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Measurement of diffusion coefficients of radical in silicon ionic liquids by transient grating method

Research Project

Project/Area Number 23560918
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionKanazawa University

Principal Investigator

TAKAHASHI Kenji  金沢大学, 自然システム学系, 教授 (00216714)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsイオン液体 / 拡散 / 粘度 / シリコン / シロキサン / 過渡回折 / 分子拡散 / シラン構造 / 拡散係数 / 過渡回折格子法 / レーザー / ポリシロキサン / イミダゾリウム / 非線形レーザー分光
Research Abstract

Ionic liquids (ILs) have various interesting properties, for example, low vapor pressure, high electrical conductivity, chemical stability. Due to these unique properties, ILs can overcome the drawback of organic solvents such as high vapor pressure and flammability. Therefore it is attracted much attention as an electrolysis solution in Li ion battery. However it is known that molecular diffusion in IL is generally slow, because viscosities of ILs are higher than that of organic solvent. On the other hand, it has been reported that molecular diffusion in silicone oil is higher than that in organic solvents with the same viscosity. Therefore we expected that siloxane fanctional group may improve the rate of molecular diffusion. Our present purpose is analysis of transport property in silicone ionic liquids (SiILs) which is applicable to electrochemical devices. We applied the transient grating (TG) method in order to determine diffusion coefficients in SiILs.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (11 results)

All 2014 2013 2012 2011 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] Twin-peaks absorption spectra of excess electron in ionic liquids2014

    • Author(s)
      R. M. Musat, T. Kondoh, Y. Yoshida, K. Takahashi
    • Journal Title

      Radiat. Phys. Chem.

      Volume: 100 Pages: 32-37

    • DOI

      10.1016/j.radphyschem.2014.03.013

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced enzymatic saccharification of kenaf powder after ultrasonic pretreatment in ionic liquids at room temperature2012

    • Author(s)
      K.Ninomiya, K.Kamide, K.Takahashi, N.Shimizu
    • Journal Title

      Bioresour.Technol.

      Volume: 103 Issue: 1 Pages: 259-265

    • DOI

      10.1016/j.biortech.2011.10.019

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] In situ near-infrared spectroscopic studies of the structural changes of polyethylene during melting2011

    • Author(s)
      M.Mizushima, T.Kawamura, K.Takahashi, K.Nitta
    • Journal Title

      Polymer Journal

      Volume: 44 Issue: 3 Pages: 245-251

    • DOI

      10.1038/pj.2011.119

    • NAID

      10030168697

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 過渡回折格子法によるシリコンイオン液体中の拡散係数と粘度との関係2013

    • Author(s)
      合歓垣慎也, 松下裕貴, 高橋憲司
    • Organizer
      第4回イオン液体討論会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] The analysis of diffusion coefficient in silicone ionic liquid studied by transient grating method2013

    • Author(s)
      Shinya Nemgaki, Yukie Ohta, Yusuke Hiejima, Kenji Takahashi
    • Organizer
      33rd International Conference on Solution Chemistry
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Final Research Report
  • [Presentation] 過渡回折格子法によるシリコンイオン液体中の拡散係数と粘度の関係2013

    • Author(s)
      合歓垣慎也, 松下裕貴, 高橋憲司
    • Organizer
      第4回イオン液体討論会
    • Place of Presentation
      慶応義塾大学日吉キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 過渡回折格子法によるシリコンイオン液体中での拡散係数の測定2012

    • Author(s)
      合歓垣慎也,比江嶋祐介,太田幸恵,高橋憲司
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄
    • Related Report
      2012 Research-status Report
  • [Presentation] Laser-induced N2 Plasma Emission Spectra and Reaction on the Surface of Water Mist2012

    • Author(s)
      Chisato Kurosawa, Kenji Takahashi
    • Organizer
      2nd International Workshop on Radiation Effects in Nuclear Technology
    • Place of Presentation
      University of Tokyo, Tokyo
    • Related Report
      2011 Research-status Report
  • [Presentation] Excess Electrons in Ionic Liquids2011

    • Author(s)
      Kenji Takahashi
    • Organizer
      The 27th Miller Conference on Radiation Chemistry(招待講演)
    • Place of Presentation
      Tallbergsgaerdens Hotel, Sweden
    • Related Report
      2011 Research-status Report
  • [Presentation] シリコンイオン液体中での過渡回折格子法による分子拡散の測定2011

    • Author(s)
      坂井康弘, 大野智是, 比江嶋祐介, 木村桂文, 高橋憲司
    • Organizer
      第2回イオン液体討論会
    • Place of Presentation
      キャンパスプラザ京都,京都府
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://ktlabo.w3.kanazawa-u.ac.jp/

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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