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Shape formation in silicon surface by transfer photo-etching using chemical reaction at fluorinating agent-silicon interface

Research Project

Project/Area Number 23560123
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Production engineering/Processing studies
Research InstitutionOsaka University

Principal Investigator

UCHIKOSHI Junichi  大阪大学, 工学(系)研究科(研究院), 招へい教員 (90273581)

Co-Investigator(Kenkyū-buntansha) MORITA Mizuho  大阪大学, 大学院工学研究科, 教授 (50157905)
KAWAI Kentaro  大阪大学, 大学院工学研究科, 助教 (90514464)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Keywordsフッ素化剤 / N-フルオロピリジニウム塩 / 光エッチング / 光転写 / シリコン / 3次元形状 / 半導体表面 / 形状創成 / N-フルオロピリジニウム塩 / エッチング / フォトエッチング / 創成加工 / 修正加工
Research Abstract

A new photo-etching method with N-fluoropyridinium salts is proposed in this study. Si is etched by applying N-fluoropyridinium salts to its surface and exposing the surface to light. Si is etched by the irradiation of light with an energy higher than the band gap of Si. The N-F bond in the salts is broken by receiving excited electrons and releases an active F species. The F species react with Si to produce SiF4. The SiF4 is released.
The etching rate increases with exposure time or light intensity or temperature. A ditch with different depths and a spherical surface and a flat surface are formed by exposing to light with different intensities at a time. It is expected to form arbitrary three-dimensional shape in a silicon surface by controlling light intensity distribution.
Absolute flatness of three silicon plane mirrors have been measured by a three-intersection method based on the three-flat method using a near-infrared interferometer.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (30 results)

All 2013 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (20 results) Remarks (3 results) Patent(Industrial Property Rights) (4 results) (of which Overseas: 2 results)

  • [Journal Article] Absolute flatness measurements of silicon mirrors by a three-intersection method by near-infrared interferometry2013

    • Author(s)
      Junichi Uchikoshi, Yoshinori Hayashi, Noritaka Ajari, Kentaro Kawai, Kenta Arima and Mizuho Morita
    • Journal Title

      Nanoscale Research Letters

      Volume: 8 Issue: 1 Pages: 2751-7

    • DOI

      10.1186/1556-276x-8-275

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Si etching with N-fluoropyridinium salt2012

    • Author(s)
      Kentaro Tsukamoto, Junichi Uchikoshi, Masaki Otani, Toshinori Hirano, Yutaka Ie, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima, and Mizuho Morita
    • Journal Title

      Current Applied Physics

      Volume: 12

    • URL

      http://www.sciencedirect.com/science/journal/15671739/12/supp/S4

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Si etching with N-fluoropyridinium salt2012

    • Author(s)
      Kentaro Tsukamoto, Junichi Uchikoshi, Masaki Otani, Toshinori Hirano, Yutaka Ie, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima, Mizuho Morita
    • Journal Title

      Current Applied Physics

      Volume: 12

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] N-フルオロピリジニウム塩を用いた光エッチングによるシリコンのランダム逆ピラミッドの形成2013

    • Author(s)
      足達健二、永井隆文、平野利典、大谷真輝、川合健太郎、打越純一、森田瑞穂
    • Organizer
      第36回フッ素化学討論会
    • Place of Presentation
      つくば国際会議場(つくば市)
    • Year and Date
      2013-10-04
    • Related Report
      2013 Final Research Report
  • [Presentation] N-フルオロピリジニウム塩を用いた光エッチングによるシリコンのランダム逆ピラミッドの形成2013

    • Author(s)
      平野利典、打越純一、大谷真輝、永井隆文、足達健二、川合健太郎、有馬健太、森田瑞穂
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      厚木市
    • Year and Date
      2013-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Development of Silicon Photo-Etching with N-Fluoropyridinium Salts2012

    • Author(s)
      Junichi Uchikoshi, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima and Mizuho Morita
    • Organizer
      Fifth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2012-10-24
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Formation of Three-Dimensional Shape in Silicon Surface by Photo-Etching with N-Fluoropyridinium Salts2012

    • Author(s)
      Masaki Otani, Junichi Uchikoshi, Toshinori Hirano, Kentaro Tsukamoto, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima and Mizuho Morita
    • Organizer
      Fifth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2012-10-23
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Absolute Flatness Measurements of Silicon Mirrors by A Three-Intersections Method Using Near-Infrared Interferometry2012

    • Author(s)
      Junichi Uchikoshi, Yoshinori Hayashi, Noritaka Ajari, Katsumi Oda, Taro Arai, Kentaro Kawai, Kenta Arima and Mizuho Morita
    • Organizer
      Fifth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2012-10-23
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Formation of Si Random Inverted-Pyramids by Etching with N-Fluoropyridinium Salts2012

    • Author(s)
      Toshinori Hirano, Junichi Uchikoshi, Masaki Otani, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima and Mizuho Morita
    • Organizer
      Fifth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2012-10-23
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Optical property of random inverted-pyramid textures on Si surface by etching with Nfluoropyridinium salts2012

    • Author(s)
      Masaki Otani, Junichi Uchikoshi, Kentaro Tsukamoto, Toshinori Hirano, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima, and Mizuho Morita
    • Organizer
      PACIFIC RIM MEETING ON ELECTROCHEMICAL AND SOLID-STATE SCIENCE
    • Place of Presentation
      Honolulu, Hawaii, U.S.A.
    • Year and Date
      2012-10-10
    • Related Report
      2013 Final Research Report
  • [Presentation] N-フルオロピリジニウム塩を用いたエッチングによるSiのランダム逆ピラミッドの形成2012

    • Author(s)
      平野利典、打越純一、大谷真輝、塚本健太郎、永井隆文、足達健二、川合健太郎、有馬健太、森田瑞穂
    • Organizer
      2012年度精密工学会秋季大会学術講演会
    • Place of Presentation
      北九州市
    • Year and Date
      2012-09-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Photo-etching of Silicon by N-Fluoropyridinium Salts2012

    • Author(s)
      Kenji Adachi, Takabumi Nagai, Junichi Uchikoshi, Kentaro Tsukamoto, Masaki Otani, and Mizuho Morita
    • Organizer
      20th INTERNATIONAL SYMPOSIUM ON FLUORINE CHEMISTRY 2012
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2012-07-24
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] N-フルオロピリジニウム塩を用いた光エッチングによるSi表面テクスチャの形成2012

    • Author(s)
      大谷真輝、打越純一、塚本健太郎、平野利典、永井隆文、足達健二、川合健太郎、有馬健太、森田瑞穂
    • Organizer
      2012年度精密工学会春季大会学術講演会
    • Place of Presentation
      八王子市
    • Year and Date
      2012-03-15
    • Related Report
      2013 Final Research Report 2011 Research-status Report
  • [Presentation] Cu assisted etching with N-fluoropyridinium salts2011

    • Author(s)
      Kentaro Tsukamoto, Junichi Uchikoshi, Masaki Otani,Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima, and Mizuho Morita
    • Organizer
      Extended Abstracts of Fourth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2011-10-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Metal Particulates on Si Etching with N-Fluoropyridinium Salts2011

    • Author(s)
      Masaki Otani, Junichi Uchikoshi, Kentaro Tsukamoto, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima, and Mizuho Morita
    • Organizer
      Extended Abstracts of Fourth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2011-10-10
    • Related Report
      2013 Final Research Report
  • [Presentation] N-フルオロピリジニウム塩を用いた光エッチングによるシリコン表面の精密位置合わせ3次元形状創成2011

    • Author(s)
      大谷真輝、打越純一、塚本健太郎、永井隆文、足達健二、川合健太郎、有馬健太、森田瑞穂
    • Organizer
      2011年度精密工学会秋季大会学術講演会
    • Place of Presentation
      金沢市
    • Year and Date
      2011-09-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Cu assisted etching of Si with N-fluoropyridinium salt2011

    • Author(s)
      Kentaro Tsukamoto, Junichi Uchikosh, Masaki Otani, Takabumi Nagai, Kenji Adachi,Kentaro Kawai, Kenta Arima and Mizuho Morita
    • Organizer
      Extended Abstracts of Fourth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] Metal Particulates on Si Etching with N-fluoropyridinium Salts2011

    • Author(s)
      Masaki Otani, Junichi Uchikoshi, Kentaro Tsukamoto, Takabumi Nagai, Kenji Adachi,Kentaro Kawai, Kenta Arima and Mizuho Morita
    • Organizer
      Extended Abstracts of Fourth International Symposium on Atomically Controlled Fabrication Technology
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] N-フルオロピリジニウム塩を用いた光エッチングによるシリコン表面の精密位置合わせ3次元形状創成2011

    • Author(s)
      大谷真輝、打越純一、塚本健太郎、永井隆文、足達健二、川合健太郎、有馬健太、森田瑞穂
    • Organizer
      2011年度精密工学会秋季大会学術講演会
    • Place of Presentation
      金沢市
    • Related Report
      2011 Research-status Report
  • [Presentation] N-フルオロピリジニウム塩を用いた光エッチングによるシリコンのランダム逆ピラミッドの形成

    • Author(s)
      足達健二、永井隆文、平野利典、大谷真輝、川合健太郎、打越純一、森田瑞穂
    • Organizer
      第36回フッ素化学討論会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] N-フルオロピリジニウム塩を用いたエッチングによるSiのランダム逆ピラミッドの形成

    • Author(s)
      平野利典,打越純一,大谷真輝,塚本健太郎,永井隆文,足達健二,川合健太郎,有馬健太,森田瑞穂
    • Organizer
      2012年度精密工学会秋季大会学術講演会
    • Place of Presentation
      北九州市
    • Related Report
      2012 Research-status Report
  • [Presentation] Optical property of random inverted-pyramid textures on Si surface by etching with N-fluoropyridinium salts

    • Author(s)
      Masaki Otani, Junichi Uchikoshi, Kentaro Tsukamoto, Toshinori Hirano, Takabumi Nagai, Kenji Adachi, Kentaro Kawai, Kenta Arima, and Mizuho Morita
    • Organizer
      PACIFIC RIM MEETING ON ELECTROCHEMICAL AND SOLID-STATE SCIENCE
    • Place of Presentation
      Honolulu, Hawaii, U.S.A.
    • Related Report
      2012 Research-status Report
  • [Presentation] N-フルオロピリジニウム塩を用いた光エッチングによるシリコンのランダム逆ピラミッドの形成

    • Author(s)
      平野利典,打越純一,大谷真輝,永井隆文,足達健二,川合健太郎,有馬健太,森田瑞穂
    • Organizer
      第60 回応用物理学会春季学術講演会
    • Place of Presentation
      厚木市
    • Related Report
      2012 Research-status Report
  • [Remarks] 先端機器システム領域 研究内容紹介、光エッチングによる3次元形状の創製

    • URL

      http://www-pm.prec.eng.osaka-u.ac.jp/research.html

    • Related Report
      2012 Research-status Report
  • [Remarks] 研究領域紹介、森田研究室(先端機器システム領域)、赤外線でシリコンの平面形状をはかる

    • URL

      http://www.pm.prec.eng.osaka-u.ac.jp/psthomepage/lab/morita/index.html

    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www-pm.prec.eng.osaka-u.ac.jp/research.html

    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] エッチング方法2012

    • Inventor(s)
      森田瑞穂、打越純一、塚本健太郎、 大谷真輝、永井孝文、足達健二
    • Industrial Property Rights Holder
      国立大学法人大阪大学、ダイキン工業
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-044861
    • Filing Date
      2012-02-29
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] エッチング方法2012

    • Inventor(s)
      森田瑞穂、打越純一、塚本健太郎、大谷真輝、永井隆文、足達健二
    • Industrial Property Rights Holder
      国立大学法人大阪大学、ダイキン工業
    • Industrial Property Number
      2012-044861
    • Filing Date
      2012
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] エッチング方法2011

    • Inventor(s)
      森田瑞穂、打越純一、塚本健太郎、 永井孝文、足達健二
    • Industrial Property Rights Holder
      国立大学法人大阪大学、ダイキン工業
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2011-264131
    • Filing Date
      2011-12-01
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] エッチング方法2011

    • Inventor(s)
      森田瑞穂、打越純一、塚本健太郎、永井隆文、足達健二
    • Industrial Property Rights Holder
      国立大学法人大阪大学、ダイキン工業
    • Industrial Property Number
      2011-264131
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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