Study on preparation of functional nanoribbons via solid phase reactions under hydrothermal conditions
| Project/Area Number |
23550226
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Kobe University |
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Principal Investigator |
EDA Kazuo 神戸大学, 理学(系)研究科(研究院), 助教 (00193996)
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| Co-Investigator(Renkei-kenkyūsha) |
ONODERA Hiroaki 京都府立大学, 大学院生命環境科学研究科, 講師 (80360246)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 無機合成 / ソフトケミストリ / 機能性酸化物 / ナノリボン / 水熱合成 / ソフトケミストリー / ナノワイヤー |
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| Research Abstract |
Blue bronzes exhibit numerous interesting behaviors due to the CDW motion at a lower temperature and have been expected to show novel properties when being nanoribbon-like crystals. However, so far it was hardly possible to obtain blue bronze nanoribbons. In this study we aimed at developing preparation methods of them.
First we developed a facile preparation method of single phase of blue bronze. Using the method we have succeeded in preparing the potassium blue bronze K0.3MoO3 nanoribbons grown well along the crystal b axis that corresponds to the direction of quasi-1D metallic conduction. Some properties of the nanoribbons (the electrical conductivity and the magnetic susceptibility of nanoribbon ensemble) were measured. Furthermore, we have succeeded in preparing nanoribbons of cesium blue bronze Cs0.3MoO3 and cesium-potassium blue bronze mixed crystals Cs0.3-xKxMoO3 (0<x<0.3) that cannot be obtained by usual preparation techniques such as molten salt methods.
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Report
(4 results)
Research Products
(9 results)
