• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of high performance emitters for TPV power generator using eutectic materials formed from amorphous materials

Research Project

Project/Area Number 23560799
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionChiba University

Principal Investigator

KAKEGAWA Kazuyuki  千葉大学, 工学(系)研究科(研究院), 教授 (50009693)

Co-Investigator(Kenkyū-buntansha) UEKAWA Naofumi  千葉大学, 大学院工学研究科, 准教授 (60282448)
KOJIMA Takashi  千葉大学, 大学院工学研究科, 准教授 (70333896)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
KeywordsTPV発電 / 非晶体 / 共晶組織 / 超急冷 / 湿式 / SPS / 湿式法 / エルビア / アルミナ / 酸化サマリウム / 酸化ディスプロシウム / エミッタ材料 / 共晶 / 湿式合成 / SPS焼結
Research Abstract

Thermophotovoltaic system generates electricity by applying an infrared radiation from a heated emitter to TPV cell. Emitters are required to radiate infrared having wave lengths of 1-2 micro meters. Previous studies used Al2O3-ER2O3 (ER: rare earth elements) eutectic systems. In these systems, when the composition departs from the eutectic composition, inhomogeneous primary crystals form. This study succeeded to fabricate emitters by a crystallization of amorphous materials. This method enabled to form a structure in which two components homogeneously entangle each other, even when the composition departs from the eutectic composition. Using this method, expensive rare earth could be reduced without deteriorating the generation performance. While the main method to form amorphous materials was rapid quenching, wet methods were also developed. These methods could fabricate amorphous materials with high productivity.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (59 results)

All 2014 2013 2012 2011 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (38 results) (of which Invited: 8 results) Remarks (1 results)

  • [Journal Article] Synthesis of Ce3+-doped Y3Al5O12 phosphor particles by precipitation method with diamine molecules as precipitating agent2014

    • Author(s)
      N.Uekawa, Y.Hokawa, C.M.Wen, T.Kojima
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 122 Pages: 54-57

    • NAID

      130004950908

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Homogeneously Entangled Microstruc- ture in Al2O3-YAG-ZrO2 Ternary System by Crystallization of Rapid-Quenched Film Having an Off-Eutctic Composition2013

    • Author(s)
      D.Toyama, T.Makino, N.Uekawa, T.Kojima, Y.Han, K.Kakegawa
    • Journal Title

      J. Soc. Inorg. Mater. Japan

      Volume: 20 Pages: 266-274

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Homogeneously Entangled Microstructure in Al2O3-YAG-ZrO2 Ternary System by Crystallization of Rapid-Quenched Film Having an Off-Eutctic Composition2013

    • Author(s)
      D.Toyama, T.Makino, N.Uekawa, T.Kojima, Y.Han, K.Kakegawa
    • Journal Title

      J. Soc. Inorg. Mater. Japan

      Volume: 20 Pages: 266-274

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of ZnO sols by low-temperature heating of ethylene glycol solution and control of their photoluminescence with addition of glucose2013

    • Author(s)
      N.Uekawa, T.Fujino, T.Kojima, K.Kakegawa
    • Journal Title

      J. Ceram. Coc. Jpn.

      Volume: 121 Pages: 62-67

    • NAID

      130004950783

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 高圧PECSダイの検討とこれによるチタン酸バリウム鉛の焼結2013

    • Author(s)
      掛川一幸,鳥居翔平,Young Hwan Han, 上川直文,小島隆
    • Journal Title

      J.Soc.Inorn.Mat.Japan

      Volume: 20

    • NAID

      10031151953

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] HR-TEM and FIB-SEM characterization of formation of eutec- tic-like structure from amourphous GdA- lO3-Al2O3 system2012

    • Author(s)
      Y.Han, Y.Harada, J.Shackelford, J.Lee, K.Kakegawa
    • Journal Title

      Trans.Nonferrous Met. Soc. China

      Volume: 22

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] For- mation of Ultra-Fine Eutectic-Like Micro- structure in YAG-Al2O3 Ternary System by crystallization from Amorphous Film2012

    • Author(s)
      D.Toyama, T.Makino, N.Uekawa, T.Kojima, Y.Han, K.Kakegawa
    • Journal Title

      J.Soc.Inorg.Mater.Japan

      Volume: 19 Pages: 170-174

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Ce-TZP/Ba hexaaluminate composites using amorphous precursor of the second phase2012

    • Author(s)
      S.Oori, T.Kojima, T.Hara, N.Uekawa, K.Kakegawa
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 120 Pages: 111-115

    • NAID

      130002067596

    • Related Report
      2012 Research-status Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of Titanium Oxide Nanoparticles Obtained by Hydrolysis Reaction of Ethylene Glycol Solution of Alkoxide2012

    • Author(s)
      N.Uekawa, N.Endo, K.Ishii, T.Kojima, K.Kakegawa
    • Journal Title

      J. Nanotech.

      Volume: 2012

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of oriented zinc oxide thin films by firing Zn-Al layered double hydroxide thin films2012

    • Author(s)
      N.Uekawa, S.Takahiro, T.Kojima
    • Journal Title

      Mater. Lett.

      Volume: 86 Pages: 125-128

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Formation of Ultra-Fine Eutectic-Like Microstructure in YAG-Al<sub>2</sub>O<sub>3</sub> Ternary System by crystallization from Amorphous Film2012

    • Author(s)
      D.Toyama, T.Makino, N.Uekawa, T.Kojima, Y.Han, K.Kakegawa
    • Journal Title

      J.Soc.Inorg.Mater.Japa

      Volume: 19 Pages: 170-174

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] HR-TEM and FIB-SEM characterization of formation of eutectic-like structure from amourphous GdAlO<sub>3</sub>-Al<sub>2</sub>O<sub>3</sub> system2012

    • Author(s)
      Y.Han, Y.Harada, J.Shackelford, J.Lee, K.Kakegawa
    • Journal Title

      rans.Nonferrous Met. Soc. China

      Volume: 22

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] HR-TEM and FIB-SEM Characterization of the Formation of Eutectic-Like Structure from an Amorphous GdAlO3- Al2O3 System2011

    • Author(s)
      Y.Han, Y.Harada, J.Shackelford, J.Lee, I.Jung, K.Kakegawa, D.Kim
    • Journal Title

      Trans. Nonferrous Met. Soc. China

      Volume: 21 Pages: 703-710

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] SPSの焼結の際のチタン酸ジルコン酸鉛への炭素の滲入2011

    • Author(s)
      掛川,高橋,上川,小島,稲垣
    • Journal Title

      J. Soc. Inorg. Mater. Japan

      Volume: 18 Pages: 63-69

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a stble sol of Mn2+-doped ZnS nonoparticles by low-temperature heating of sulfide precipitate in ethylene glycol2011

    • Author(s)
      N.Uekawa, T.Matsumoto, T.Kojima, K.Kakegawa
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 119 Pages: 346-350

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] カラー画像の白黒印刷の問題点とその解決法2011

    • Author(s)
      掛川
    • Journal Title

      J. Soc. Inorg. Mater. Japan

      Volume: 18 Pages: 161-165

    • NAID

      10028151400

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 文献のグラフの活用2011

    • Author(s)
      掛川
    • Journal Title

      J. Soc. Inorg. Mater. Japan

      Volume: 18 Pages: 225-231

    • NAID

      10028151528

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 面積を求める方法2011

    • Author(s)
      掛川
    • Journal Title

      J. Soc. Inorg. Mater. Japan

      Volume: 18 Pages: 283-287

    • NAID

      10029343065

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of oxides obtained by heating a mixture of peroxoniobic acid and peroxotitanic acid2011

    • Author(s)
      N.Uekawa, Y.Oosawa, Y.Kojima, K.Kakegawa
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 1817-1822

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low Temperature Preparation of Ce-TZP/Ba Hexaaluminate Composites2011

    • Author(s)
      S.Oori, T.Kojima, N.Uekawa, K.Kakegawa
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 119 Pages: 903-908

    • NAID

      130002067665

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] New SPS technique using SiC die2014

    • Author(s)
      K.Kakegawa
    • Organizer
      IWCSB 2014
    • Place of Presentation
      韓国・亀尾
    • Year and Date
      2014-03-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Advanced spark plasma sintering technique using SiC die in Air2014

    • Author(s)
      K.Kakegawa
    • Organizer
      IWCSB 2014
    • Place of Presentation
      Gumi, Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] SPS using SiC die2013

    • Author(s)
      K.Kakegawa, C.M.Wen, N.Uekawa, T.Kojima
    • Organizer
      ISIEM 2013
    • Place of Presentation
      フランス・レンヌ
    • Year and Date
      2013-10-27
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Preparation of Emitter Materials for Photovoltaic Electric Generation2013

    • Author(s)
      K.Kakegawa, H.Kubo, H.Tamagawa, N. Uekawa, T.Kojima
    • Organizer
      ICCPS-12
    • Place of Presentation
      米国・ポートランド
    • Year and Date
      2013-08-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Preparation of Emitter Materials for Photovoltaic Electric Generation2013

    • Author(s)
      K.Kakegawa, H.Kubo, H.Tamagawa, N.Uekawa, T,Kojima
    • Organizer
      ICCPS-12
    • Place of Presentation
      Portland, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] SPS using SiC die2013

    • Author(s)
      K.Kakegawa, C.M.Wen, N.Uekawa, T.Kojima
    • Organizer
      ISIEM 2013
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Synthesis of titanium oxide nanoparticles by using ethylene glycol solution of alkoxide and characterization of their surface by dye adsorption2013

    • Author(s)
      N.Uekawa, K.Ishii, T.Kojima, K.Kakegawa
    • Organizer
      ISIEM 2013
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of titanium oxide sols with peroxide compounds and their application for preparation of highly oriented oxide thin films2013

    • Author(s)
      C.M.Wen, K.Takayama, N.Uekawa, T.Kojima, K.Kakegawa
    • Organizer
      ISIEM 2013
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of Porous Titania by Partial Dissolution of Particle Surface2013

    • Author(s)
      T.Kojima, T.Baba, K.Inamoto, N.Uekawa, K.Kakegawa
    • Organizer
      ISIEM 2013
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Thermophotovoltaic generation system using Al2O3/Er3Al5O12 eutectic ceramics from amorphous phase2013

    • Author(s)
      H.Kubo, K.Furudate, N.Uekawa, T.Kojima, K.Kakegawa
    • Organizer
      ISIEM 2013
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] New SPS Method Using SiC Die2013

    • Author(s)
      K.Kakegawa, T.Kogo, S.Kawamori, K.Kikuchi
    • Organizer
      Thermec 2013
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] 非晶体からの共晶様組織の形成2012

    • Author(s)
      掛川
    • Organizer
      第177回溶融塩委員会(招待講演)
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] ジアミンを用いた沈殿法によるAlドープZnO粒子の調製と物性の検討2012

    • Author(s)
      上川、齋藤、小島、掛川
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都
    • Related Report
      2011 Research-status Report
  • [Presentation] SPSによるZn2TiO4-Zn2SnO4系の組成変動変化2011

    • Author(s)
      鳥居,上川,小島,Young-Hwan Han,掛川一幸
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] Zn(OH)2の糖類共存溶液中での低温加熱処理による蛍光発光性ZnOナノ粒子の合成2011

    • Author(s)
      藤野、上川、小島、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 層状複水酸化物粒子を用いた配向性亜鉛酸化物薄膜調製2011

    • Author(s)
      齋藤、上川、小島、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 針状ベーマイト粒子を用いたアルミナ系多孔体の作製と耐熱性改善2011

    • Author(s)
      真栄田、小島、上川、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 水和チタニアの部分溶出による多孔性チタニア粒子の合成と評価2011

    • Author(s)
      馬場、小島、上川、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 尿素沈殿法による酸化アルミニウム‐酸化ガドリニウム系共晶系セラミックスの作製2011

    • Author(s)
      高橋,上川,小島,稲垣,掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 放電プラズマ焼結法によるチタン酸ジルコン酸鉛の誘電率の温度特性2011

    • Author(s)
      文、上川、小島、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 放電プラズマ焼結と常圧焼結による固溶体反応速度の違い2011

    • Author(s)
      金、上川、小島、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 非晶質前駆体を用いたCe-TZP/BaAl<sub>12</sub>O<sub>19</sub>コンポジットの自己複合化2011

    • Author(s)
      大理、小島、上川、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] 非晶体からのAl2O3-Er3Al5O12共晶の作製とその性質の評価2011

    • Author(s)
      古館、上川、小島、掛川
    • Organizer
      第27回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      千葉
    • Related Report
      2011 Research-status Report
  • [Presentation] New Formation Technique of Eutectic Structures as a Basis of TPV Application2011

    • Author(s)
      K.Kakegawa
    • Organizer
      The 2nd International Symposium on Hybrid Materials and Processing (HyMaP2011)(招待講演)
    • Place of Presentation
      釜山
    • Related Report
      2011 Research-status Report
  • [Presentation] 尿素を用いた沈殿による酸化ガドリニウム-酸化アルミニウム計セラミックスの組織変化2011

    • Author(s)
      高橋,上川,小島,稲垣,掛川
    • Organizer
      無機マテリアル学会第123回学術講演会
    • Place of Presentation
      佐賀
    • Related Report
      2011 Research-status Report
  • [Presentation] アルコキシド法による多孔性チタニア粒子の調製と水熱結晶化2011

    • Author(s)
      小島,馬場,上川,掛川
    • Organizer
      無機マテリアル学会第123回学術講演会
    • Place of Presentation
      佐賀
    • Related Report
      2011 Research-status Report
  • [Presentation] 層状複水酸化物粒子を用いた配向生を有するAl3+ドープZnOの作製2011

    • Author(s)
      上川,齋藤,小島,掛川
    • Organizer
      無機マテリアル学会第123回学術講演会
    • Place of Presentation
      佐賀
    • Related Report
      2011 Research-status Report
  • [Presentation] 常圧焼結とSPSにおける反応速度の違い2011

    • Author(s)
      掛川、金
    • Organizer
      第16回SPS研究会(招待講演)
    • Place of Presentation
      仙台
    • Related Report
      2011 Research-status Report
  • [Presentation] エチレングリコールを溶媒として用いたZnOナノ粒子の合成と糖添加による蛍光発光特性制御

    • Author(s)
      藤野辰哉, 上川直文, 小島隆, 掛川一幸
    • Organizer
      無機マテリアル学会第124回学術講演会
    • Place of Presentation
      船橋
    • Related Report
      2012 Research-status Report
  • [Presentation] 針状ベーマイト粒子の積層によるアルミナ系多孔体の作製

    • Author(s)
      真栄田義樹小島隆上川直文掛川一幸
    • Organizer
      無機マテリアル学会第124回学術講演会
    • Place of Presentation
      船橋
    • Related Report
      2012 Research-status Report
  • [Presentation] アルコキシド法による球場ジルコニア粒子の調製と水熱結晶化

    • Author(s)
      柳原佑哉, 小島隆, 上川直文, 掛川一幸
    • Organizer
      無機マテリアル学会第124回学術講演会
    • Place of Presentation
      船橋
    • Related Report
      2012 Research-status Report
  • [Presentation] ジアミンを用いた水溶液からの沈殿法によるAl-Zn系酸化物薄膜の調製と導電性の検討

    • Author(s)
      上川直文,齋藤貴宏,小島隆,掛川一幸
    • Organizer
      無機マテリアル学会第124回学術講演会
    • Place of Presentation
      船橋
    • Related Report
      2012 Research-status Report
  • [Presentation] Difference of Reaction Rate between SPS and Pressureless Sintering

    • Author(s)
      KakegawaK., JinJiaquing, UekawaN., KojimaT.,
    • Organizer
      STAC-6
    • Place of Presentation
      Yokohama
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Formation of Eutectic Structure for TPV Emitter

    • Author(s)
      KakegawaK., KuboH., FurudateK., KojimaT., UekawaN.,
    • Organizer
      AMEC-8
    • Place of Presentation
      ペナン
    • Related Report
      2012 Research-status Report
  • [Presentation] クエン酸イオン含有水溶液から得たZnS 沈殿の解膠によるゾル合成と蛍光発光特性の検討

    • Author(s)
      大内真弓, 上川直文, 小島隆, 掛川一幸
    • Organizer
      第28回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      浜松
    • Related Report
      2012 Research-status Report
  • [Presentation] Sn2+含有水溶液の大気中撹拌による酸化スズナノ粒子の合成と導電性薄膜作製への応用

    • Author(s)
      佐々木良輔上川直文小島隆掛川一幸
    • Organizer
      第28回日本セラミックス協会関東支部研究発表会
    • Place of Presentation
      浜松
    • Related Report
      2012 Research-status Report
  • [Presentation] Penetration of carbon into lead zirconate-titanete during sintering by SPS and their dielectric properties

    • Author(s)
      Kazuyuki Kakegawa, Yuich Takahashi, Takashi Kojima, Naofumi Uekawa
    • Organizer
      ic-cmtp2
    • Place of Presentation
      Miskolc-Lillafured
    • Related Report
      2012 Research-status Report
  • [Presentation] TPV発電用共晶系エミッタ作製とその特性

    • Author(s)
      掛川一幸, 久保浩之, 古館一成, 小島隆, 上川直文
    • Organizer
      第17回通電焼結研究会
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
    • Invited
  • [Remarks]

    • URL

      http://chem.tf.chiba-u.jp/~kake/index_J.html

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi