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In-situ synthesis of alumina-matrix oxide/oxide composites and performance enhancement by multiple toughening

Research Project

Project/Area Number 23560835
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionTottori University

Principal Investigator

CHEN Zhongchun  鳥取大学, 工学(系)研究科(研究院), 教授 (00282111)

Co-Investigator(Renkei-kenkyūsha) ONDA Tetsuhiko  鳥取大学, 工学研究科, 准教授 (80273879)
AKAO Takahiro  鳥取大学, 工学研究科, 助教 (70335503)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords複合材料 / セラミックス / アルミナ / 反応焼結 / In situ合成 / 組織靱化 / 破壊靱性
Research Abstract

Alumina matrix composites reinforced with barium hexaluminate and zirconia were synthesized in situ through reactive sintering of alumina and barium zirconate powder mixtures. The in-situ synthesized composites exhibited a microstructural feature of the elongated barium hexaluminate and equiaxed zirconia particles. The formation of Ba-beta-Al2O3 phase with an elongated morphology is likely to be attributed to preferred diffusion of Ba cations along the basal planes. The incorporation of TZP or Y2O3 promotes densification of the composites and formation of tetragonal zirconia due to diffusion of yttria to monoclinic zirconia, which is generated through reaction between alumina and barium zirconate during sintering. The synthesized alumina matrix composites showed high fracture toughness, as a result of multiple toughening effects including crack deflection, crack bridging, and martensitic transformation of zirconia from tetragonal to monoclinic phases.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (30 results)

All 2013 2012 2011

All Journal Article (6 results) (of which Peer Reviewed: 4 results) Presentation (24 results) (of which Invited: 7 results)

  • [Journal Article] In-Situ Synthesis of Alumina Matrix Composites by Spark Plasma Sintering2013

    • Author(s)
      Z. Chen, S. Nugroho and A. Kawasaki
    • Journal Title

      Materials Science Forum

      Volume: 750 Pages: 92-95

    • DOI

      10.4028/www.scientific.net/msf.750.92

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of TZP Addition on Microstructure and Mechanical Properties of Alumina-Matrix Composites2013

    • Author(s)
      K. Maeda, M. Ezumi, T. Yamashita, T. Akao, T. Onda and Z. Chen
    • Journal Title

      Proceedings of the 2012 Powder Metallurgy World Congress

      Volume: CD-ROM Pages: 1-6

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstruture and Mechanical Properties of Reactive-Synthesized Alumina-Matrix Composites2013

    • Author(s)
      K. Maeda, T. Akao, T. Onda and Z. Chen
    • Journal Title

      Proceedings of JSMME 2012

      Volume: 4 Pages: 265-272

    • Related Report
      2013 Annual Research Report
  • [Journal Article] In-Situ Synthesis of Alumina-Matrix Oxide/Oxide Composites by Reactive Sintering2012

    • Author(s)
      Z. Chen, S. Nugroho, M. Ezumi, T. Akao and T. Onda
    • Journal Title

      Materials Science and Engineering A

      Volume: 557 Pages: 59-68

    • DOI

      10.1016/j.msea.2012.05.106

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of TZP addition on microstructure and mechanical properties of alumina-matrix composites2012

    • Author(s)
      K. Maeda, M. Ezumi, T. Yamashita, T. Akao, T. Onda and Z.-C. Chen
    • Journal Title

      Proc. of the 2012 Powder Metallurgy World Congress

      Pages: 1-6

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microstruture and mechanical properties of reactive-synthesized alumina-matrix compo- sites2012

    • Author(s)
      K. Maeda, T. Akao, T. Onda and Z.-C. Chen
    • Journal Title

      Proceedings of JSMME 2012

      Pages: 265-272

    • Related Report
      2013 Final Research Report
  • [Presentation] Multiple toughening in in-situ synthesized alumina matrix composites2013

    • Author(s)
      Z.-C. Chen, K. Maeda, T. Onda and T. Akao
    • Organizer
      The 8^<th> International Conference on Processing and Manufacturing of Advanced Materials (THERMEC'2013)
    • Place of Presentation
      Las Vegas, USA.
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] アルミナ基複合材料の組織制御および機械的性質2013

    • Author(s)
      音田哲彦、前田健作、赤尾尚洋、陳中春
    • Organizer
      2013年日本金属学会秋季講演大会
    • Place of Presentation
      金沢大学(金沢市)
    • Related Report
      2013 Final Research Report
  • [Presentation] アルミナ基複合材料の組織や機械的性質に及ぼす金属酸化物添加の影響2013

    • Author(s)
      板倉慧史、赤尾尚洋、音田哲彦、陳中春
    • Organizer
      平成25年日本鉄鋼協会・日本金属学会中国四国支部講演大会
    • Place of Presentation
      愛媛大学(松山市)
    • Related Report
      2013 Final Research Report
  • [Presentation] 反応焼結によるアルミナ系酸化物/酸化物複合材料のIn-situ合成2013

    • Author(s)
      陳中春
    • Organizer
      平成25年粉体粉末冶金協会春季大会
    • Place of Presentation
      早稲田大学(東京都)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] TZPを添加したアルミナ基複合材料におけるマルチ靱化効果2013

    • Author(s)
      前田健作、赤尾尚洋、音田哲彦、陳中春
    • Organizer
      平成25年粉体粉末冶金協会春季大会
    • Place of Presentation
      早稲田大学(東京都)
    • Related Report
      2013 Final Research Report
  • [Presentation] Multiple Toughening in In-situ Synthesized Alumina Matrix Composites2013

    • Author(s)
      Z. Chen, K. Maeda, T. Onda and T. Akao
    • Organizer
      The 8th International Conference on Processing & Manufacturing of Advanced Materials (THERMEC’2013)
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 反応焼結によるアルミナ系酸化物/酸化物複合材料のIn-situ合成2013

    • Author(s)
      陳中春
    • Organizer
      平成25年度粉体粉末冶金協会春季大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] TZPを添加したアルミナ基複合材料におけるマルチ靱化効果2013

    • Author(s)
      前田健作,赤尾尚洋,音田哲彦,陳中春
    • Organizer
      平成25年度粉体粉末冶金協会春季大会
    • Place of Presentation
      早稲田大学(東京)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルミナ基複合材料の組織や機械的性質に及ぼす金属酸化物添加の影響2013

    • Author(s)
      板倉慧史,赤尾尚洋,音田哲彦,陳中春
    • Organizer
      平成25年度日本鉄鋼協会・日本金属学会中国四国支部講演大会
    • Place of Presentation
      愛媛大学(愛媛)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルミナ基複合材料の組織制御および機械的性質2013

    • Author(s)
      音田哲彦,前田健作,赤尾尚洋,陳中春
    • Organizer
      2013年日本金属学会秋季講演大会
    • Place of Presentation
      金沢大学(金沢)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of TZP addition on microstructure and mechanical properties of alumina-matrix composites2012

    • Author(s)
      K. Maeda, M. Ezumi, T. Yamashita, T. Akao, T. Onda and Z.-C. Chen
    • Organizer
      2012 Powder Metallurgy World Congress
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Related Report
      2013 Final Research Report
  • [Presentation] アルミナ基複合材料の反応合成およびマルチ靱化効果2012

    • Author(s)
      前田健作、赤尾尚洋、音田哲彦、陳中春
    • Organizer
      2012年日本金属学会秋季講演大会
    • Place of Presentation
      愛媛大学(松山市)
    • Related Report
      2013 Final Research Report
  • [Presentation] アルミナ基複合材料の反応合成および組織2012

    • Author(s)
      前田健作、赤尾尚洋、音田哲彦、陳中春
    • Organizer
      平成24年日本鉄鋼協会・日本金属学会中国四国支部講演大会
    • Place of Presentation
      鳥取大学(鳥取市)
    • Related Report
      2013 Final Research Report
  • [Presentation] In-situ synthesis of alumina matrix composites by spark plasma sintering2012

    • Author(s)
      Z.-C. Chen, S. Nugroho and A. Kawasaki
    • Organizer
      The 8^<th> International Forum on Advanced Materials Science and Technology
    • Place of Presentation
      福岡工業大学(福岡市)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] In-Situ Synthesis of Alumina Matrix Composites by Spark Plasma Sintering2012

    • Author(s)
      Z. Chen, S. Nugroho and A. Kawasaki
    • Organizer
      The 8th International Forum on Advanced Materials Science and Technology
    • Place of Presentation
      福岡工業大学(福岡)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Effect of TZP Addition on Microstructure and Mechanical Properties of Alumina-Matrix Composites2012

    • Author(s)
      K. Maeda, M. Ezumi, T. Yamashita, T. Akao, T. Onda and Z. Chen
    • Organizer
      2012 Powder Metallurgy World Congress
    • Place of Presentation
      パシフィコ横浜(横浜)
    • Related Report
      2012 Research-status Report
  • [Presentation] アルミナ基複合材料の反応合成およびマルチ靱化効果2012

    • Author(s)
      前田健作、赤尾尚洋、音田哲彦、陳中春
    • Organizer
      2012年日本金属学会秋季講演大会
    • Place of Presentation
      愛媛大学(愛媛)
    • Related Report
      2012 Research-status Report
  • [Presentation] アルミナ基複合材料の反応合成および組織2012

    • Author(s)
      前田健作、赤尾尚洋、音田哲彦、陳中春
    • Organizer
      日本金属学会中国四国支部第52回講演大会
    • Place of Presentation
      鳥取大学(鳥取)
    • Related Report
      2012 Research-status Report
  • [Presentation] In-situ synthesis, microstruc-ture, and mechanical properties of alumina matrix composites2011

    • Author(s)
      Z.-C. Chen
    • Organizer
      Materials Science & Technology 2011 Conference
    • Place of Presentation
      Columbus, USA.
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] アルミナ基複合材料の組織や機械的性質に及ぼすTZP添加の影響2011

    • Author(s)
      江角誠、山下達也、赤尾尚洋、音田哲彦、陳中春
    • Organizer
      平成23年日本鉄鋼協会・日本金属学会中国四国支部講演大会
    • Place of Presentation
      岡山理科大学(岡山市)
    • Related Report
      2013 Final Research Report
  • [Presentation] アルミナ基複合材料の組織と機械的性質に及ぼすTZP添加の影響2011

    • Author(s)
      陳中春、江角誠、山下達也、赤尾尚洋、音田哲彦
    • Organizer
      平成23年粉体粉末冶金協会春季大会
    • Place of Presentation
      早稲田大学(東京都)
    • Related Report
      2013 Final Research Report
  • [Presentation] In-situ synthesis, microstructure, and mechanical properties of alumina matrix composites2011

    • Author(s)
      Z. Chen
    • Organizer
      Materials Science & Technology 2011 International Conference & Exhibition(招待講演)
    • Place of Presentation
      Columbus, Ohio, USA
    • Related Report
      2011 Research-status Report
  • [Presentation] アルミナ基複合材料の組織と機械的性質に及ぼすTZP添加の影響2011

    • Author(s)
      陳中春
    • Organizer
      平成23年粉体粉末冶金協会春季大会
    • Place of Presentation
      早稲田大学
    • Related Report
      2011 Research-status Report
  • [Presentation] アルミナ基複合材料の組織や機械的性質に及ぼすTZP添加の影響2011

    • Author(s)
      江角誠
    • Organizer
      平成23年日本鉄鋼協会・日本金属学会中国四国支部講演大会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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