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Synthesis of photocatalyst materials utilizing localized surface plasmon resonance of metal nanoparticles

Research Project

Project/Area Number 23560935
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKinki University

Principal Investigator

KOMINAMI Hiroshi  近畿大学, 理工学部, 准教授 (00257966)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords金ナノ粒子 / 表面プラズモン共鳴 / 光触媒 / 可視光 / 酸化チタン / 表面プラズモン吸収 / コロイド / 酸化セリウム
Research Abstract

Many efforts have been devoted to synthesis of photocatalysts that respond to visible light. This study explored new application of surface plasmon resonance (SPR) of gold (Au) nanoparticles as plasmonic photocatalysts working under irradiation of visible light. The plasmonic photocatalysts exhibited unique photoabsorption properties and photocatalytic performances in the minerarization of organic acid, selective oxidation, H2 formation, and reduction of organic compounds under irradiation of visible light. The functionalized SPR photocatalysts with platinum, silver and palladium co-catalysts worked effectively in H2 formation, reduction of nitrobenzene and dechlorination of chlorobenzene, respectively. The results introduced in this study can be widely applied for design and development of new plasmonic photocatalysts exhibiting further excellent activities and selectivities.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (46 results)

All 2014 2013 2012 2011 Other

All Journal Article (21 results) (of which Peer Reviewed: 21 results) Presentation (20 results) (of which Invited: 4 results) Book (1 results) Remarks (4 results)

  • [Journal Article] Visible-light-induced hydrogen and oxygen formation over Pt/Au/WO_3 photocatalyst utilizing two types of photoabsorption due to surface plasmon resonance and band-gap excitation2014

    • Author(s)
      田中淳皓、橋本圭司、古南 博
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 2 Pages: 586-589

    • DOI

      10.1021/ja410230u

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic chemoselectivc reduction of epoxides to alkenes along with formati on of ketones in alcoholic suspensions of silver-loaded titanium (IV) oxide at roo m temperature without use of reducing gas2014

    • Author(s)
      古南博、山本悟志、今村和也、田中淳晧、橋本圭司
    • Journal Title

      Chemical Communications

      Volume: (印刷中) Issue: 35 Pages: 4558-4560

    • DOI

      10.1039/c3cc49340g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functionalization of Au/TiO_2 plasmonic photocatalysts with Pd by formation of a core-shell structure for effective dechlorination of chlorobenzene under irradiation of visible light2013

    • Author(s)
      田中淳皓、福康二郎、西卓也、橋本圭司、古南 博
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Issue: 33 Pages: 16983-16989

    • DOI

      10.1021/jp403855p

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simultaneous and stoichiometric water oxidation and Cr (VI) reduction in aqueous suspensions of functionalized plasmonic photocatalyst Au/TiO_2-Pt under irradiation of green Light2013

    • Author(s)
      田中淳皓、中西康介、濱田涼介、橋本圭司、古南 博
    • Journal Title

      ACS Catal.

      Volume: 3 Issue: 8 Pages: 1886-1891

    • DOI

      10.1021/cs400433r

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Non-linear photocatalytic reaction induced by visible-light surface-plasmon resonance absorption of gold nanoparticles loaded on titania particles2013

    • Author(s)
      A. Tanaka, K. Hashimoto, B. Ohtani, H. Kominami
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 33 Pages: 3419-3419

    • DOI

      10.1039/c3cc41122b

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Functionalization of plasmonic Au/TiO2 photocatalyst with Ag co-catalyst for quantitative reduction of nitrobenzene to aniline in 2-propanol suspensions under irradiation of visible light2013

    • Author(s)
      A. Tanaka, Y. Nishino, S. Sakaguchi, T. Yoshikawa, K. Imamura, K. Hashimoto, H. Kominami
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 25 Pages: 2551-2553

    • DOI

      10.1039/c3cc39096a

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of Au/TiO_2 with Metal Cocatalysts Exhibiting Strong Surface Plasmon Resonance Effective for Photoinduced Hydrogen Formation under Irradiation of Visible Light2013

    • Author(s)
      A. Tanaka, S. Sakaguchi, K. Hashimoto, H. Kominami
    • Journal Title

      ACS Catal.

      Volume: 3 Pages: 79-79

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic reduction of benzonitrile to benzylamine in aqueous suspension of palladium-loaded titanium(IV) oxide2013

    • Author(s)
      K. Imamura, T. Yoshikawa, K. Nakanishi, K. Hashimoto, H. Kominami
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 93 Pages: 10911-10913

    • DOI

      10.1039/c3cc46439c

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Au/TiO2 with Metal Cocatalysts Exhibiting Strong Surface Plasmon Resonance Effective for Photoinduced Hydrogen Formation under Irradiation of Visible Light2013

    • Author(s)
      A. Tanaka, S. Sakaguchi, K. Hashimoto, H. Kominami
    • Journal Title

      ACS Catal.

      Volume: 3 Pages: 79-85

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Gold–Titanium(IV) Oxide Plasmonic Photocatalysts Prepared by a Colloid-Photodeposition Method: Correlation Between Physical Properties and Photocatalytic Activities2012

    • Author(s)
      A. Tanaka, A. Ogino, M. Iwaki, K. Hashimoto, A. Ohnuma, F. Amano, B. Ohtani, H. Kominami
    • Journal Title

      Langmuir

      Volume: 28 Issue: 36 Pages: 13105-13111

    • DOI

      10.1021/la301944b

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of Au/CeO2 exhibiting strong surface plasmon resonance effective for selective or chemoselective oxidation of alcohols to aldehydes or ketones in aqueous suspensions under irradiation of green light2012

    • Author(s)
      A. Tanaka, K. Hashimoto, H. Kominami
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 35 Pages: 14526-14533

    • DOI

      10.1021/ja305225s

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of Au/TiO2 exhibiting strong surface plasmon resonance effective for photoinduced hydrogen formation from organic and inorganic compounds under irradiation of visible light2012

    • Author(s)
      A. Tanaka, S. Sakaguchi, K. Hashimoto, H. Kominami
    • Journal Title

      Catal. Sci. Technol.

      Volume: 2 Issue: 5 Pages: 907-909

    • DOI

      10.1039/c2cy20108a

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic hydrogen formation from ammonia and methyl amine in an aqueous suspension of metal-loaded titanium(IV) oxide particles2012

    • Author(s)
      Hiroshi Kominami, Haruhiko Nishimune, Yuichi Ota, Yuma Arakawa, Takenori Inaba
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 111-112 Pages: 297-302

    • DOI

      10.1016/j.apcatb.2011.10.011

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Gold and Copper Nanoparticles Supported on Cerium(IV) Oxide : A Photocatalyst Mineralizing Organic Acids under Red Light Irradiation2011

    • Author(s)
      A. Tanaka, K. Hashimoto, H. Kominami
    • Journal Title

      ChemCatChem

      Volume: 3 Issue: 10 Pages: 1619-1619

    • DOI

      10.1002/cctc.201100158

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective photocatalytic oxidation of aromatic alcohols to aldehydes in an aqueous suspension of gold nanoparticles supported on cerium(IV) oxide under irradiation of green light2011

    • Author(s)
      A. Tanaka, K. Hashimoto, H. Kominami
    • Journal Title

      Chem. Commun.

      Volume: 47 Issue: 37 Pages: 10446-10446

    • DOI

      10.1039/c1cc13801d

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Gold nanoparticles supported on cerium(IV) oxide powder for mineralization of organic acids in aqueous suspensions under irradiation of visible light of lambda = 530 nm2011

    • Author(s)
      Hiroshi Kominami, Atsuhiro Tanaka, Keiji Hashimoto
    • Journal Title

      Applied Catalysis A: General

      Volume: 397 Issue: 1-2 Pages: 121-126

    • DOI

      10.1016/j.apcata.2011.02.029

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic reduction of nitrobenzenes to aminobenzenes in aqueous suspensions of titanium(IV) oxide in the presence of hole scavengers under deaerated and aerated conditions2011

    • Author(s)
      Kazuya Imamura, Shin-ichi Iwasaki, Tsuyoshi Maeda, Keiji Hashimoto, Bunsho Ohtani, and Hiroshi Kominami
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 13 Issue: 11 Pages: 5114-5119

    • DOI

      10.1039/c0cp02279a

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic degradation of 2-propanol over metal-ion-loaded titanium(IV) oxide under visible light irradiation: Effect of physical properties of nano-crystalline titanium(IV) oxide2011

    • Author(s)
      Sho Kitano, Keiji Hashimoto, Hiroshi Kominami
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 101 Issue: 3-4 Pages: 206-211

    • DOI

      10.1016/j.apcatb.2010.09.021

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Stoichiometric formation of benzene and ketones by photocatalytic dechlorination of chlorobenzene in secondary alcohol suspensions of palladium-loaded titanium(IV) oxide powder in the presence of sodium ion sources2011

    • Author(s)
      Kojirou Fuku, Keiji Hashimoto, Hiroshi Kominami
    • Journal Title

      Catal. Sci. Technol.

      Volume: 1 Issue: 4 Pages: 586-592

    • DOI

      10.1039/c0cy00040j

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic mineralization of acetic acid in aqueous suspension of metal-loaded cerium(IV) oxide under irradiation of visible light2011

    • Author(s)
      Atsuhiro Tanaka, Keiji Hashimoto, Hiroshi Kominami
    • Journal Title

      Chem. Lett.

      Volume: 40 Issue: 4 Pages: 354-356

    • DOI

      10.1246/cl.2011.354

    • NAID

      130004426176

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic mineralization of volatile organic compounds over commercial titanium(IV) oxide modified with rhodium(III) ion under visible light irradiation and correlation between physical properties and photocatalytic activity2011

    • Author(s)
      Sho Kitano, Keiji Hashimoto, Hiroshi Kominami
    • Journal Title

      Catalysis Today

      Volume: 164 Issue: 1 Pages: 404-409

    • DOI

      10.1016/j.cattod.2010.10.064

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 金の表面プラズモン共鳴と酸化タングステン(VI)のバンドギャップ励起を用いた可視光水素生成反応2014

    • Author(s)
      田中淳皓, 橋本圭司, 古南博
    • Organizer
      第113回触媒討論会
    • Place of Presentation
      豊橋
    • Year and Date
      2014-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] 金の表面プラズモン共鳴と酸化タングステンのバンドギャップ励起を用いた可視光水素生成反応2014

    • Author(s)
      田中淳皓・橋本圭司・古南博
    • Organizer
      第113回触媒討論会
    • Place of Presentation
      ロワジールホテル豊橋
    • Related Report
      2013 Annual Research Report
  • [Presentation] 表面プラズモン共鳴誘起型光触媒の機能化2013

    • Author(s)
      田中淳皓・橋本圭司・古南博
    • Organizer
      第32回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京工業大学蔵前会館くらまえホール
    • Related Report
      2013 Annual Research Report
  • [Presentation] 表面プラズモン共鳴誘起型光触媒による可視光水素生成反応2013

    • Author(s)
      田中淳皓・橋本圭司・古南博
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学手形キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Hydrogen formation by Au/TiO2 plasmonic photocatalyst with metal cocatalysts under irradiation of visible light2013

    • Author(s)
      A. Tanaka, K. Hashimoto, H. Kominami
    • Organizer
      XIth European Congress on Catalysis
    • Place of Presentation
      Lyon Convention Center, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Gold plasmonic photocatalysts: design, synthesis and functionalization2013

    • Author(s)
      H. Kominami
    • Organizer
      Kick Off Workshop for Gold Catalysis Research Center of DICP
    • Place of Presentation
      Dalian, China
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Functionalization of Photocatalysts Utilizing Surface-plasmon Resonance Absorption of Gold Nanoparticles2013

    • Author(s)
      H. Kominami
    • Organizer
      International Symposium on Advanced Mesostructured Catalysts and Photocatalysts (ISAM-Cat)
    • Place of Presentation
      Convention Center, Suita Campus, Osaka University
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Photocatalytic selective and chemoselective reactions2013

    • Author(s)
      H. Kominami
    • Organizer
      C&FC 2013 Pre-Symposium in Himeji
    • Place of Presentation
      Egret Himeji, Himeji
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 助触媒修飾金-酸化チタン(IV)による含塩素芳香族化合物の可視光誘起脱塩素反応2013

    • Author(s)
      田中淳皓、福 康二郎、西 卓也、橋本圭司、古南 博
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      滋賀、立命館大学びわこ・くさつキャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] 強い表面プラズモン共鳴を示す金ナノ粒子による多光子光触媒反応2013

    • Author(s)
      田中 淳皓、橋本 圭司、大谷 文章、古南 博
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      大阪、関西大学 千里山キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Au/CeO2: A new-type photocatalyst for selective oxidation of aromatic alcohols to aldehydes working under visible light irradiation2012

    • Author(s)
      A. Tanaka, K. Hashimoto, H. Kominami
    • Organizer
      IPS-19
    • Place of Presentation
      Pasadena、Caltech、USA
    • Related Report
      2012 Research-status Report
  • [Presentation] Gold nanoparticle-modified cerium(IV) oxide inducing plasmonic selective oxidation of aromatic alcohols under irradiation of visible light2012

    • Author(s)
      A. Tanaka, K. Hashimoto, H. Kominami
    • Organizer
      Gold2012
    • Place of Presentation
      東京、京王プラザホテル
    • Related Report
      2012 Research-status Report
  • [Presentation] Gold-titanium(IV) oxide plasmonic photocatalysts prepared by newly developed colloid-photodeposition method: correlation between physical properties and photocatalytic activities2012

    • Author(s)
      H. Kominami, A. Tanaka, K. Hashimoto
    • Organizer
      Gold2012
    • Place of Presentation
      東京、京王プラザホテル
    • Related Report
      2012 Research-status Report
  • [Presentation] 表面プラズモン共鳴誘起型光触媒による可視光水素生成反応の高速化2012

    • Author(s)
      田中 淳皓、橋本 圭司、古南 博
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      福岡、九州大学 伊都キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] 表面プラズモン共鳴を利用した可視光応答型光触媒の調製とその評価2012

    • Author(s)
      田中 淳皓、橋本 圭司、古南 博
    • Organizer
      第31回固体・表面光化学討論会
    • Place of Presentation
      大阪、大阪大学 吹田キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Photocatalytic Reactions over Gold-Metal Oxides under Irradiation of Visible Light2012

    • Author(s)
      H. Kominami, A. Tanaka, K. Hashimoto
    • Organizer
      The International Symposium on Photocatalysis
    • Place of Presentation
      Kyoto University Rakuyu-Kaikan
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 金ナノ粒子修飾酸化セリウム(IV)光触媒による芳香族アルコールのアルデヒドへの選択酸化反応:多段階光析出法の効果2012

    • Author(s)
      田中淳皓、橋本圭司、古南 博
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2011 Research-status Report
  • [Presentation] 多段階光析出法による金ナノ粒子修飾酸化チタン(IV)の調製と可視光照射下における光誘起水素生成2012

    • Author(s)
      田中淳皓、橋本圭司、古南 博
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應大学(神奈川県)
    • Related Report
      2011 Research-status Report
  • [Presentation] 緑色照射下における金ナノ粒子修飾酸化セリウム(IV)光触媒による芳香族アルコールのアルデヒドへの選択酸化反応2011

    • Author(s)
      田中淳皓、橋本圭司、古南 博
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Related Report
      2011 Research-status Report
  • [Presentation] コロイド法により調製した金ナノ粒子修飾酸化チタンによる可視光誘起光触媒反応2011

    • Author(s)
      古南 博、田中淳皓、荻野麻子、岩城 萌、大沼 明、天野史章、大谷文章
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学(北海道)
    • Related Report
      2011 Research-status Report
  • [Book] 光化学【プラズモニック光触媒 -設計・合成・応用-】2013

    • Author(s)
      田中淳皓、古南 博
    • Total Pages
      8
    • Publisher
      科学技術社
    • Related Report
      2013 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.apch.kindai.ac.jp/surface-folder/surface-index.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 表面設計化学研究室

    • URL

      http://www.apch.kindai.ac.jp/surface-folder/surface-index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 表面設計化学研究室

    • URL

      http://www.apch.kindai.ac.jp/surface-folder/surface-index.html

    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.apch.kindai.ac.jp/surface-folder/surface-index.html

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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