Processing of structural controlled ceramics with Nanospace

• Project/Area Number: 23560816
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic materials/Physical properties
• Research Institution: Japan Fine Ceramics Center
• Principal Investigator: IKUHARA Yumi 一般財団法人ファインセラミックスセンター, その他部局等, 研究員 (80450849)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000); Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: 結晶構造 / 組織制御 / ナノ粒子 / 前駆体 / 電子顕微鏡 / シリカ / 金属酸化物 / 微細構造 / ナノ構造 / microstructure

Research Abstract

Synthesis of microporous silica containing uniformly dispersed metal oxide nanoparticles using precursor solution method has been studied and the transformation of the Si-M-O precursor into the composite powder was investigated systematically to determine the formation mechanism of the composite ceramics with nanospace. The relationship between the microstructure of the obtained composite and the gas adsorption property was investigated. Further, it is found that the composites catalytically induce to grow the carbon micro coil and the formation mechanism of the carbon micro coil was studied by transmission electron microscopy.

Research Products

• [Journal Article] Microscopic observation of carbon micro coil (2014)
  • Author(s): K. Fukunaga, Y. H. Ikuhara, R. Yoshida, S. Motojima, Y. Ikuhara
  • Journal Title: Advanced Microscopy and Theoretical Calculations Letters Volume: 4 Pages: 238-239
• [Journal Article] A new hierarchically porous Pd@HSQ monolithic catalyst for Mizoroki–Heck cross-coupling reactions" (2014)
  • Author(s): N. Moitra, A. Matsushima, T. Kamei, K. Kanamori, Y. H. Ikuhara, X. Gao, K. Takeda, Y.Zhu, K. Nakanishi and T. Shimada
  • Journal Title: New J. Chem. Volume: 38 Pages: 1144-1149
• [Journal Article] A new hierarchically porous Pd@HSQ monolithic catalyst for Mizoroki–Heck cross-coupling reactions (2014)
  • Author(s): N. Moitra, A. Matsushima, T. Kamei, K. Kanamori, Y. H. Ikuhara, X. Gao, K. Takeda, Y.Zhu, K. Nakanishi and T. Shimada
  • Journal Title: New Journal of Chemistry Volume: 38 Issue: 3 Pages: 1144-1149
  • DOI: 10.1039/c3nj01433a
  • Peer Reviewed
• [Journal Article] Synthesis and microstructural analysis of homogeneously dispersed nickel nanoparticles in amorphous silica (2012)
  • Author(s): Y. H. Ikuhara, T. Saito, S. Takahashi, Y. Sasaki and T. Hirayama
  • Journal Title: J. Am. Ceram. Soc. Volume: 95 Pages: 524-529
• [Journal Article] Towards one key to one lock : catalyst modified indium oxide nanoparticle thin film sensor array for selective gas detection (2012)
  • Author(s): K. Yao, D. Caruntu, B. Cao, R. Huang, Y. H. Ikuhara C. J. O'Connora and W. Zhou
  • Journal Title: J. Mater. Chem. Volume: 22 Pages: 7308-7313
• [Journal Article] Synthesis and microstructural analysis of homogeneously dispersed nickel nanoparticles in amorphous silica (2012)
  • Author(s): Yumi H. Ikuhara, Tomohiro Saito, Yukichi Sasaki, Seiji Takahashi and Tsukasa Hirayama
  • Journal Title: Journal of American Ceramics Society Volume: 95 Pages: 524-529
  • Peer Reviewed
• [Journal Article] Towards one key to one lock: catalyst modified indium oxide nanoparticle thin film sensor array for selective gas detection (2012)
  • Author(s): Kun Yao , Daniela Caruntu, Sarah Wozny, Rong Huang, Yumi H. Ikuhara, Baobao Cao, Charles J. O'Connor and Weilie Zhou
  • Journal Title: Journal of Materials Chemistry Volume: 22 Pages: 7308-7313
  • Peer Reviewed
• [Presentation] カーボンマイクロコイルのらせん構造メカニズムの検討 (2014)
  • Author(s): 福永啓一,幾原裕美,吉田竜視,元島栖二,幾原雄一
  • Organizer: 日本金属学会2014年春季大会
  • Place of Presentation: 東京理科大学
• [Presentation] Microscopic observation of carbon micro coil (2014)
  • Author(s): K. Fukunaga, Y. H. Ikuhara, R. Yoshida, S. Motojima, Y. Ikuhara
  • Organizer: The 4th International Symposium on Advanced Microscopy and Theoretical Calculations
  • Place of Presentation: アクトシティ浜松
• [Presentation] カーボンマイクロコイルの微細構造解析 (2014)
  • Author(s): 福永啓一,幾原裕美,吉田竜視,元島栖二,幾原雄一
  • Organizer: 日本顕微鏡学会第70回学術講演会
  • Place of Presentation: 幕張メッセ国際会議場
• [Presentation] 金属ドープシリカ多孔質複合体の合成と構造解析 (2014)
  • Author(s): 小出剛之,小林正典,川西美里,幾原裕美
  • Organizer: 日本機械学会
  • Place of Presentation: 東京電機大学
• [Presentation] カーボンマイクロコイルのらせん構造メカニズムの検討 (2014)
  • Author(s): 福永啓一、幾原裕美 吉田竜視 元島栖二 幾原雄一
  • Organizer: 日本金属学会２０１４年春季大会
  • Place of Presentation: 東京理科大学神楽坂キャンパス
• [Presentation] カーボンマイクロコイルの微細構造解析 (2014)
  • Author(s): 福永啓一、幾原裕美 吉田竜視 元島栖二 幾原雄一
  • Organizer: 日本顕微鏡学会第７０回学術講演会
  • Place of Presentation: 幕張メッセ国際会議場
• [Presentation] "カーボンマイクロコイルの微細構造解析" (2013)
  • Author(s): 福永啓一,幾原裕美,元島栖二,幾原雄一
  • Organizer: 日本顕微鏡学会第69回学術講演会
  • Place of Presentation: H阪急エキスポパーク
• [Presentation] "カーボンマイクロコイルの微細構造解析" (2013)
  • Author(s): 福永啓一,幾原裕美,元島栖二,幾原雄一
  • Organizer: 第57回シンポジウム日本顕微鏡学会
  • Place of Presentation: ウインク愛知
• [Presentation] Synthesis and microstructural analysis of metal - nanopartilce dispersed amorphous silica (2012)
  • Author(s): Y. H. Ikuhara, T. Saito, Y. Sasaki, S. Takahashi, T. Hirayama
  • Organizer: 2012 MRS Fall Meeting (Materials Research Society)
  • Place of Presentation: Hynes Convention Center
  • Year and Date: 2012-11-30
• [Presentation] "カーボンマイクロコイル先端触媒の微細構造解析" (2012)
  • Author(s): 福永啓一,幾原裕美,元島栖二,幾原雄一
  • Organizer: 日本顕微鏡学会第68回学術講演会
  • Place of Presentation: つくば国際会議場
• [Presentation] カーボンマイクロコイルの構造解析 (2012)
  • Author(s): 幾原裕美,福永啓一,元島栖二,幾原雄一
  • Organizer: 日本セラミックス協会第25回秋期シンポジウム
  • Place of Presentation: 名古屋大学
• [Presentation] Synthesis and microstructural analysis of metal-nanopartilce dispersed amorphous silica (2012)
  • Author(s): Y. H. Ikuhara, T. Saito, Y. Sasaki, S. Takahashi, T. Hirayama
  • Organizer: 2012 MRS Fall Meeting
  • Place of Presentation: Hynes Convention Center, Boston, USA
• [Presentation] カーボンマイクロコイルの構造解析 (2012)
  • Author(s): 幾原裕美 福永啓一 元島栖二 幾原雄一
  • Organizer: 日本セラミックス協会第２５回秋期シンポジウム
  • Place of Presentation: 名古屋大学
• [Presentation] カーボンマイクロコイル先端触媒の微細構造解析 (2012)
  • Author(s): 福永啓一 幾原裕美 元島栖二 幾原雄一
  • Organizer: 日本顕微鏡学会第６８回学術講演会
  • Place of Presentation: つくば国際会議場
• [Presentation] "カーボンマイクロコイルの構造的特徴" (2011)
  • Author(s): 福永啓一,幾原裕美,元島栖二,幾原雄一
  • Organizer: 日本顕微鏡学会第67回学術講演会
  • Place of Presentation: 福岡国際会議場
• [Presentation] カーボンマイクロコイルの微細構造解析 (2011)
  • Author(s): 幾原裕美,福永啓一,元島栖二,幾原雄一
  • Organizer: 第24回日本セラミックス協会秋季シンポジウム
  • Place of Presentation: 北海道大学
• [Presentation] カーボンマイクロコイルの構造的特徴
  • Author(s): 福永啓一 幾原裕美 元島栖二 幾原雄一
  • Organizer: 日本顕微鏡学会第６７回学術講演会
  • Place of Presentation: 福岡国際会議場
• [Presentation] カーボンマイクロコイルの微細構造解析
  • Author(s): 幾原裕美 福永啓一 元島栖二 幾原雄一
  • Organizer: 第２４回日本セラミックス協会秋季シンポジウム
  • Place of Presentation: 北海道大学