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A study on the generation of new carbon materials by piling up non-equilibrium conditions with defects

Research Project

Project/Area Number 23560787
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical properties of metals
Research InstitutionHyogo University of Teacher Education

Principal Investigator

NIWASE Keisuke  兵庫教育大学, 学校教育研究科(研究院), 教授 (50198545)

Co-Investigator(Renkei-kenkyūsha) ATOU Toshiyuki  東京工業大学, 応用セラミックス研究所, 准教授 (40241567)
NAGAI Yasuyoshi  東北大学, 金属材料研究所, 教授 (10302209)
SATOU Youhei  東北大学, 多元物質科学研究所, 助教 (70455856)
TACHIBANA Masaru  横浜市立大学, 国際総合科学研究科, 教授 (80236546)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsダイヤモンド / 黒鉛 / 衝撃圧縮 / 照射 / アモルファス / 変換 / ラマン分光法 / 欠陥 / アモルファスダイヤモンド / 中性子照射 / 格子欠陥
Research Abstract

Previously, we have discovered transformation from neutron-irradiated highly oriented pyrolytic graphite (HOPG) to amorphous diamond under shock compression. Here, we show the band gap energy of amorphous diamond is estimated to be 4 eV, which is similar to the value reported for the amorphous diamond synthesized from C60 fullerene by shock compression. In addition, we utilized HOPG foils irradiated with a neutron dose of about a half of the previous study, and found the transformation to the amorphous diamond. Also, we reported the synthesis of transparent graphitic tiles from carbon nanowalls by shock compression. It was suggested that the transparent tile is a mixture of amorphous diamond and superhard graphitic material.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (38 results)

All 2014 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (30 results)

  • [Journal Article] High energ,y-resolution electron energy-loss spectroscopy and soft-x-ray emission spectroscopy studies of amorphous diamond transformed from neutron-irradiated graphite2014

    • Author(s)
      Y. Sato, M. Terauchi, K. Niwase, K. G. Nakamura, T. Atou and T. Iwata
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 500 Issue: 19 Pages: 5-5

    • DOI

      10.1088/1742-6596/500/19/192013

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transformation of multiwalled carbon nanotubes to amorphous carbon nanorods under ion irradiation2014

    • Author(s)
      S. Honda, R. Tamura, Y. Nosho, A. Tsukagoshi, M. Niibe, M. Terasawa, R. Hirase, H. Izumi, H. Yoshioka, K. Niwase, E. Taguchi, K.-Y. Lee, M. Oura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 2S Pages: 02BD06-02BD06

    • DOI

      10.7567/jjap.53.02bd06

    • NAID

      210000143376

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] High energy-resolution electron energy-loss spectroscopy and soft-x-ray emission spectroscopy studies of amorphous diamond transformed from neutron-irradiated graphite2014

    • Author(s)
      Y Sato, M Terauchi, K Niwase, K G Nakamura, T Atou and T Iwata
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 未定

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic characterization of ion-irradiated multi-layer graphenes2013

    • Author(s)
      A. Tsukagoshi, S. Honda, R. Osugi, H. Okada, M. Niibe, M. Terasawa, R. Hirase, K. Niwase, M. Oura
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B : Beam Interactions with Materials and Atoms

      Volume: 315 Pages: 64-67

    • DOI

      10.1016/j.nimb.2013.04.039

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transparent graphitic tiles synthesized from carbon nanowalls by shock compression and rapid quenching2013

    • Author(s)
      K. Nakamura, T. Atou, K. Niwase, K.G. Nakamura, A. Yoshimura, M. Tanimura, K. Kobayashi, and M. Tachibana
    • Journal Title

      Journal of Applied Physcs

      Volume: 113 Issue: 4 Pages: 44313-44313

    • DOI

      10.1063/1.4789609

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Defect Evolution in Multiwalled Carbon Nanotube Films Irradiated by Ar Ions,2012

    • Author(s)
      S. Honda, S. Nanba, Y. Hasegawa, Y. Nosho, A.Tsukagoshi, M. Niibe, M. Terasawa, R. Hirase, H. Izumi, H., Yoshioka, K. Lee, K. Niwase, E. Taguchi, M. Oura
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 51 Issue: 11R Pages: 110202-110204

    • DOI

      10.1143/jjap.51.110202

    • NAID

      210000141553

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Dose and Pressure on the Transformation from Neutron-Irradiated Graphite to Amorphous Diamond2012

    • Author(s)
      K. Niwase, T Atou, K G Nakamura, and T. Iwata
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 377 Pages: 012026-012026

    • DOI

      10.1088/1742-6596/377/1/012026

    • NAID

      120004702818

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Raman Spectroscopy for Quantitative Analysis of Point Defects and Defect Clusters in Irradiated Graphite2012

    • Author(s)
      K. Niwase
    • Journal Title

      International Journal of Spectroscopy

      Volume: 2012 Pages: 1-14

    • DOI

      10.1155/2012/197609

    • NAID

      120003779742

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 熱衝撃を受けた黒鉛の結晶化と照射効果2014

    • Author(s)
      庭瀬敬右、平井武志、J. Compan、J. Linke
    • Organizer
      日本物理学会春季講演大会
    • Place of Presentation
      東海大学(神奈川湘南)
    • Year and Date
      2014-03-30
    • Related Report
      2013 Final Research Report
  • [Presentation] 熱衝撃を受けた黒鉛の結晶化と照射効果2014

    • Author(s)
      庭瀬敬右、平井武志、J. Compan、J. Linke
    • Organizer
      日本物理学会
    • Place of Presentation
      東海大(神奈川湘南)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 強照射された黒鉛の熱衝撃と照射損傷による構造変化2013

    • Author(s)
      庭瀬敬右、平井武志、J. Compan、J. Linke
    • Organizer
      日本金属学会秋季講演大会
    • Place of Presentation
      金沢大学(金沢)
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Arイオン照射された多層カーボンナノチューブの構造変化2013

    • Author(s)
      本多信一、納庄裕介、塚越旭、新部正人、寺澤倫孝、平瀬龍二、吉岡秀樹、泉宏和、庭瀬敬右、田口英次、和賀井達也、大浦正樹
    • Organizer
      日本金属学会春季講演大会
    • Place of Presentation
      東京理科大(東京)
    • Year and Date
      2013-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 衝撃圧縮によってカーボンナノウォールから生成された透明グラファイトタイル2013

    • Author(s)
      中村和貴、阿藤敏行、庭瀬敬右、中村一隆、橘勝
    • Organizer
      第44回フラーレン・カーボンナノチューブシンポジウム
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2013-03-11
    • Related Report
      2013 Final Research Report
  • [Presentation] 強照射された黒鉛の熱衝撃と照射損傷による構造変化2013

    • Author(s)
      庭瀬敬右、平井武志、J. Compan、J. Linke
    • Organizer
      日本金属学会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 軟X線吸収分光法によるイオン照射多層グラフェンの構造・電子状態評価2013

    • Author(s)
      武田 昴之,塚越 旭,本多 信一,新部 正人,寺澤 倫孝,平瀬 龍二,吉岡 秀樹,泉 宏和,庭瀬 敬右,田口 英次,和賀井 達也,大浦 正樹
    • Organizer
      先端技術セミナー
    • Place of Presentation
      イーグレひめじ
    • Related Report
      2012 Research-status Report
  • [Presentation] 中性子照射と衝撃圧縮の重畳による黒鉛のアモルファスダイヤモンドへの直接変換2012

    • Author(s)
      庭瀬敬右、中村一隆、阿藤敏行、岩田忠夫
    • Organizer
      日本物理学会秋季講演大会
    • Place of Presentation
      横浜国立大学(横浜)
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] イオン照射多層グラフェンの分光学的評価2012

    • Author(s)
      塚越旭、大杉僚、岡田拓、本多信一、新部正人、寺澤倫孝、庭瀬敬右、田口英次、平瀬龍二、吉岡秀樹、泉宏和、和賀井達也、大浦正樹
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学(松山)
    • Year and Date
      2012-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] 多価イオン照射垂直配向多層カーボンナノチューブの分光学的評価」"2012

    • Author(s)
      本多信一、新部正人、寺澤倫孝、庭瀬敬右,田口英次、平瀬龍二、吉岡秀樹、泉宏和、和賀井達也、大浦正樹
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学(松山)
    • Year and Date
      2012-09-11
    • Related Report
      2013 Final Research Report
  • [Presentation] プラズマ曝露によって黒鉛中に生成された欠陥のラマン分光法による同定2012

    • Author(s)
      庭瀬敬右、平井武志、J. Compan、J. Linke
    • Organizer
      日本金属学会春期講演大会
    • Place of Presentation
      横浜国立大学(横浜)
    • Year and Date
      2012-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 中性子照射された黒鉛の衝撃圧縮によるアモルファスダイヤモンド変換に及ぼす照射量および圧力の影響2011

    • Author(s)
      庭瀬敬右、阿藤敏行、中村一隆、岩田忠夫
    • Organizer
      日本金属学会
    • Place of Presentation
      日本金属学会秋期講演大会沖縄コンベンションセンター(那覇)
    • Year and Date
      2011-11-19
    • Related Report
      2013 Final Research Report
  • [Presentation] TEM-EELS/XESによるアモルファスダイヤモンドの電子構造の研究2011

    • Author(s)
      佐藤庸平、寺内正己、庭瀬敬右、中村一隆、岩田忠夫
    • Organizer
      日本物理学会秋季講演大会
    • Place of Presentation
      富山大学(富山)
    • Year and Date
      2011-09-22
    • Related Report
      2013 Final Research Report
  • [Presentation] ナノカーボン材料の破壊と創製を誘発する格子欠陥の役割2011

    • Author(s)
      庭瀬敬右
    • Organizer
      第21回格子欠陥フォーラム
    • Place of Presentation
      立山国際ホテル(富山)
    • Year and Date
      2011-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of Dose and Pressure on the Transformation from Neutron-Irradiated Graphite to Amorphous Diamond2011

    • Author(s)
      K. Niwase, T. Atou, K. G. Nakamura, M. T. Iwata
    • Organizer
      AIRAPT-23
    • Place of Presentation
      ムンバイ
    • Related Report
      2011 Research-status Report
  • [Presentation] ナノカーボン材料の破壊と創製を誘発する格子欠陥の役割2011

    • Author(s)
      庭瀬敬右
    • Organizer
      日本物理学会 格子欠陥フォーラム(招待講演)
    • Place of Presentation
      富山
    • Related Report
      2011 Research-status Report
  • [Presentation] TEM-EELS/XESによるアモルファスダイヤモンドの電子構造の研究2011

    • Author(s)
      佐藤庸平、寺内正己、庭瀬敬右、中村一隆、岩田忠夫
    • Organizer
      日本物理学会
    • Place of Presentation
      富山
    • Related Report
      2011 Research-status Report
  • [Presentation] 中性子照射された黒鉛の衝撃圧縮によるアモルファスダイヤモンド変換に及ぼす照射量および圧力の影響2011

    • Author(s)
      庭瀬敬右、阿藤敏行、中村一隆、岩田忠夫
    • Organizer
      日本金属学会
    • Place of Presentation
      沖縄
    • Related Report
      2011 Research-status Report
  • [Presentation] SYNTHESIS OF AMORPHOIUS DIAMOND FROM NEUTRON-IRRADIATED GRAPHITE

    • Author(s)
      K. Niwase, T. Atou, K.G. Nakamura, and T. Iwata
    • Organizer
      Nano 2012
    • Place of Presentation
      Rhodes, Greece
    • Related Report
      2012 Research-status Report
  • [Presentation] Electronic Structure of Multi-walled Carbon Nanotubes Irradiated by Multiply Charged Ar Ions

    • Author(s)
      S.Honda, Y.Nosho, A.Tsukagoshi, S.Miyamoto, M.Niibe, M.Terasawa, T.Tokushima, Y.Horikawa, R.Hirase, H.Yoshioka, H.Izumi, K.Niwase, E.Taguchi, K,-Y.Lee, and M.Oura
    • Organizer
      12th International Conference on Electronic Spectroscopy and Structure (ICESS 2012),
    • Place of Presentation
      Sait-Malo, France
    • Related Report
      2012 Research-status Report
  • [Presentation] Spectroscopic Characterization of Ion-irradiated Multi-layer Graphenes

    • Author(s)
      A.Tsukagoshi, R.Osugi, H.Okada, S.Honda, M.Niibe, M.Terasawa, R.Hirase, H.Yoshioka, H.Izumi, K.Niwase, E.Taguchi, K.-Y.Lee, and M.Oura
    • Organizer
      25th International Conference on Atomic Collisions in Solids & 8th International Symposium on Swift Heavy Ions on Matter (ICACS-25 & SHIM2012)
    • Place of Presentation
      Kyoto
    • Related Report
      2012 Research-status Report
  • [Presentation] Change of Diameter of Multi-walled Carbon Nanotubes by Multiply Charged Ar Ion Irradiation

    • Author(s)
      S.Honda, Y.Nosho, A.Tsukagoshi, H.Okada, M.Niibe, M.Terasawa, R.Hirase, H.Yoshioka, H.Izumi, K.Niwase, E.Taguchi, K,-Y.Lee, and M.Oura
    • Organizer
      25th International Conference on Atomic Collisions in Solids & 8th International Symposium on Swift Heavy Ions on Matter (ICACS-25 & SHIM2012)
    • Place of Presentation
      Kyoto
    • Related Report
      2012 Research-status Report
  • [Presentation] Analysis of the C 1s X-ray Photoelectron Spectrum and the C K X-ray Emission Spectrum of Multi-walled Carbon Nanotubes Irradiated by Multiply Charged Ar Ions

    • Author(s)
      S.Honda, Y.Nosho, A. Tsukagoshi, S.Miyamoto, M.Niibe, M.Terasawa, T.Tokushima, Y.Horikawa, R.Hirase, H.Yoshioka, H.Izumi, K.Niwase, E.Taguchi, K,-Y.Lee, and M.Oura
    • Organizer
      25th International Conference on Atomic Collisions in Solids & 8th International Symposium on Swift Heavy Ions on Matter (ICACS-25 & SHIM2012)
    • Place of Presentation
      Kyoto
    • Related Report
      2012 Research-status Report
  • [Presentation] Raman and X-ray Absorption Spectroscopic Study on Defects in Vertically Aligned Multi-walled Carbon Nanotubes irradiated with Ar ions

    • Author(s)
      S.Honda, Y.Nosho, A.Tsukagoshi, R.Mukouda, M.Niibe, M.Terasawa, R.Hirase, H.Yoshioka, H.Izumi, K.Niwase, E.Taguchi, K,-Y.Le
    • Organizer
      25th International Conference on Atomic Collisions in Solids & 8th International Symposium on Swift Heavy Ions on Matter (ICACS-25 & SHIM2012)
    • Place of Presentation
      Kyoto
    • Related Report
      2012 Research-status Report
  • [Presentation] 中性子照射と衝撃圧縮の重畳による黒鉛のアモルファスダイヤモンドへの直接変換

    • Author(s)
      庭瀬敬右,中村一隆,阿藤敏行,岩田忠夫
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大
    • Related Report
      2012 Research-status Report
  • [Presentation] 多価イオン照射垂直配向多層カーボンナノチューブの分光学的評価

    • Author(s)
      本多 信一,納庄 裕介,塚越 旭,岡田 拓,本多 信一,新部 正人,寺澤 倫孝,庭瀬 敬右,田口 英次,平瀬 龍二,吉岡 秀樹,泉 宏和,和賀井 達也,大浦 正樹
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Research-status Report
  • [Presentation] イオン照射多層グラフェンの分光学的評価

    • Author(s)
      塚越 旭,大杉僚,岡田 拓,本多 信一,新部 正人,寺澤倫孝,庭瀬敬右,田口英次,平瀬 龍二,吉岡秀樹,泉 宏和,和賀井 達也,大浦正樹
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 衝撃圧縮によってカーボンナノウォールから生成された透明グラファイトタイル

    • Author(s)
      中村和貴、阿藤敏行、庭瀬敬右、中村一隆、橘勝
    • Organizer
      第44回フラーレン・カーボンナノチューブシンポジウム
    • Place of Presentation
      東京大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Arイオン照射された多層カーボンナノチューブの構造変化

    • Author(s)
      本多 信一,納庄 裕介,塚越 旭,新部 正人,寺澤 倫孝,平瀬 龍二,吉岡 秀樹,泉 宏和,庭瀬 敬右,田口 英次,和賀井 達也,大浦 正樹
    • Organizer
      日本金属学会年春期大会
    • Place of Presentation
      東京理科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] プラズマ曝露によって黒鉛中に生成された欠陥のラマン分光法による同定

    • Author(s)
      庭瀬敬右、平井武志J. Compan, J. Linke
    • Organizer
      日本金属学会
    • Place of Presentation
      横浜
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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