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Optimization of laser plasma for in situ underwater surface elemental analysis

Research Project

Project/Area Number 23560023
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionKyoto University

Principal Investigator

SAKKA Tetsuo  京都大学, 工学(系)研究科(研究院), 教授 (10196206)

Co-Investigator(Renkei-kenkyūsha) FUKAMI Kazuhiro  京都大学, 大学院工学研究科, 准教授 (60452322)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsレーザープラズマ / 水中プラズマ / レーザー誘起ブレークダウン分光法 / キャビテーションバブル / 発光分光 / レーザー誘起プレークダウン分光法 / 分光イメージング / 液相レーザーアブレーション / レーザー誘起ブレークダウン分光 / 水中その場元素分析 / 気泡 / ダブルパルス / マルチパルス
Research Abstract

For in situ elemental analysis of solid materials submerged in water by the emission spectroscopy of the plasma generated by the pulsed laser irradiation of the solid surface in water, it is difficult to obtain stably well-defined atomic emission lines. In the present study we focused on the effects of the temporal profile of the irradiation laser upon the behavior of the plasma and the cavitation bubble, and tried to obtain clearer atomic emission lines by optimizing the irradiation conditions as well as the detection techniques for the emission spectra. Also, we tried to clarify the reason why such conditions give clear atomic emission lines from the point of view of the plasma formation mechanism.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (48 results)

All 2014 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (42 results) (of which Invited: 4 results)

  • [Journal Article] Effects of pulse width on nascent laser-induced bubbles for underwater laser-induced breakdown spectroscopy2014

    • Author(s)
      Tetsuo Sakka, Ayaka Tamura, Ayumu Matsumoto, Kazuhiro Fukami, Naoya Nishi and Blair Thornton
    • Journal Title

      Spectrochimica Acta Part B

      Volume: 97 Pages: 94-98

    • DOI

      10.1016/j.sab.2014.05.009

    • Related Report
      2013 Final Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spectroscopic Measurements of Solids Immersed in Water at High Pressure Using a Long-Duration Nanosecond Laser Pulse2013

    • Author(s)
      Blair Thornton, Tetsuo Sakka, Tomoko Takahashi, Ayaka Tamura, Tatsuya Masamura, Ayumu Matsumoto
    • Journal Title

      Applied Physics Express

      Volume: 6 Issue: 8 Pages: 82401-82401

    • DOI

      10.7567/apex.6.082401

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dynamics of cavitation bubbles generated by multi-pulse laser irradiation of a solid target in water2013

    • Author(s)
      Ayaka Tamura, Tetsuo Sakka, Kazuhiro Fukami, Yukio H. Ogata
    • Journal Title

      Applied Physics A

      Volume: vol.112, No. 1 Issue: 1 Pages: 209-213

    • DOI

      10.1007/s00339-012-7291-x

    • NAID

      120005477226

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Single-Pulse Underwater Laser-Induced Breakdown Spectroscopy with Nongated Detection Scheme2013

    • Author(s)
      A. Matsumoto, A. Tamura, K. Fukami, Y. H. Ogata, T. Sakka
    • Journal Title

      Anal. Chem.

      Volume: 85 Issue: 8 Pages: 3807-3811

    • DOI

      10.1021/ac400319v

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Two-dimensional space-resolved emission spectroscopy of laser ablation plasma in water2013

    • Author(s)
      Ayumu Matsumoto, Ayaka Tamura, Kazuhiro Fukami, Yukio H. Ogata, Tetsuo Sakka
    • Journal Title

      Journal of Applied Physics

      Volume: vol.113, No. 5 Issue: 5 Pages: 53302-53302

    • DOI

      10.1063/1.4789968

    • NAID

      120005439681

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synergetic effects of double laser pulses for the formation of mild plasma in water: Toward non-gated underwater laser-induced breakdown spectroscopy2012

    • Author(s)
      Tetsuo Sakka, Ayaka Tamura, Takashi Nakajima, Kazuhiro Fukami, and Yukio H. Ogata
    • Journal Title

      Journal of Chemical Physics

      Volume: 136 Issue: 17 Pages: 174201-174201

    • DOI

      10.1063/1.4709391

    • NAID

      120004367779

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 電析皮膜のレーザーアブレーションで生成するプラズマの発光スペクトルと照射痕の関係2014

    • Author(s)
      松本 歩、 田村 文香、深見 一弘、西 直哉、作花 哲夫
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      吹田
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水中レーザープラズマの生成とレーザー誘起ブレークダウン分光法によるその場元素分析2013

    • Author(s)
      作花哲夫、田村文香、松本歩、西直哉、深見一弘、Blair Thornton
    • Organizer
      東北大学金属材料研究所ワークショップ―金属材料の高度利用、省資源化、及び循環利用に資する分析・解析技術
    • Place of Presentation
      東北大学金属材料研究所、仙台
    • Related Report
      2013 Final Research Report
  • [Presentation] レーザー誘起ブレークダウン分光法による水中その場元素分析における初期気泡とレーザープラズマの観察2013

    • Author(s)
      田村文香、松本歩、深見一弘、西直哉、作花哲夫
    • Organizer
      第59回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      石垣市民会館、石垣市
    • Related Report
      2013 Final Research Report
  • [Presentation] Space-resolved emission spectroscopy of the plasma generated by laser ablation in water2013

    • Author(s)
      A. Matsumoto, A. Tamura, K. Fukami, Y. Ogata, T. Sakka
    • Organizer
      12th International Conference on Laser Ablation (COLA2013)
    • Place of Presentation
      Ischia, Italy
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Optimizing the plasma-in-the-bubble structure for improvement of underwater laser-induced breakdown spectra2013

    • Author(s)
      A. Tamura, A. Matsumoto, K. Fukami, Y. Ogata, N. Nishi, T. Sakka
    • Organizer
      The 7th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy (EMS-LIBS2013)
    • Place of Presentation
      Bari, Italy
    • Related Report
      2013 Final Research Report
  • [Presentation] Non-gated underwater LIBS by the combination of long-pulse irradiation and space-resolved emission spectroscopy2013

    • Author(s)
      A. Matsumoto, A. Tamura, K. Fukami, Y. Ogata, N. Nishi, T. Sakka
    • Organizer
      The 7th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy (EMS-LIBS2013)
    • Place of Presentation
      Bari, Italy
    • Related Report
      2013 Final Research Report
  • [Presentation] Laser plasma generation in water and application to underwater LIBS2013

    • Author(s)
      T. Sakka, A. Tamura, A. Matsumoto, K. Fukami, Y. H. Ogata, N. Nishi, B. Thornton
    • Organizer
      The 7th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy (EMS-LIBS2013)
    • Place of Presentation
      Bari, Italy
    • Related Report
      2013 Final Research Report
  • [Presentation] レーザー誘起ブレイクダウン分光法による水中その場元素分析のための最適なレーザープラズマの検討2013

    • Author(s)
      田村文香、松本歩、深見一弘、尾形幸生、作花哲夫
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      函館
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] シングルパルスレーザー照射による液中プラズマのゲート動作なしでの分光分析2013

    • Author(s)
      松本歩、田村文香、深見一弘、尾形幸生、作花哲夫
    • Organizer
      第60回応用物学会春季学術講演会
    • Place of Presentation
      厚木
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] レーザー誘起ブレイクダウン分光法による液中金属イオンの高感度分析2013

    • Author(s)
      松本 歩、田村 文香、幸田 吏央、深見 一弘、尾形 幸生、作花 哲夫
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      函館
    • Related Report
      2013 Annual Research Report
  • [Presentation] Laser Plasma Generation in Water and Application to Underwater LIBS2013

    • Author(s)
      T. Sakka, A. Tamura, A. Matsumoto, K. Fukami, Y. H. Ogata, N. Nishi, B. Thornton
    • Organizer
      The 7th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy (EMS-LIBS2013)
    • Place of Presentation
      Bari Italy
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Non-Gated Underwater LIBS by the Combination of Long-Pulse Irradiation and Space-Resolved Emission Spectroscopy2013

    • Author(s)
      A. Matsumoto, A. Tamura, K. Fukami, Y. H. Ogata, N. Nishi, T. Sakka
    • Organizer
      The 7th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy (EMS-LIBS2013)
    • Place of Presentation
      Bari Italy
    • Related Report
      2013 Annual Research Report
  • [Presentation] Optimizing the Plasma-in-the-Bubble Structure for Improvement of Underwater Laser-Induced Breakdown Spectra2013

    • Author(s)
      A. Tamura, A. Matsumoto, K. Fukami, Y. H. Ogata, N. Nishi, T. Sakka
    • Organizer
      The 7th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy (EMS-LIBS2013)
    • Place of Presentation
      Bari Italy
    • Related Report
      2013 Annual Research Report
  • [Presentation] 電解析出とレーザー誘起ブレークダウン分光法を組み合わせた液中微量金属イオンのその場定量分析法の開発2013

    • Author(s)
      松本 歩、田村文香、深見一弘、西直哉、Blair Thornton、作花哲夫
    • Organizer
      第59回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      石垣
    • Related Report
      2013 Annual Research Report
  • [Presentation] レーザー誘起ブレークダウン分光法による水中その場元素分析における初期気泡とレーザープラズマの観察2013

    • Author(s)
      田村文香、松本 歩、深見一弘、西 直哉、作花哲夫
    • Organizer
      第59回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      石垣
    • Related Report
      2013 Annual Research Report
  • [Presentation] 吸収分光法による液中レーザー誘起微小プラズマ中の基底種の解析2013

    • Author(s)
      川崎 惇、田村文香、松本 歩、深見一弘、西 直哉、作花哲夫
    • Organizer
      第59回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      石垣
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水中レーザープラズマの生成とレーザー誘起ブレークダウン分光法によるその場元素分析2013

    • Author(s)
      作花哲夫、田村文香、松本 歩、西 直哉、深見一弘、Blair Thornton
    • Organizer
      東北大学金属材料研究所ワークショップ 金属材料の高度利用、省資源化、及び循環利用に資する分析・解析技術
    • Place of Presentation
      池田
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 水中レーザー誘起ブレークダウン分光法:キャビテーションバブルの制御によるプラズマの最適化2013

    • Author(s)
      作花哲夫
    • Organizer
      先端計測技術の応用展開に関するシンポジウム ―鉄鋼、化学工学、エネルギー関連技術への適用技術―
    • Place of Presentation
      徳島
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 短いパルス間隔のダブルパルス照射による液中レーザープラズマの発光挙動2013

    • Author(s)
      田村文香,松本 歩,Yu Qin,中嶋 隆,深見一弘,尾形幸生,作花哲夫
    • Organizer
      第60回応用物学会春季学術講演会
    • Place of Presentation
      厚木
    • Related Report
      2012 Research-status Report
  • [Presentation] 液相レーザーアブレーションプルームの発光スペクトルとその場元素分析への応用2012

    • Author(s)
      作花哲夫
    • Organizer
      東京工業大学応用セラミックス研究所共同利用研究ワークショップ「局所高密度励起の化学と応用」
    • Place of Presentation
      横浜
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] 水中でのレーザープラズマの生成と水中固体表面のその場元素分析への応用2012

    • Author(s)
      作花哲夫
    • Organizer
      第14回関西表面技術フォーラム
    • Place of Presentation
      宇治
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical emission spectroscopy of laser ablation plasma in water and application to underwater LIBS2012

    • Author(s)
      T. Sakka, A. Tamura, A. Matsumoto, Y. Qin, T. Nakajima, K. Fukami, Y. H. Ogata
    • Organizer
      The 13th Symposium on Advanced Photon Research
    • Place of Presentation
      Kizu, Japan
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Low-power multi-pulse laser as an excitation source for underwater laser-induced breakdown spectroscopy2012

    • Author(s)
      A. Tamura, A. Matsumoto, T. Sakka, K. Fukami, Y. H. Ogata
    • Organizer
      7th International Conference on Laser Induced Breakdown Spectroscopy
    • Place of Presentation
      Luxor, Egypt
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Effects of irradiation scheme on underwater LIBS2012

    • Author(s)
      T. Sakka, A. Tamura, A. Matsumoto, K. Fukami, Y. H. Ogata, Y. Qin, T. Nakajima, T. Takahashi, B. Thornton
    • Organizer
      7th International Conference on Laser Induced Breakdown Spectroscopy
    • Place of Presentation
      Luxor, Egypt
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Effects of irradiation process upon the laser plasma formation in water for in situ LIBS measurement2012

    • Author(s)
      T. Sakka, A. Tamura, A. Matsumoto, K. Fukami, Y. H. Ogata
    • Organizer
      KIFEE International Symposium on Environment, Energy and Materials
    • Place of Presentation
      Trondheim, Norway
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Laser-induced breakdown spectroscopy in water by using long-pulse laser ablation2012

    • Author(s)
      A. Matsumoto, A. Tamura, T. Sakka, K. Fukami, Y. H. Ogata
    • Organizer
      2012 ASLO Aquatic Sciences Meeting
    • Place of Presentation
      Ohtsu, Japan
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Non-gated underwater laser induced breakdown spectroscopy with double pulse and multi-pulse laser irradiation2012

    • Author(s)
      A. Tamura, A. Matsumoto, T. Sakka, K. Fukami, Y. H. Ogata
    • Organizer
      2012 ASLO Aquatic Sciences Meeting
    • Place of Presentation
      Ohtsu, Japan
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Laser-induced breakdown spectroscopy of trace metal ions in water by using electrodeposition2012

    • Author(s)
      A. Matsumoto, A. Tamura, R. Koda, T. Sakka, K. Fukami, Y. H. Ogata
    • Organizer
      7th International Conference on Laser Induced Breakdown Spectroscopy
    • Place of Presentation
      Luxor, Egypt
    • Related Report
      2012 Research-status Report
  • [Presentation] 水中でのレーザープラズマの生成と水中固体表面のその場元素分析への応用2012

    • Author(s)
      作花哲夫
    • Organizer
      第14回関西表面技術フォーラム
    • Place of Presentation
      宇治
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] レーザープラズマ分光法への電解析出の導入による液中金属イオンの検出感度向上の試み2012

    • Author(s)
      松本歩, 田村文香, 幸田吏央, 深見一弘, 尾形幸生, 作花哲夫
    • Organizer
      第14回関西表面技術フォーラム
    • Place of Presentation
      宇治
    • Related Report
      2012 Research-status Report
  • [Presentation] 水中での低出力ダブルパルスレーザーアブレーションにより生成する気泡の挙動2012

    • Author(s)
      田村文香,作花哲夫,深見一弘,尾形幸生
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学早稲田キャンパス、東京都新宿区
    • Related Report
      2011 Research-status Report
  • [Presentation] 水中レーザープラズマ発光分光におけるゲート動作なしでの明瞭な原子発光線観測2011

    • Author(s)
      田村文香、作花哲夫、深見一弘、尾形幸生
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学、山形市
    • Year and Date
      2011-08-31
    • Related Report
      2013 Final Research Report
  • [Presentation] 液相レーザーアブレーションプルームの発光スペクトルとその場元素分析への応用2011

    • Author(s)
      作花哲夫、田村文香、深見一弘、尾形幸生
    • Organizer
      ミニシンポジウム「液相中の固体とレーザー光との相互作用:ナノ材料作製のための基礎から応用」
    • Place of Presentation
      香川大学幸町キャンパス、高松市
    • Year and Date
      2011-06-11
    • Related Report
      2013 Final Research Report
  • [Presentation] Application of multipulse microchip laser to in situ under-water laser induced breakdown spectroscopy2011

    • Author(s)
      T. Sakka
    • Organizer
      9th Eco-Energy and Materials Science and Engineering Symposium
    • Place of Presentation
      Chiang Rai, Thailand
    • Year and Date
      2011-05-27
    • Related Report
      2013 Final Research Report
  • [Presentation] Continuum-free emission spectrum measurement without time-gating for underwater laser-induced breakdown spectroscopy2011

    • Author(s)
      A. Tamura, T. Sakka, K. Fukami, Y. H. Ogata
    • Organizer
      11th International Conference on Laser Ablation
    • Place of Presentation
      Playa del Carmen, Mexico
    • Related Report
      2013 Final Research Report
  • [Presentation] Application of multipulse microchip lasser to insitu under-water laser induced breakdown spectroscopy2011

    • Author(s)
      T. Sakka
    • Organizer
      9th Eco-Energy and Materials Science and Engineering Symposium
    • Place of Presentation
      Chiang Rai, Thailand
    • Related Report
      2011 Research-status Report
  • [Presentation] 液相レーザーアブレーションプルームの発光スペクトルとその場元素分析への応用2011

    • Author(s)
      作花哲夫,田村文香,深見一弘,尾形幸生
    • Organizer
      ミニシンポジウム「液相中の固体とレーザー光との相互作用:ナノ材料作製のための基礎から応用」
    • Place of Presentation
      香川大学幸町キャンパス,高松市
    • Related Report
      2011 Research-status Report
  • [Presentation] 貴金属水溶液中でのチタンのレーザーアブレーション2011

    • Author(s)
      作花哲夫,鈴木友矩,小川昌秀,深見一弘,尾形幸生
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学,山形市
    • Related Report
      2011 Research-status Report
  • [Presentation] 水中レーザープラズマ発光分光におけるゲート動作なしでの明瞭な原子発光線観測2011

    • Author(s)
      田村文香,作花哲夫,深見一弘,尾形幸生
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学,山形市
    • Related Report
      2011 Research-status Report
  • [Presentation] Continuum-free emission spectrum measurement without time-gating for underwater laser-induced breakdown spectroscopy2011

    • Author(s)
      Ayaka Tamura, Tetsuo Sakka, Kazuhiro Fukami, Yukio H. Ogata
    • Organizer
      11th International Conference on Laser Ablation
    • Place of Presentation
      Playa del Carmen,Mexico
    • Related Report
      2011 Research-status Report
  • [Presentation] Laser ablation in a solution containing noble metal ions: formation of semiconductor-metal nanocomposites2011

    • Author(s)
      Tetsuo Sakka, Tomonori Suzuki, Masahide Ogawa, Kazuhiro Fukami, Yukio H. Ogata
    • Organizer
      11th International Conference on Laser Ablation
    • Place of Presentation
      Playa del Carmen,Mexico
    • Related Report
      2011 Research-status Report
  • [Presentation] 水中レーザー誘起ブレークダウン分光法:キャビテーションバブルの制御によるプラズマの最適化

    • Author(s)
      作花哲夫
    • Organizer
      先端計測技術の応用展開に関するシンポジウム―鉄鋼、化学工学、エネルギー関連技術への適用技術―
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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