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The fabrication of the novel semiconducting material for solar cells which does not use a rare metal

Research Project

Project/Area Number 23560357
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionGunma University

Principal Investigator

OZAKI Shunji  群馬大学, 理工学研究科, 准教授 (80302454)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords多元化合物半導体結晶成長
Research Abstract

The quaternary semiconductor Cu2ZnSnSe4 and Cu2ZnSnS4 crystals were grown by the vertical Bridgman method. Optical absorption measurements indicate that both Cu2ZnSnSe4 and Cu2ZnSnS4 are direct-gap semiconductors, and having the band gap energies of 1.12 and 1.48 eV at 10 K, respectively. The thermoreflectance spectra reveal distinct structures at energies of the E0-E6 critical points (CP's). From the first-principle band-structure calculations, these CP's are assigned to specific points in the Brillouin zone.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (28 results)

All 2014 2013 2012 2011 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (23 results)

  • [Journal Article] Photomodulated transmittance spectroscopy of vacuum-evaporated AgGaTe2 films2014

    • Author(s)
      S. Ozaki and T. Ogura
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 5S1 Pages: 05FW02-05FW02

    • DOI

      10.7567/jjap.53.05fw02

    • NAID

      210000143908

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Positive temperature variation of the bandgap energy in the single-crystalline chalcopyrite semiconductor AgInS22014

    • Author(s)
      S. Ozaki and Y. Horikoshi
    • Journal Title

      J. Appl. Phys.

      Volume: 115 Issue: 5

    • DOI

      10.1063/1.4864423

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optical absorption and photoreflectance spectroscopy of the single-crystalline chalcopyrite semiconductor AgGaSe22013

    • Author(s)
      T. Hori and S. Ozaki
    • Journal Title

      J. Appl. Phys.

      Volume: 113 Issue: 17

    • DOI

      10.1063/1.4803892

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optical properties and electronic band structure of Cu_2ZnSnSe_4 kesterite semiconductor2012

    • Author(s)
      S. Ozaki and T. Namba
    • Journal Title

      Physica status solidi (c)

      Volume: 9 Issue: 12 Pages: 2403-2406

    • DOI

      10.1002/pssc.201200203

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optical properties and electronic band structure of Cu2ZnSnSe4 kesterite semiconductor2012

    • Author(s)
      S. Ozaki and T. Namba
    • Journal Title

      Physica status solidi (c)

      Volume: 9 Pages: 2403-2406

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] AgInS_2半導体バンドギャップエネルギーの正の温度変化2014

    • Author(s)
      尾崎俊二, 堀越義道
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2014-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Positive Temperature Variation of the Bandgap Energy in AgInS_2 Chalcopyrite Semiconductor2013

    • Author(s)
      S. Ozaki and Y. Horikoshi
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2013-12-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal Growth and Optical Properties of Cu_2ZnSnS_42013

    • Author(s)
      K. Hoshina and S. Ozaki
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2013-12-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal growth and optical properties of Cu_2SnSe_4 semiconductor2013

    • Author(s)
      T. Sekiya and S. Ozaki
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2013-12-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal Growth and Optical Properties of Chalcopyrite Semiconductor AgGaS_22013

    • Author(s)
      T. Onodera and S. Ozaki
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2013-12-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical Properties of Vacuum Evaporated AgGaTe_2 Thin Films2013

    • Author(s)
      S. Ozaki and T. Ogura
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2013-09-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Cu_2ZnSnS_4半導体結晶の育成と光学特性及びバンド構造評価2013

    • Author(s)
      保科慧治, 尾崎俊二
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] AgGaS_2半導体のバンドギャップエネルギーの特異な温度依存性2013

    • Author(s)
      小野寺翼, 尾崎俊二
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2013-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] Cu2ZnSnS4半導体結晶の育成と光学特性及びバンド構造評価2013

    • Author(s)
      保科慧治, 尾崎俊二
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Related Report
      2012 Research-status Report
  • [Presentation] Optical Properties of AgGaTe_2 Films2012

    • Author(s)
      S. Ozaki and T. Ogura
    • Organizer
      4th International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2012-12-07
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical properties of chalcopyrite semiconductor AgInS_22012

    • Author(s)
      Y. Horikoshi and S. Ozaki
    • Organizer
      4th International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2012-12-07
    • Related Report
      2013 Final Research Report
  • [Presentation] AgInS_2半導体結晶の育成と光学特性2012

    • Author(s)
      堀越義道, 尾崎俊二
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Year and Date
      2012-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical Properties and Electronic Band Structure of Cu_2ZnSnSe_4 Kesterite Semiconductor2012

    • Author(s)
      S. Ozaki and T. Namba
    • Organizer
      International Conference on Optical and Optoelectronic Properties of Materials and Applications
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2012-06-03
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical Properties and Electronic Band Structure of Cu2ZnSnSe4 Kesterite Semiconductor2012

    • Author(s)
      S. Ozaki and T. Namba
    • Organizer
      International Conference on Optical and Optoelectronic Properties of Materials and Applications
    • Place of Presentation
      Nara, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Crystal Growth and Optical Properties of Chalcopyrite Semiconductor AgInS_22011

    • Author(s)
      Y. Horikoshi and S. Ozaki
    • Organizer
      3^<rd> International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2011-12-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical Properties and Electronic Band Structure of Cu_2ZnSnSe_42011

    • Author(s)
      S. Ozaki and T. Namba
    • Organizer
      3^<rd> International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Japan
    • Year and Date
      2011-12-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Optical Properties and Electronic Band Structure of Cu2ZnSnSe42011

    • Author(s)
      S. Ozaki and T. Namba
    • Organizer
      3rd International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu City Performing Arts Center, Kiryu, Japan
    • Related Report
      2011 Research-status Report
  • [Presentation] AgInS2半導体バンドギャップエネルギーの正の温度変化

    • Author(s)
      尾崎俊二, 堀越義道
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県相模原市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Positive Temperature Variation of the Bandgap Energy in AgInS2 Chalcopyrite Semiconductor

    • Author(s)
      S. Ozaki and Y. Horikoshi
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Gunma
    • Related Report
      2013 Annual Research Report
  • [Presentation] Crystal Growth and Optical Properties of Cu2ZnSnS4

    • Author(s)
      K. Hoshina and S. Ozaki
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Gunma
    • Related Report
      2013 Annual Research Report
  • [Presentation] Crystal growth and optical properties of Cu2SnSe4 semiconductor

    • Author(s)
      T. Sekiya and S. Ozaki
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Gunma
    • Related Report
      2013 Annual Research Report
  • [Presentation] Crystal Growth and Optical Properties of Chalcopyrite Semiconductor AgGaS2

    • Author(s)
      T. Onodera and S. Ozaki
    • Organizer
      5h International Conference on Advanced Micro-Device Engineering
    • Place of Presentation
      Kiryu, Gunma
    • Related Report
      2013 Annual Research Report
  • [Presentation] Optical Properties of Vacuum Evaporated AgGaTe2 Thin Films

    • Author(s)
      S. Ozaki and T. Ogura
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Tanabe, Kyoto
    • Related Report
      2013 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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