Preparation of conducting nanowires with chiral chains

• Project/Area Number: 23550203
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Functional materials/Devices
• Research Institution: Tokyo University of Agriculture and Technology (2013); Yamagata University (2011-2012)
• Principal Investigator: TATEWAKI Yoko 東京農工大学, 工学(系)研究科(研究院), 講師 (30435763)
• Co-Investigator(Kenkyū-buntansha): OKADA Shuji 山形大学, 大学院理工学研究科, 教授 (30250848)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2011: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
• Keywords: 有機電子材料・素子 / ナノコイル / 分子性導体 / 分子集合体 / 有機導電体 / 電気物性 / 有機材料合成 / ナノワイヤ / 物性化学

Research Abstract

We synthesized a new diacetylene monomer with urethane groups in the middle of the substituents and tetrathiafulvalene (TTF) moieties at the end (AT). AT was found to form the CT complex with tetrafluorotetracyanoquinodimethane (F4TCNQ) to be (AT)(F4TCNQ). AT could be polymerized in the solid state to give irregular conjugated structure by UV irradiation although the solid-state polymerization of the CT complex was not confirmed. Morphology of their cast films was observed by AFM. (AT)(F4TCNQ)2 complexes formed the one dimensional structures on mica substrates. The nanowires of (AT)(F4TCNQ) before and after UV irradiation showed semiconducting temperature dependence, and the electrical conductivities at room temperature were found to be more than 10-5 Scm-1.

Research Products

• [Journal Article] Preparation and Physical Properties of Nanoaggregates Composed of Charge-Transfer Complexes Containing Butadiyne Derivatives with Tetrathiafulvalene Moieties (2014)
  • Author(s): M. Imai, Y. Tatewaki, and S. Okada
  • Journal Title: Jpn. J. Appl. Phys. Volume: 53 Issue: 5S1 Pages: 05FA02-05FA02
  • DOI: 10.7567/jjap.53.05fa02
  • NAID: 210000143770
  • Peer Reviewed / Open Access
• [Journal Article] Synthesis and Nanostructures of Several Tetrathiafulvalene Derivatives Having the Side Chains Composed of Chiral and Hydrogen-Bonding Groups and Their Charge-Transfer Complexes (2013)
  • Author(s): Y. Tatewaki, T. Watanabe, K. Watanabe, K. Kikuchi and S. Okada
  • Journal Title: Dalton Trans. Volume: 42 Issue: 45 Pages: 16121-16127
  • DOI: 10.1039/c3dt51464a
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of Monomers with Conjugated Diyne-Triene-Diyne Structure (2013)
  • Author(s): K. Higuchi, K. Sasamura, K. Mizuguchi, Y. Tatewaki, and S. Okada
  • Journal Title: Polymer Volume: 54 Issue: 12 Pages: 2901-2906
  • DOI: 10.1016/j.polymer.2013.04.018
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of L-Alanine Derivatives with a (1-Pyrenyl)butadiynyl Group (2013)
  • Author(s): Y. Tatewaki, A. Sato, S. Ito, S. Inayama and S. Okada
  • Journal Title: Mol. Cryst. Liq. Cryst. Volume: 580 Issue: 1 Pages: 58-63
  • DOI: 10.1080/15421406.2013.804382
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of 4-(Dimethylamino)phenylbutadiyne Derivatives and Their Charge-Transfer Complexes (2013)
  • Author(s): S. Ishii, S. Kaneko, Y. Tatewaki, and S. Okada
  • Journal Title: Mol. Cryst. Liq. Cryst. Volume: 580 Issue: 1 Pages: 64-68
  • DOI: 10.1080/15421406.2013.804753
  • Peer Reviewed
• [Journal Article] Quick and selective synthesis of Li6[α-P2W18O62]・28H2O soluble in various organic solvents (2013)
  • Author(s): Kato C, Nishihara S, Tsunashima R, Tatewaki Y, Okada S, Ren XM, Inoue K, Long DL, Cronin L
  • Journal Title: Dalton Transactions Volume: 42 Issue: 32 Pages: 11363-11366
  • DOI: 10.1039/c3dt51120k
  • Peer Reviewed
• [Journal Article] Thermal solid-state polymerization of a divalent metal salt of an unsaturated carboxylic acid and and the effects of additives (2013)
  • Author(s): J. Tsuchida, Y. Saito, S. Sato, U. Yuki, S. Inayama, Y. Tatewaki, *S. Okada, A. Shindo, C. Mikura, K. Fushihara, M. Yamada
  • Journal Title: Polymer Journal Volume: 45 Issue: 10 Pages: 1007-1012
  • DOI: 10.1038/pj.2013.22
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of L-Alanine Derivatives with a (1-Pyrenyl)butadiynyl Group (2013)
  • Author(s): Y. Tatewaki, A. Sato, S. Ito, S. Inayama, S. Okada
  • Journal Title: Mol. Cry. Liq. Cry Volume: -
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of 4- (Dimethylamino)phenylbutadiyne Derivatives and Their Charge-Transfer Complexes (2013)
  • Author(s): S. Ishii, S. Kaneko, Y. Tatewaki, S. Okada
  • Journal Title: Mol. Cry. Liq. Cry Volume: -
  • Peer Reviewed
• [Journal Article] 自己組織化による有機導電体を用いたナノワイヤの開発 (2013)
  • Author(s): 帯刀陽子、岡田修司
  • Journal Title: 表面 Volume: -
  • NAID: 40019604112
• [Journal Article] Synthesis and solid-state polymerization of butadiyne derivatives with trialkoxyphenylurethane groups (2012)
  • Author(s): R. Takahashi, T. Nunokawa, T. Shibuya, R. Tomita, Y. Tatewaki, S. Okada, T. Kimura, S. Shimada, H. Matsuda
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 85(2） Issue: 2 Pages: 236-244
  • DOI: 10.1246/bcsj.20110219
  • NAID: 130004153023
  • Peer Reviewed
• [Journal Article] Synthesis of Polydiacetylenes with Pyridyl Groups Directly Bound to the Main Chain (2012)
  • Author(s): T. Shibuya, Y. Tatewaki, S. Okada
  • Journal Title: Mol. Cry. Liq. Cry. Volume: 568 Issue: 1 Pages: 93-97
  • DOI: 10.1080/15421406.2012.710191
  • Peer Reviewed
• [Journal Article] Synthesis and Solid-State Polymerization of Diacetylene with TetrathiafuIvalene and the Electronic Properties (2012)
  • Author(s): Y. Tatewaki, S. Inayama, K. Watanabe, H. Shibata and S. Okada
  • Journal Title: Mol. Cry. Liq. Cry. Volume: 568 Issue: 1 Pages: 87-92
  • DOI: 10.1080/15421406.2012.710190
  • Peer Reviewed
• [Journal Article] Fixation of Surface-Modified Polydiacetylene Nano/Microcrystals on Substrates (2011)
  • Author(s): T.Kinemuchi, Y.Moritani, Y.Tatewaki, S.Okada
  • Journal Title: Jpn.J.Appl.Phys Volume: 50 Issue: 9R Pages: 095202-095202
  • DOI: 10.1143/jjap.50.095202
  • NAID: 40019010399
  • Peer Reviewed
• [Journal Article] Radical-Initiator-Induced Solid-State Polymerization of Butadiyne Nanocrystals inWater and Their Dispersion Stabilization (2011)
  • Author(s): S.Kato, T.Kinemuchi, Y.Tatewaki, S.Okada, A.Masuhara, H.Kasai, H.Oikawa
  • Journal Title: J.Nanosci.Nanotechnol Volume: 11 Issue: 4 Pages: 3340-3344
  • DOI: 10.1166/jnn.2011.4165
  • Peer Reviewed
• [Presentation] EOポリマー化を目指したピロリン骨格アクセプターを有する色素の合成と性質 (2013)
  • Author(s): 稲田駿介,佐藤迪吉,帯刀陽子,岡田修司
  • Organizer: 2013高分子学会東北支部研究発表会
  • Place of Presentation: 仙台
• [Presentation] ピロリン骨格アクセプターを持つ非線形光学色素の構造と性質 (2013)
  • Author(s): 稲田駿介,佐藤迪吉,片桐洋史,帯刀陽子,岡田修司
  • Organizer: 第22回有機結晶シンポジウム
  • Place of Presentation: 札幌
• [Presentation] Synthesis and Solid-State Polymerization of Conjugated Compounds with Two Oligoyne Structures (2013)
  • Author(s): K. Sasamura, Y. Tatewaki, and S. Okada
  • Organizer: International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
  • Place of Presentation: Sendai
• [Presentation] Synthesis of Polydiacetylenes with 1-Pyrenyl Groups and Their Optical and Electric Properties (2013)
  • Author(s): S. Ito, Y. Tatewaki, and S. Okada
  • Organizer: International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
  • Place of Presentation: Sendai
• [Presentation] Synthesis and Electrical Properties of Tetrathiafulvalen Derivatives with Ferrocene-Terminated Side Chains (2013)
  • Author(s): K. Mizuguchi, Y. Tatewaki, and S. Okada
  • Organizer: International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
  • Place of Presentation: Sendai
• [Presentation] Synthesis and Physical Properties of Several Tetrathiafulvalene Derivatives with Side Chains Composed of Chiral and Hydrogen-Bonding Substituents (2013)
  • Author(s): M. Kikuchi, K. Mizuguchi, T. Watanabe, K. Watanabe, Y. Tatewaki, and S. Okada
  • Organizer: International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
  • Place of Presentation: Sendai
• [Presentation] Preparation and Physical Property of Nanocrystals Composed of CT Complexes Containing Butadiyne Derivatives with TTF Moieties (2013)
  • Author(s): M. Imai, Y. Tatewaki, and S. Okada
  • Organizer: 2013 JSAP-MRS Joint Symposia included in the 2013 JSPS Autumn Meeting
  • Place of Presentation: Kyotanabe
• [Presentation] キラル部位を有する(1-ピレニル)ブタジイン誘導体の合成とナノ構造体の作製 (2013)
  • Author(s): 佐藤昭礼,帯刀陽子,岡田修司
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢
• [Presentation] Some Approaches to Prepare Polar Orders in Polymeric Materials (2013)
  • Author(s): S. Okada, T. Matsuura, Y. Sato, S. Inada, T. Wada, and Y. Tatewaki
  • Organizer: 13th International Symposium on Advanced Organic Photonics (ISAOP-13)
  • Place of Presentation: Kingston, Canada
• [Presentation] Preparation and Electrical Poling of Several Organic Polar Species (2013)
  • Author(s): S. Okada, T. Wada, T. Matsuura, M. Suzuki, T. Ikeda, and Y. Tatewaki
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics (KJF 2013)
  • Place of Presentation: Busan, Korea
• [Presentation] Synthesis and Properties of Chromophores with a Pyrroline-Type Acceptor for Electro-Optic Polymers (2013)
  • Author(s): Y. Sato, S. Inada, T. Araki, Y. Tatewaki, and S. Okada
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics (KJF 2013)
  • Place of Presentation: Busan, Korea
• [Presentation] Nanostructures and Electrical Properties of Charge Transfer Complexes Composed of Several Derivatives having Tetrathiafulvalene and Pyrene Moieties with TCNQ (2013)
  • Author(s): Y. Tatewaki, A. Sato, and S. Okada
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics (KJF 2013)
  • Place of Presentation: Busan, Korea
• [Presentation] ポリジアセチレン-電荷移動錯体ハイブリッドの合成の試み (2013)
  • Author(s): 岡田修司,帯刀陽子
  • Organizer: 附置研究所間アライアンス「次世代エレクトロニクス」グループ(G1)分科会山形大学ジョイントシンポジウム
  • Place of Presentation: 米沢
• [Presentation] (1-ピレニル)ブタジイン誘導体のナノ構造体の作製 (2013)
  • Author(s): 佐藤昭礼,帯刀陽子,岡田修司
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都
• [Presentation] ピロリン骨格アクセプターを有する非線形光学色素の合成とそのポリマー分散薄膜の作製 (2013)
  • Author(s): 稲田俊介,佐藤迪吉,帯刀陽子,岡田修司
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都
• [Presentation] 重合性官能基を導入したピロリン骨格アクセプターを持つ非線形光学色素の合成と重合 (2013)
  • Author(s): 佐藤迪吉,稲田俊介,帯刀陽子,岡田修司
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都
• [Presentation] TTFを置換したブタジイン誘導体ナノ結晶の固相重合と構造評価 (2013)
  • Author(s): 今井将人,帯刀陽子,岡田修司
  • Organizer: 第60回応用物理学会春季学術講演会
  • Place of Presentation: 厚木
• [Presentation] 有機非線形光学材料の研究の歩み―テラヘルツ波応用まで (2013)
  • Author(s): 岡田 修司
  • Organizer: 第27回ポリマー光回路(POC)研究会
  • Place of Presentation: 仙台、東北大学
• [Presentation] Synthesis of Polydiacetylenes with 1-Pyrenyl Groups and Their Optical and Electric Properties (2013)
  • Author(s): S. Ito, Y. Tatewaki, and S. Okada
  • Organizer: International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
  • Place of Presentation: Sendai, Tohoku Univ.
• [Presentation] Synthesis and Electrical Properties of Tetrathiafulvalen Derivatives with Ferrocene-Terminated Side Chains (2013)
  • Author(s): K. Mizuguchi, Y. Tatewaki, and S. Okada
  • Organizer: International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
  • Place of Presentation: Sendai,Tohoku Univ.
• [Presentation] Synthesis and Physical Properties of Several Tetrathiafulvalene Derivatives with Side Chains Composed of Chiral and Hydrogen-Bonding Substituents (2013)
  • Author(s): M. Kikuchi, K. Mizuguchi, T. Watanabe, K. Watanabe, Y. Tatewaki, and S. Okada
  • Organizer: International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
  • Place of Presentation: Sendai,Tohoku Univ.
• [Presentation] Preparation and Physical Property of Nanocrystals Composed of CT Complexes Containing Butadiyne Derivatives with TTF Moieties (2013)
  • Author(s): M. Imai, Y. Tatewaki, and S. Okada
  • Organizer: 2013 JSAP-MRS Joint Symposia included in the 2013 JSPS Autumn Meeting
  • Place of Presentation: Kyotanabe,Doushisha Univ.
• [Presentation] キラル部位を有する(1-ピレニル)ブタジイン誘導体の合成とナノ構造体の作製 (2013)
  • Author(s): 佐藤 昭礼, 帯刀 陽子, 岡田 修司
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢,金沢大学
• [Presentation] Some Approaches to Prepare Polar Orders in Polymeric Materials (2013)
  • Author(s): S. Okada, T. Matsuura, Y. Sato, S. Inada, T. Wada, and Y. Tatewaki
  • Organizer: 13th International Symposium on Advanced Organic Photonics (ISAOP-13)
  • Place of Presentation: Kingston, Canada,Queen's Univ.
• [Presentation] Preparation and Electrical Poling of Several Organic Polar Species (2013)
  • Author(s): S. Okada, T. Wada, T. Matsuura, M. Suzuki, T. Ikeda, and Y. Tatewaki
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics (KJF 2013)
  • Place of Presentation: Busan, Korea,Korea Univ.
• [Presentation] Nanostructures and Electrical Properties of Charge Transfer Complexes Composed of Several Derivatives having Tetrathiafulvalene and Pyrene Moieties with TCNQ (2013)
  • Author(s): Y. Tatewaki, A. Sato, and S. Okada
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics (KJF 2013)
  • Place of Presentation: Busan, Korea,Korea Univ.
• [Presentation] ポリジアセチレン-電荷移動錯体ハイブリッドの合成の試み (2013)
  • Author(s): 岡田 修司, 帯刀 陽子
  • Organizer: 附置研究所間アライアンス「次世代エレクトロニクス」グループ(G1)分科会山形大学ジョイントシンポジウム
  • Place of Presentation: 米沢,山形大学
• [Presentation] (1-ピレニル)ブタジイン誘導体のナノ構造体の作製 (2013)
  • Author(s): 佐藤 昭礼, 帯刀 陽子, 岡田 修司
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都,京都国際会館
• [Presentation] アラニン部位を有する(1-ピレニル)ブタジイン誘導体の合成と構造・物性評価 (2012)
  • Author(s): 佐藤 昭礼, 帯刀 陽子, 岡田 修司
  • Organizer: 2012高分子学会東北支部研究発表会
  • Place of Presentation: 仙台
• [Presentation] TTFを置換したブタジイン誘導体及びそのCT錯体のナノ結晶の作製と構造評価 (2012)
  • Author(s): 今井 将人, 帯刀 陽子, 岡田 修司
  • Organizer: 第21回有機結晶シンポジウム
  • Place of Presentation: 横浜
• [Presentation] Synthesis and Properties of Tetrathiafulvalene Derivatives with Bulky Alicyclic Chiral Substituents and the Charge-Transfer Complexes (2012)
  • Author(s): T. Watanabe, Y. Tatewaki, and S. Okada
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics 2012 (KJF 2012)
  • Place of Presentation: Sendai
• [Presentation] Synthesis, Solid-state Polymerization and Properties of 1-Pyrenylbutadiyne Derivative (2012)
  • Author(s): S. Ito, A. Sato, Y. Tatewaki, and S. Okada
  • Organizer: KJF International Conference on Organic Materials for Electronics and Photonics 2012 (KJF 2012)
  • Place of Presentation: Sendai
• [Presentation] 脂環式キラル置換基を付与したテトラチアフルバレン誘導体の合成と電気物性評価 (2012)
  • Author(s): 帯刀 陽子, 渡部 貴紀, 渡邉 晃司, 菊地 光平, 岡田 修司
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜
• [Presentation] 分子性導体を付与した種々誘導体の自己組織化制御 (2012)
  • Author(s): 帯刀 陽子、 渡部 貴紀、 伊藤 尚矢、 今井 将人、 光山 俊、 岡田 修司
  • Organizer: 日本化学会
  • Place of Presentation: 横浜市 慶応義塾大学
• [Presentation] 有機導体を用いたゲル形成分子の合成とその物性評価 (2011)
  • Author(s): 帯刀 陽子, 渡邉 晃司, 岡田 修司
  • Organizer: 高分子学会
  • Place of Presentation: 大阪 大阪国際会議場
• [Presentation] Tetrathiafulvaleneを置換したブタジイン誘導体ナノ結晶の固相重合性と電子物性評価 (2011)
  • Author(s): 帯刀陽子，松浦辰郎，今井将人，菊地光平，岡田修司
  • Organizer: 応用物理学会
  • Place of Presentation: 山形 山形大学
• [Presentation] Optical and Electrical Properties of Butadiyne Derivatives with Donor Moieties (2011)
  • Author(s): Yoko TATEWAKI, Takanori WATANABE, Syoya ITO, Kohei KIKUCHI, and Shuji OKADA
  • Organizer: ACC14
  • Place of Presentation: Thailand バンコク
• [Presentation] Solid-State Polymerization of Butadiyne with donor molecules and Their Electrical and Optical Properties (2011)
  • Author(s): Yoko TATEWAKI, Takanori WATANABE, Syoya ITO, Kohei KIKUCHI, and Shuji OKADA
  • Organizer: ICONO12
  • Place of Presentation: Ireland Dublin
• [Presentation] Physical Properties of Butadiyne Derivatives with Tetrathiafulvalene Moieties (2011)
  • Author(s): Yoko Tatewaki Takanori Watanabe, Syoya Ito, Masato Imai
  • Organizer: KJF
  • Place of Presentation: Korea Gyeongju
• [Presentation] 1-ピレニルブタジイン誘導体からなるCT錯体の固相重合と光・電気物性評価 (2011)
  • Author(s): 帯刀陽子、伊藤尚矢、今井将人、岡田修司
  • Organizer: 高分子学会
  • Place of Presentation: 岡山 岡山大学
• [Presentation] Molecular Nanowires of Charge-Transfer Complexes and Their Optical and Electrical Properties (2011)
  • Author(s): Yoko TATEWAKI
  • Organizer: Nano S and T(招待講演)
  • Place of Presentation: China Dalian
• [Book] 「ゲル」第2節有機導電体を用いたゲル形成分子の合成とその物性評価 (2013)
  • Author(s): 帯刀陽子
  • Publisher: 技術情報協会
• [Book] ゲル (2013)
  • Author(s): 帯刀陽子
  • Total Pages: 552
  • Publisher: 技術情報協会
• [Remarks] 山形大学大学院理学研究科 岡田研究室
  • URL: http://polyweb.yz.yamagata-u.ac.jp/~okadalab/J-Index.html