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Molecular orientation and the interaction between metal-organic interfaces probed by in situ nonliniear spectroscopy

Research Project

Project/Area Number 23550213
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

MIYAMAE Takayuki  独立行政法人産業技術総合研究所, ナノシステム研究部門, 主任研究員 (80358134)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords表面・界面 / 和周波発生 / 有機EL / 有機薄膜太陽電池 / 有機デバイス / レーザー分光
Research Abstract

We investigated buried organic interfaces and the organic light emitting diode (OLED) interfaces using sum-frequency generation (SFG) vibrational spectroscopy with visible wavelength tunability. In the organic light emitting material interfaces, we found that charge transfer state between the metal and the organic materials were formed at the organic functional material/ metal interfaces. By applying the doubly resonant SFG technique to the OLED devices, we succeed to probe the buried organic layers in the multi-layered OLED device during operation. We also performed the characterization of the PCBM: P3HT surfaces and their thermal annealing effect using doubly-resonant SFG spectroscopy. We found that the extent of the -conjugation length are expanded at the surface by the thermal annealing.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (67 results)

All 2014 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 7 results) Presentation (44 results) (of which Invited: 2 results) Book (10 results) Remarks (3 results)

  • [Journal Article] Why Can Organic Liquids Move Easily on Smooth Alkyl-terminated Surfaces?2014

    • Author(s)
      Chihiro Urata, Benjamin Masheder, Dalton Frederick Cheng, Daniel F Miranda, Gary James Dunderdale, Takayuki Miyamae, Atsushi Hozumi
    • Journal Title

      Langmuir

      Volume: 30 Issue: 14 Pages: 4049-4055

    • DOI

      10.1021/la500548v

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of P3HT:PCBM Thin Film Interfaces by Doubly-Resonant Sum-Frequency Generation Spectroscopy2014

    • Author(s)
      T. Miyamae, Y. Shimoi
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: -

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Feasibility Study for Near-Field Optical Sum-Frequency Generation Spectroscopy Using a Metal-Coated Fiber2013

    • Author(s)
      T. Miyamae, T. Tokizaki
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 11 Issue: 0 Pages: 76-79

    • DOI

      10.1380/ejssnt.2013.76

    • NAID

      130004933782

    • ISSN
      1348-0391
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 和周波発生分光法による界面評価2013

    • Author(s)
      宮前孝行
    • Journal Title

      接着の技術

      Volume: 32 Pages: 44-48

    • Related Report
      2013 Final Research Report
  • [Journal Article] Probing buried organic layers in organic light-emitting diodes under operation by electric-fieldinduced doubly resonant sum-frequency generation spectroscopy2012

    • Author(s)
      T. Miyamae,N. Takada, T. Tsutsui
    • Journal Title

      Appl. Phys. Lett.

      Volume: 101 Issue: 7 Pages: 73304-73304

    • DOI

      10.1063/1.4746273

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Analysis at the Soft Contact Lens Material-Water Interface Using SFG Spectroscopy2012

    • Author(s)
      伊藤裕治、河合哲司、安田章廣、宮前孝行
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 69 Issue: 1 Pages: 27-32

    • DOI

      10.1295/koron.69.27

    • NAID

      130004489363

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 和周波発生分光による界面の分析評価・解析2012

    • Author(s)
      宮前孝行
    • Journal Title

      Polyfile

      Volume: 49 Pages: 38-42

    • Related Report
      2013 Final Research Report
  • [Journal Article] 和周波発生(SFG)分光による有機界面の解析―埋もれた界面を探る計測技術―2011

    • Author(s)
      宮前孝行
    • Journal Title

      O Plus E

      Volume: 33 Pages: 155-159

    • Related Report
      2013 Final Research Report
  • [Journal Article] Surface Structure of Sulfuric Acid Solution Relevant to Sulfate Aerosol : Molecular Dynamics Simulation Combined with Sum Frequency Generation Measurement2011

    • Author(s)
      T. Ishiyama, A. Morita, T. Miyamae
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 13 Issue: 47 Pages: 20965-20973

    • DOI

      10.1039/c1cp21920k

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of the interactions between Alq_3 thin films and Al probed by two-color sum-frequency generation spectroscopy2011

    • Author(s)
      T. Miyamae, E. Ito, Y. Noguchi, H. Ishii
    • Journal Title

      J. Phys. Chem. C

      Volume: 115 Issue: 19 Pages: 9551-9560

    • DOI

      10.1021/jp201051h

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 界面和周波発生法による有機デバイスにおける層界面の構造評価2014

    • Author(s)
      宮前孝行
    • Organizer
      産総研計測フロンティア研究部門第32回公開セミナー
    • Place of Presentation
      つくば
    • Year and Date
      2014-02-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Probing Buried Organic Interfaces using Sum-Frequency Generation Vibrational Spectroscopy2014

    • Author(s)
      T. Miyamae
    • Organizer
      3rd NANOTECH-NRI Joint Workshop
    • Place of Presentation
      つくば
    • Year and Date
      2014-01-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 界面和周波発生法による有機デバイスにおける層界面の構造評価2014

    • Author(s)
      宮前孝行
    • Organizer
      計測フロンティア研究部門第32回公開セミナー
    • Place of Presentation
      産総研つくばセンター(茨城)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 2重共鳴SFG分光によるP3HT : PCBMバルクへテロ接合薄膜表面の熱処理効果2013

    • Author(s)
      宮前孝行、下位幸弘
    • Organizer
      第33回表面科学学術講演会
    • Place of Presentation
      つくば
    • Year and Date
      2013-11-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Surface Structural Study of PCBM : P3HT thin films by Sum-Frequency Generation Spectroscopy2013

    • Author(s)
      T. Miyamae and Y. Shimoi
    • Organizer
      12th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures
    • Place of Presentation
      つくば
    • Year and Date
      2013-11-07
    • Related Report
      2013 Final Research Report
  • [Presentation] PCBM : P3HT薄膜界面の二重共鳴SFG分光2013

    • Author(s)
      宮前孝行、下位幸弘
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都
    • Year and Date
      2013-09-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 二重共鳴SFG分光によるPCBM : P3HT薄膜表面の解析2013

    • Author(s)
      宮前孝行、下位幸弘
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 二重共鳴和周波発生分光を用いた有機薄膜の解析2013

    • Author(s)
      宮前孝行
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Characterization of PCBM : P3HT Thin Film Interfaces by Doubly-Resonant Sum-Frequency Generation Spectroscopy2013

    • Author(s)
      T. Miyamae and Y. Shimoi
    • Organizer
      KJF International Conference 2013 on Organic Materials for Electronics and Photonics (KJF 2013)
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2013-08-31
    • Related Report
      2013 Final Research Report
  • [Presentation] 和周波発生分光法による界面評価2013

    • Author(s)
      宮前孝行
    • Organizer
      日本接着学会講習会
    • Place of Presentation
      東京
    • Year and Date
      2013-01-25
    • Related Report
      2013 Final Research Report
  • [Presentation] PCBM:P3HT薄膜界面の二重共鳴SFG分光2013

    • Author(s)
      宮前孝行、下位幸弘
    • Organizer
      第7回分子科学討論会2013京都
    • Place of Presentation
      京都テルサ(京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Characterization of PCBM:P3HT Thin film Interfaces by Doubly-Resonant Sum Frequency Generation Spectroscopy2013

    • Author(s)
      T. Miyamae and Y. Shimoi
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics
    • Place of Presentation
      Busan, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] 二重共鳴SFG分光によるPCBM:P3HT薄膜表面の解析2013

    • Author(s)
      宮前孝行、下位幸弘
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 二重共鳴和周波発生分光を用いた有機薄膜の解析2013

    • Author(s)
      宮前孝行
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Surface Structural Study of PCBM:P3HT thin films by Sum-Frequency Generation Spectroscopy2013

    • Author(s)
      T. Miyamae and Y. Shimoi
    • Organizer
      12th International Conference on Atomically Controlled Surfaces, Interfaces, and Nanostructures
    • Place of Presentation
      つくば国際会議場(茨城)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 有機高分子の界面の先端分析2012

    • Author(s)
      宮前孝行
    • Organizer
      第日本ゴム協会24回エラストマーの補強研究分科会
    • Place of Presentation
      東京
    • Year and Date
      2012-12-12
    • Related Report
      2013 Final Research Report
  • [Presentation] 電界誘起2重共鳴和周波分光による多層有機EL素子の解析2012

    • Author(s)
      宮前孝行、高田徳幸、筒井哲夫
    • Organizer
      有機EL討論会第15回例会
    • Place of Presentation
      島根
    • Year and Date
      2012-11-21
    • Related Report
      2013 Final Research Report
  • [Presentation] Probing surfaces and interfaces using sum-frequency generation spectroscopy2012

    • Author(s)
      T. Miyamae
    • Organizer
      International Mini-symposium on Surface and Interface for Engineering Neo-Biomimetics
    • Place of Presentation
      Nagoya
    • Year and Date
      2012-10-18
    • Related Report
      2013 Final Research Report
  • [Presentation] SFG and MD simulation study of aqueous sulfuric acid solution surfaces2012

    • Author(s)
      T. Miyamae, T. Ishiyama, A. Morita
    • Organizer
      14th International Conference on Vibrations at Surfaces
    • Place of Presentation
      Kobe
    • Year and Date
      2012-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 多層有機EL素子の電界誘起2重共鳴SFG分光2012

    • Author(s)
      宮前孝行、高田徳幸、筒井哲夫
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 実動作下の多層有機EL素子の2重共鳴SFG分光2012

    • Author(s)
      宮前孝行、高田徳幸、筒井哲夫
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-11
    • Related Report
      2013 Final Research Report
  • [Presentation] 和周波発生分光を用いた高分子表面・界面分析2012

    • Author(s)
      宮前孝行
    • Organizer
      高分子学会第30回高分子表面研究会講座
    • Place of Presentation
      東京
    • Year and Date
      2012-07-06
    • Related Report
      2013 Final Research Report
  • [Presentation] 和周波発生分光による埋もれた固体界面の測定2012

    • Author(s)
      宮前孝行
    • Organizer
      日本表面科学会第72回表面科学研究会「和周波発生分光法による表面・界面計測」
    • Place of Presentation
      東京
    • Year and Date
      2012-03-19
    • Related Report
      2013 Final Research Report
  • [Presentation] 和周波発生分光による有機界面の挙動2012

    • Author(s)
      宮前孝行
    • Organizer
      高分子学会高分子基礎物性・高分子計算機科学合同研究会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-14
    • Related Report
      2013 Final Research Report
  • [Presentation] SFG分光による界面の解析ー固液界面、極微界面ー2012

    • Author(s)
      宮前孝行
    • Organizer
      第5回SFG研究会
    • Place of Presentation
      仙台
    • Year and Date
      2012-03-10
    • Related Report
      2013 Final Research Report
  • [Presentation] ミクロンサイズの共振器を用いた極微センシング技術2012

    • Author(s)
      宮前孝行
    • Organizer
      第4回産総研ナノシステム連携促進フォーラム
    • Place of Presentation
      秋葉原
    • Year and Date
      2012-02-02
    • Related Report
      2013 Final Research Report
  • [Presentation] 実動作下の多層有機EL素子の2重共鳴SFG分光2012

    • Author(s)
      宮前孝行,高田徳幸、筒井哲夫
    • Organizer
      2012年 秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛県、愛媛大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 多層有機EL 素子の電界誘起2 重共鳴SFG 分光2012

    • Author(s)
      宮前孝行,高田徳幸、筒井哲夫
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京都、東京大学
    • Related Report
      2012 Research-status Report
  • [Presentation] SFG and MD simulation study of aqueous sulfuric acid solution surfaces2012

    • Author(s)
      T.Miyamae, T. Ishiyama, A. Morita
    • Organizer
      14th International Conference on Vibrations at Surfaces
    • Place of Presentation
      兵庫県、Nichii Gakkan Kobe Port Island Center
    • Related Report
      2012 Research-status Report
  • [Presentation] Probing surfaces and interfaces using sum-frequency generation spectroscopy2012

    • Author(s)
      T. Miyamae
    • Organizer
      International Mini-symposium on Surface and Interface for Engineering Neo-Biomimetics
    • Place of Presentation
      愛知県、産総研中部センター
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 電界誘起2重共鳴和周波分光による多層有機 EL 素子の解析2012

    • Author(s)
      宮前孝行,高田徳幸、筒井哲夫
    • Organizer
      有機EL討論会第15回例会
    • Place of Presentation
      島根県、くにびきメッセ
    • Related Report
      2012 Research-status Report
  • [Presentation] SFG分光による界面の解析ー固液界面、極微界面ー2012

    • Author(s)
      宮前孝行
    • Organizer
      第5回SFG研究会(招待講演)
    • Place of Presentation
      宮城県、東北大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 和周波発生分光による有機界面の挙動2012

    • Author(s)
      宮前孝行
    • Organizer
      高分子基礎物性・高分子計算機科学合同研究会(招待講演)
    • Place of Presentation
      東京都、東京工業大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 和周波発生分光による埋もれた固体界面の測定2012

    • Author(s)
      宮前孝行
    • Organizer
      第72回表面科学研究会(招待講演)
    • Place of Presentation
      東京都、東京理科大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Two-Color Sum-Frequency Generation Study for Buried Poly(9,9-diocthylfluorenyl- 2,7-diyl) Interfaces2011

    • Author(s)
      T. Miyamae, K. Tsukagoshi, W. Mizutani
    • Organizer
      6th International Symposium onSurface Science
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-12-14
    • Related Report
      2013 Final Research Report
  • [Presentation] 硫酸水溶液表面の解離状態2011

    • Author(s)
      宮前孝行、石山達也、森田明弘
    • Organizer
      表面界面スペクトロスコピー2011
    • Place of Presentation
      三浦市
    • Year and Date
      2011-12-03
    • Related Report
      2013 Final Research Report
  • [Presentation] 微小球共振器による化学・バイオセンサー2011

    • Author(s)
      宮前孝行、西村聡、井上貴仁、時崎高志
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] Probing Organic/Metal Interfaces using Two-Color Sum-Frequency Generation2011

    • Author(s)
      T. Miyamae
    • Organizer
      Workshop on characterizations for OPV materials and devices
    • Place of Presentation
      Tsukuba
    • Year and Date
      2011-09-02
    • Related Report
      2013 Final Research Report
  • [Presentation] Two-color SFG分光によるAlq_3/Al界面の解析2011

    • Author(s)
      宮前孝行、伊藤英輔、野口裕、石井久夫
    • Organizer
      有機EL討論会第12回例会
    • Place of Presentation
      東京
    • Year and Date
      2011-06-30
    • Related Report
      2013 Final Research Report
  • [Presentation] 和周波発生(SFG)分光による有機界面の解析2011

    • Author(s)
      宮前孝行
    • Organizer
      日本ゴム協会第172回ゴム技術シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2011-06-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 和周波発生(SFG)分光による有機界面の解析2011

    • Author(s)
      宮前孝行
    • Organizer
      第172回ゴム技術シンポジウム(招待講演)
    • Place of Presentation
      東京都、東京電業会館
    • Related Report
      2011 Research-status Report
  • [Presentation] Two-color SFG 分光によるAlq3/Al 界面の解析2011

    • Author(s)
      宮前孝行,伊藤英輔,野口裕,石井久夫
    • Organizer
      有機EL討論会第12回例会
    • Place of Presentation
      東京都、日本科学未来館
    • Related Report
      2011 Research-status Report
  • [Presentation] Probing Organic/Metal Interfaces using Two-Color Sum-Frequency Generation2011

    • Author(s)
      Takayuki Miyamae
    • Organizer
      Workshop on characterizations for OPV materials and devices(招待講演)
    • Place of Presentation
      茨城県、産業技術総合研究所
    • Related Report
      2011 Research-status Report
  • [Presentation] Two-Color Sum-Frequency Generation Study for Buried Poly(9,9-diocthylfluorenyl-2,7-diyl) Interfaces2011

    • Author(s)
      Takayuki Miyamae
    • Organizer
      6th International Symposium onSurface Science
    • Place of Presentation
      Tokyo, Funabori Tower Hall
    • Related Report
      2011 Research-status Report
  • [Book] 高分子ナノテクノロジーハンドブック2014

    • Author(s)
      宮前孝行, 他
    • Total Pages
      7
    • Publisher
      NTS
    • Related Report
      2013 Final Research Report
  • [Book] 高分子ナノテクノロジーハンドブック ~最新ポリマーABC技術を中心として~2014

    • Author(s)
      西敏夫、宮前孝行他
    • Total Pages
      1096
    • Publisher
      NTS
    • Related Report
      2013 Annual Research Report
  • [Book] ゲルの安定化と機能性付与・次世代への応用開発2013

    • Author(s)
      宮前孝行, 他
    • Total Pages
      8
    • Publisher
      技術情報協会
    • Related Report
      2013 Final Research Report
  • [Book] in situ測定/その場観察実例集2013

    • Author(s)
      宮前孝行, 他
    • Publisher
      情報機構
    • Related Report
      2013 Final Research Report
  • [Book] 薄膜の評価技術ハンドブック2013

    • Author(s)
      宮前孝行, 他
    • Publisher
      テクノシステム
    • Related Report
      2013 Final Research Report
  • [Book] in-situ測定/その場観察 実例集 ~各種計測技術の実践テクニックおよび材料・デバイス別分析例~2013

    • Author(s)
      進藤大輔、宮前孝行他
    • Total Pages
      315
    • Publisher
      情報機構
    • Related Report
      2013 Annual Research Report
  • [Book] ゲルの安定化と 機能性付与・次世代への応用開発2013

    • Author(s)
      伊藤和明、宮前孝行他
    • Total Pages
      552
    • Publisher
      技術情報協会
    • Related Report
      2013 Annual Research Report
  • [Book] 薄膜の評価技術ハンドブック2013

    • Author(s)
      宮前孝行他
    • Total Pages
      620
    • Publisher
      テクノシステム
    • Related Report
      2012 Research-status Report
  • [Book] Vibrational Spectroscopy2012

    • Author(s)
      Takayuki Miyamae
    • Total Pages
      168
    • Publisher
      Intech
    • Related Report
      2011 Research-status Report
  • [Book] Vibrational Spectroscopy2011

    • Author(s)
      T. Miyamae, 他
    • Publisher
      Intech
    • Related Report
      2013 Final Research Report
  • [Remarks] 2012年8月15日産総研プレスリリース 「発光している有機EL素子内部の状態を計測・評価」

    • URL

      http://www.aist.go.jp/aist_j/press_release/pr2012/pr20120815/pr20120815.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 宮前孝行、高田徳幸,発光している有機EL素子の内部を計測・評価,産総研TODAY, 2013年, 1月号, 18

    • URL

      http://www.aist.go.jp/Portals/0/resource_images/aist_j/aistinfo/aist_today/vol13_01/vol13_01_p18.pdf

    • Related Report
      2013 Final Research Report
  • [Remarks] 発光している有機EL素子内部の状態を計測・評価

    • URL

      http://www.aist.go.jp/aist_j/press_release/pr2012/pr20120815/pr20120815.html

    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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