッシュマンサミットOSAKA
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 化学分解機能を付与した両親媒性化合物の創製

    • Author(s)
      小野大助
    • Organizer
      化粧品技術フォーラム
    • Place of Presentation
      東京ビックサイト
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.omtri.or.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] 研究室紹介

    • URL

      http://www.omtri.or.jp/

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://w3o.omtri.city.osaka.jp/

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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