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Development of new electro-advanced oxidation processes reusing resources in wastewater

Research Project

Project/Area Number 23560655
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Civil and environmental engineering
Research InstitutionRyukoku University

Principal Investigator

KISHIMOTO Naoyuki  龍谷大学, 理工学部, 教授 (00293895)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords促進酸化処理 / 電解フェントン型処理 / 水酸基ラジカル / 電解処理 / 次亜塩素酸 / 鉄 / Fenton / 電解促進酸化処理
Research Abstract

The conventional advanced oxidation processes (AOPs) have defects of high costs of special apparatus and/or heavy chemicals management. Accordingly, new AOPs, namely the electrochemical Fenton-type process (E-Fenton) and the electrolytic hypochlorous acid-hydrogen peroxide process (E-HOCl/H2O2), were developed in this research, in which chloride ion in wastewater was catalytically reused.
Effects of several operational parameters like current density and linear velocity on the performance of E-Fenton were evaluated, and the reusability of iron sludge was discussed. Consequently, E-Fenton was established as a new AOP requiring lower chemicals cost than the conventional one.
The availability of seawater as a chloride ion source for E-HOCl/H2O2 was demonstrated, and finally this process was proved to function well as a new AOP under neutral pH without sludge production.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (16 results)

All 2013 2012

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (12 results) Book (2 results)

  • [Journal Article] Reusability of iron sludge as an iron source for the electrochemical Fenton-type process using Fe2+/HOCl system2013

    • Author(s)
      Naoyuki KISHIMOTO, Takuya KITAMURA, Masaaki KATO, Hideo OTSU
    • Journal Title

      Water Research

      Volume: 47 Issue: 5 Pages: 1919-1927

    • DOI

      10.1016/j.watres.2013.01.021

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of chelating agents on Fenton-type reaction using ferrous ion and hypochlorous acid2013

    • Author(s)
      Naoyuki Kishimoto, Takuya Kitamura, Masaaki Kato, Hideo Otsu
    • Journal Title

      Journal of Water and Environment Technology

      Volume: Vol.11 Pages: 21-32

    • NAID

      130003363005

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 次亜塩素酸を用いた新しいFenton法による難分解性有機物の分解2013

    • Author(s)
      川口理恵,加藤昌明,大津秀緒,岸本直之
    • Organizer
      第37回電解技術討論会
    • Place of Presentation
      大阪府立大学
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 電気化学的促進酸化処理の今後の展開2013

    • Author(s)
      岸本直之
    • Organizer
      第16回日本水環境学会シンポジウム
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Fe^2+/HOCl反応系を用いた電解Fenton型プロセスの処理条件とORPの関係2013

    • Author(s)
      中村優,岸本直之,加藤昌明,大津秀緒
    • Organizer
      第47回日本水環境学会年会
    • Place of Presentation
      大阪工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 過酸化水素と次亜塩素酸を用いた電解促進酸化処理の影響因子2013

    • Author(s)
      渡部宏典,岸本直之
    • Organizer
      第47回日本水環境学会年会
    • Place of Presentation
      大阪工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 過酸化水素と次亜塩素酸を用いた電解促進酸化処理の影響因子2013

    • Author(s)
      渡部宏典,岸本直之
    • Organizer
      第47回日本水環境学会年会
    • Place of Presentation
      大阪工業大学大宮キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Fe2+/HOCl反応系を用いた電解Fenton型プロセスの処理条件とORPの関係2013

    • Author(s)
      中村優,岸本直之,加藤昌明,大津秀緒
    • Organizer
      第47回日本水環境学会年会
    • Place of Presentation
      大阪工業大学大宮キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Fe^2+/HOCl反応系を用いたフローセル型電解Fenton反応器の運転操作因子の評価2012

    • Author(s)
      中村優,岸本直之,加藤昌明,大津秀緒
    • Organizer
      第12回環境技術学会年次大会
    • Place of Presentation
      立命館大学
    • Year and Date
      2012-09-03
    • Related Report
      2013 Final Research Report
  • [Presentation] Fe^2+/HOCl反応系を用いた電解フローセルの電解特性2012

    • Author(s)
      中村優,岸本直之,加藤昌明,大津秀緒
    • Organizer
      第46回日本水環境学会年会
    • Place of Presentation
      北海道大学
    • Year and Date
      2012-03-14
    • Related Report
      2013 Final Research Report
  • [Presentation] 過酸化水素の電解生成における影響因子の検討2012

    • Author(s)
      渡部宏典,岸本直之
    • Organizer
      第46回日本水環境学会年会
    • Place of Presentation
      北海道大学
    • Year and Date
      2012-03-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Fe2+/HOCl反応系を用いたフローセル型電解Fenton反応器の運転操作因子の評価2012

    • Author(s)
      中村優,岸本直之,加藤昌明,大津秀緒
    • Organizer
      第12回環境技術学会年次大会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] 過酸化水素の電解生成における影響因子の検討2012

    • Author(s)
      渡部宏典,岸本直之
    • Organizer
      日本水環境学会
    • Place of Presentation
      第46回日本水環境学会年会
    • Related Report
      2011 Research-status Report
  • [Presentation] Fe2+/HOCl反応系を用いた電解フローセルの電解特性2012

    • Author(s)
      中村優,岸本直之,加藤昌明,大津秀緒
    • Organizer
      日本水環境学会
    • Place of Presentation
      第46回日本水環境学会年会
    • Related Report
      2011 Research-status Report
  • [Book] 排水・汚水処理技術集成vol.22013

    • Author(s)
      岸本直之
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2013 Final Research Report
  • [Book] 排水・汚水処理技術集成 vol.2 (pp.249-275)2013

    • Author(s)
      岸本直之
    • Total Pages
      408
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2013 Annual Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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