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Fabrication of Conductive Quantum Wire by using Dislocation Array

Research Project

Project/Area Number 23560817
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Composite materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

SAITO Mitsuhiro  東北大学, 原子分子材料科学高等研究機構, 助教 (00510546)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords量子細線 / 電子顕微鏡 / 転位 / 結晶界面 / 粒界 / 界面
Research Abstract

In this work, a conductive quantum wire was fabricated by using high-temperature segregation behavior of a metallic dopant along a dislocation core in an insulating MgO bicrystal grain boundary (GB) and then was characterized by a scanning TEM (STEM) and a first-principle calculation. The STEM image and electron energy loss spectrum (EELS) mapping showed that a structure unit in the MgO GB is formed to compensate lattice mismatch and calcium (Ca) and titanium (Ti) impurities are strongly localized in the GB. The first-principle calculation revealed that the segregated Ti atoms form conductive channels along the GB suggesting semi-conductor like behavior. By using self-segregation behavior along a dislocation core, we demonstrated to fabricate a low dimensional quantum structure with a specific electronic property in an insulating solid crystal.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (11 results)

All 2014 2013 2012 2011

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (8 results)

  • [Journal Article] Selective impurity segregation at a near-Σ5 grain boundary in MgO2014

    • Author(s)
      M. Saito, Z. Wang, and Y. Ikuhara
    • Journal Title

      J. Mater. Sci

      Volume: 49 Issue: 11 Pages: 3956-3961

    • DOI

      10.1007/s10853-014-8016-7

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local atomic structure of a near-sigma 5 tilt grain boundary in MgO2013

    • Author(s)
      Saito, Z. Wang, S. Tsukimoto, and Y. Ikuhara
    • Journal Title

      M, J. Mater. Sci.

      Volume: 48 Issue: 16 Pages: 5470-5474

    • DOI

      10.1007/s10853-013-7340-7

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Atom-resolved imaging of ordered defect superstructures at individual grain boundaries2011

    • Author(s)
      Z.C.Wang, M.Saito, K.P.McKenna, L.Gu, S.Tsukimoto, A.L.Shluger, Y.Ikuhara
    • Journal Title

      NATURE

      Volume: 479 Issue: 7373 Pages: 380-383

    • DOI

      10.1038/nature10593

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Atom-Resolved Imaging of 3D Defect Structure of MgOΣ5 Grain Boundary2013

    • Author(s)
      M. Saito, Z. Wang, L. Gu, C. Chen, and Y. Ikuhara
    • Organizer
      1st East Asia Electron Microscopy Conference (EAMC1)
    • Place of Presentation
      Chongqing, China
    • Year and Date
      2013-10-16
    • Related Report
      2013 Final Research Report
  • [Presentation] Atomic Structure Characterization of MgO Bicrystal Sigma 5 (310)[001] Tilt Grain Boundary2013

    • Author(s)
      M. Saito , Z. Wang, and Y. Ikuhara
    • Organizer
      Intergranular and Interphase Boundaries in Materials (iib2013)
    • Place of Presentation
      Halkidiki, Greece
    • Year and Date
      2013-06-23
    • Related Report
      2013 Final Research Report
  • [Presentation] MgOバイクリスタルNear-Σ5(310)[001]粒界に形成される超構造原子配列の構造解析2013

    • Author(s)
      斎藤光浩、王中長、幾原雄一
    • Organizer
      日本顕微鏡学会
    • Place of Presentation
      大阪
    • Year and Date
      2013-05-22
    • Related Report
      2013 Final Research Report
  • [Presentation] MgOバイクリスタルNear-Σ5(310)[001]粒界に形成される超構造原子配列の構造解析2013

    • Author(s)
      斎藤光浩、王中長、着本享、幾原雄一
    • Organizer
      日本セラミックス協会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2013-03-17
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] MgO双結晶Σ5(310)[001]粒界に自己形成される超構造原子配列の構造解析2012

    • Author(s)
      斎藤光浩、王中長、着本享、幾原雄一
    • Organizer
      日本顕微鏡学会
    • Place of Presentation
      つくば
    • Year and Date
      2012-05-14
    • Related Report
      2013 Final Research Report
  • [Presentation] MgO双結晶Σ5(310)[001]粒界に自己形成される超構造原子配列の構造解析2012

    • Author(s)
      斎藤光浩、王中長、着本享、幾原雄一
    • Organizer
      日本セラミックス協会
    • Place of Presentation
      京都大学
    • Year and Date
      2012-03-19
    • Related Report
      2013 Final Research Report
  • [Presentation] MgO双結晶Σ5(310)[001]粒界に自己形成される超構造原子配列の構造解析2012

    • Author(s)
      斎藤 光浩
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 酸化マグネシウム双結晶における粒界原子構造2011

    • Author(s)
      着本 享
    • Organizer
      日本金属学会 第149回秋季講演会
    • Place of Presentation
      沖縄
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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