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Design and Development of Complex with Light-harvesting Molecule, Artificial Co-enzyme and Formate Dehydrogenase for Carbon Dioxide Fuelization

Research Project

Project/Area Number 23560947
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Biofunction/Bioprocess
Research InstitutionOsaka City University (2013-2014)
Oita University (2011-2012)

Principal Investigator

AMAO YUTAKA  大阪市立大学, 複合先端研究機構, 教授 (80300961)

Project Period (FY) 2011-04-28 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords人工光合成 / 二酸化炭素還元 / 人工補酵素 / ソーラー燃料生成 / 酵素反応速度論 / ギ酸脱水素酵素 / 光捕集分子 / 酵素反応 / 光誘起電子移動 / 低炭素燃料
Outline of Final Research Achievements

In this study, design and development of complex with light-harvesting molecule, artificial co-enzyme and formate dehydrogenase for carbon dioxide fuelization were studied. The results are as follows.
(1) The suitable artificial co-enzyme for formate dehydrogenase was designed and synthesized. Relationship between the catalytic activity of formate dehydrogenase and chemical structure of artificial co-enzyme was clarified.
(2) The complex with light-harvesting molecule and artificial co-enzyme was was designed and synthesized. Photochemical and physical properties of the complex were clarified using fluorescence spectroscopy.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (54 results)

All 2015 2014 2013 2012 2011

All Journal Article (5 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 4 results) Presentation (45 results) (of which Invited: 14 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Formate dehydrogenase catalyzed CO2 reduction in a chlorin-e6 sensitized photochemical biofuel cell2015

    • Author(s)
      Yutaka Amao, Naho Shuto
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 19 Issue: 01-03 Pages: 459-464

    • DOI

      10.1142/s1088424615500406

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Visible-light induced hydrogen and formic acid production from biomass and carbon dioxide with enzymatic and artificial photosynthesis system2014

    • Author(s)
      Yutaka Amao, Satomi Takahara, Yuka Sakai
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 39 Issue: 35 Pages: 20771-20776

    • DOI

      10.1016/j.ijhydene.2014.06.135

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chloroplast from Spinach adsorbed nanocrystalline TiO2 electrode for photovoltaic conversion device toward artificial photosynthesis system2014

    • Author(s)
      Yutaka Amao, Akemi Tadokoro, Miki Nakamura, Naho Shuto, Ayumi Kuroki
    • Journal Title

      Research on Chemical Intermediates

      Volume: 40 Issue: 9 Pages: 3257-3265

    • DOI

      10.1007/s11164-014-1831-2

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formate dehydrogenase-viologen immobilized electrode for CO2 conversion toward the development of artificial photosynthesis system2014

    • Author(s)
      Yutaka Amao, Naho Shuto
    • Journal Title

      Research on Chemical Intermediates

      Volume: 40 Issue: 9 Pages: 3267-3276

    • DOI

      10.1007/s11164-014-1832-1

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 二酸化炭素を燃料化する人工光合成系2011

    • Author(s)
      天尾 豊
    • Journal Title

      光化学

      Volume: 42 Pages: 107-113

    • NAID

      10030166811

    • Related Report
      2011 Research-status Report
  • [Presentation] バイオ燃料生産のための人工光合成システム2014

    • Author(s)
      天尾豊
    • Organizer
      日本応用細胞生物学会第12回大会
    • Place of Presentation
      京都市国際交流会館(京都市・左京区)
    • Year and Date
      2014-12-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Promotion of formate dehydrogenase activity of the conversion of CO2 to formic acid by an artificial coenzyme with 2,2’- bipyridinium salt skeletons2014

    • Author(s)
      Yutaka Amao, Ryutaro Abe, Sachina Shiotani
    • Organizer
      7th Asian Biological Inorganic Chemistry Conference (AsBIC7)
    • Place of Presentation
      Gold Coast (Australia)
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] The effect of chemical structure of artificial co-enzyme with 4,4’-bipyridine skeleton on the photoinduced formic acid production from CO2 with formate dehydrogenase2014

    • Author(s)
      Shusaku Ikeyama, Yutaka Amao
    • Organizer
      7th Asian Biological Inorganic Chemistry Conference (AsBIC7)
    • Place of Presentation
      Gold Coast (Australia)
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Methanol Production from Carbon Dioxide Based on the Artificial Photosynthesis System2014

    • Author(s)
      Ryota Kataoka, Yutaka Amao
    • Organizer
      7th Asian Biological Inorganic Chemistry Conference (AsBIC7)
    • Place of Presentation
      Gold Coast, (Australia)
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Visible-light induced conversion of CO2 to chemical with sensitizer-enzyme hybrid artificial photosynthesis system2014

    • Author(s)
      Yutaka Amao
    • Organizer
      2014 International Conference on Artificial Photosynthesis (ICARP2014)
    • Place of Presentation
      Awaji Yumebutai International Conference Center (Hyogo, Japan)
    • Year and Date
      2014-11-24 – 2014-11-28
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Artificial Photosynthesis System Based on the Water-Soluble Porphyrins2014

    • Author(s)
      Yutaka Amao
    • Organizer
      2nd International ALA and Porphyrin Symposium (IAPS2)
    • Place of Presentation
      The University of Tokyo (Tokyo, Japan)
    • Year and Date
      2014-11-15 – 2014-11-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Artificial Photosynthesis System for Solar Fuel and Energy Carrier Molecule Production2014

    • Author(s)
      Yutaka Amao
    • Organizer
      21st International SPACC Symposium (SPACC)-Innovative Applications of Coordination Compounds
    • Place of Presentation
      Kogakuin University (Tokyo, Japan)
    • Year and Date
      2014-10-31 – 2014-11-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Visible-light induced methanol production from carbon dioxide with enzymatic and artificial photosynthesis2014

    • Author(s)
      Ryota Kataoka, Yutaka Amao
    • Organizer
      21st International SPACC Symposium (SPACC)-Innovative Applications of Coordination Compounds
    • Place of Presentation
      Kogakuin University (Tokyo, Japan)
    • Year and Date
      2014-10-31 – 2014-11-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of artificial co-enzyme for synthesis of formic acid from carbon dioxide with formate dehydrogenase2014

    • Author(s)
      Ryutaro Abe, Yutaka Amao
    • Organizer
      21st International SPACC Symposium (SPACC)-Innovative Applications of Coordination Compounds
    • Place of Presentation
      Kogakuin University (Tokyo, Japan)
    • Year and Date
      2014-10-31 – 2014-11-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of chemical structure of artificial co-enzyme with 4,4’-bipyridinium salt on the photoinduced formic acid production from CO2 with formate dehydrogenase2014

    • Author(s)
      Shusaku Ikeyama, Yutaka Amao
    • Organizer
      21st International SPACC Symposium (SPACC)-Innovative Applications of Coordination Compounds
    • Place of Presentation
      Kogakuin University (Tokyo, Japan)
    • Year and Date
      2014-10-31 – 2014-11-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hydrogen production form formic acid with enzyme and the catalyst complex system2014

    • Author(s)
      Atsuro Kai, Yutaka Amao
    • Organizer
      21st International SPACC Symposium (SPACC)-Innovative Applications of Coordination Compounds
    • Place of Presentation
      Kogakuin University (Tokyo, Japan)
    • Year and Date
      2014-10-31 – 2014-11-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] ギ酸脱水素酵素が触媒する二酸化炭素‐ギ酸変換反応に有効な人工補酵素の開発2014

    • Author(s)
      安部龍太朗・天尾豊
    • Organizer
      第4回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酵素・触媒複合システムによるギ酸-水素変換反応2014

    • Author(s)
      甲斐温朗・天尾豊
    • Organizer
      第4回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] ギ酸脱水素酵素-増感剤系による可視光駆動型二酸化炭素-ギ酸変換反応2014

    • Author(s)
      天尾豊・安部龍太朗・塩谷祥奈
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] ギ酸脱水素酵素が触媒する二酸化炭素-ギ酸変換反応に対するビピリジン骨格を基盤とした人工補酵素の影響に関する研究2014

    • Author(s)
      天尾豊・池山秀作
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県・東広島市)
    • Year and Date
      2014-09-25 – 2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 二酸化炭素を資源化する人工光合成系の構築:バイオマス利用への展開2014

    • Author(s)
      天尾豊
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県・東広島市)
    • Year and Date
      2014-09-25 – 2014-09-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Effect of Chemical Structure of Viologen-derivatives as an Artificial Co-enzyme on the Carbon Dioxide Reduction Activity of Formate Dehydrogenase2014

    • Author(s)
      Yutaka Amao, Shusaku Ikeyama
    • Organizer
      International Conference "Molecular Complexity in Modern Chemistry" (MCMC-2014)
    • Place of Presentation
      Moscow (Russia)
    • Year and Date
      2014-09-13 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 二酸化炭素を分子変換する酵素触媒を基盤とした人工光合成系2014

    • Author(s)
      天尾豊
    • Organizer
      第66回日本生物工学会大会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌市)
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Promotion of formate dehydrogenase activity of the conversion of carbon dioxide to formic acid by viologen derivatives as an artificial coenzyme2014

    • Author(s)
      Yutaka Amao, Ryutaro Abe, Sachina Shiotani
    • Organizer
      7th International Congress on Biocatalysis (biocat2014)
    • Place of Presentation
      Hamburg (Germany)
    • Year and Date
      2014-08-31 – 2014-09-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photoelectrochemical Biofuel Cell with the Carbon Dioxide Conversion Function Consisting of Thylakoid Membrane from Algae and Enzyme Immobilized Electrodes2014

    • Author(s)
      Yutaka Amao, Naho Shuto, Akemi Tadokoro, Miki Nakamura
    • Organizer
      20th International Conference on Photochemical Conversion and Storage of Solar Energy (IPS-20)
    • Place of Presentation
      Berlin (Germany)
    • Year and Date
      2014-07-27 – 2014-08-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of Chemical Structure of Viologen-Derivatives on the Reduction Catalyst Activity with Formate Dehydrogenase2014

    • Author(s)
      Shusaku Ikeyama, Yutaka Amao
    • Organizer
      20th International Conference on Photochemical Conversion and Storage of Solar Energy (IPS-20)
    • Place of Presentation
      Berlin (Germany)
    • Year and Date
      2014-07-27 – 2014-08-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 可視光駆動型二酸化炭素‐ギ酸変換反応系における人工補酵素-ギ酸脱水素酵素間相互作用に関する研究2014

    • Author(s)
      池山秀作・天尾豊
    • Organizer
      第33回光が関わる触媒化学シンポジウム
    • Place of Presentation
      東京理科大学(東京都・葛飾区)
    • Year and Date
      2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] ソーラ燃料生成のためのArtificial Leafデバイスの創製2014

    • Author(s)
      天尾豊
    • Organizer
      第10回 有機太陽電池シンポジウム
    • Place of Presentation
      京都大学(京都府・宇治市)
    • Year and Date
      2014-07-17 – 2014-07-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 光水素生産反応のための水素発生用人工酵素の構築と評価2013

    • Author(s)
      甲斐温朗,天尾豊
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 光捕集‐人工補酵素機能を合わせ持つ複合分子の合成と光化学的特性評価2013

    • Author(s)
      安部龍太郎,天尾豊
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 光増感分子‐酵素系による二酸化炭素‐メタノール変換反応機構解明に関する研究2013

    • Author(s)
      片岡良太、天尾豊
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 二酸化炭素‐ギ酸変換反応系を触媒するギ酸脱水素酵素に対する人工補酵素の化学構造と機能相関に関する研究2013

    • Author(s)
      池山秀作、天尾豊
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 藻類由来光合成器官を利用した光電変換デバイスの機能評価2013

    • Author(s)
      天尾豊
    • Organizer
      2013有機太陽電池シンポジウム
    • Place of Presentation
      京都大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ソーラー燃料・物質生産のための人工光合成技術~これまでの成果と実用への課題~2013

    • Author(s)
      天尾豊
    • Organizer
      ITACテクノカフェ大阪25年度第3回定例会
    • Place of Presentation
      大阪府立大学 I-siteなんば
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 二酸化炭素分子変換する光増感分子-酵素複合系2013

    • Author(s)
      天尾豊
    • Organizer
      2013光化学討論会
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 二酸化炭素‐ギ酸変換反応を触媒するギ酸脱水素酵素に対する人工補酵素の化学構造と機能相関2013

    • Author(s)
      天尾豊,池山秀作
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ソーラー燃料生成のためのハイブリッド型人工光合成システムの構築2013

    • Author(s)
      天尾豊
    • Organizer
      日本太陽エネルギー学会関西支部 2013 年度シンポジウム
    • Place of Presentation
      キャンパスポート大阪
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 光水素生産反応のための水素発生用人工酵素の構築と評価2013

    • Author(s)
      甲斐温朗,天尾豊
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] ギ酸脱水素酵素が触媒する二酸化炭素‐ギ酸変換反応に有効な人工補酵素の開発2013

    • Author(s)
      安部龍太郎,天尾豊
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 光増感剤‐酵素系による二酸化炭素‐メタノール変換系の構築2013

    • Author(s)
      片岡良太、天尾豊
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 二酸化炭素還元能を有する酵素を活性化する人工補酵素の開発2013

    • Author(s)
      池山秀作、天尾豊
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Chemical Structure of Viologen-derivatives on the CO2 Reduction Activity with Formate Dehydrogenase2013

    • Author(s)
      Yutaka Amao, Shusaku, Ikeyama
    • Organizer
      he Sixteenth International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC-16)
    • Place of Presentation
      Hokkaido University
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Chemical Structure of Viologen-derivatives on the Conversion of CO2 to Formic acid Activity with Formate Dehydrogenase2013

    • Author(s)
      Yutaka Amao, Shusaku, Ikeyama
    • Organizer
      XIth European Congress on Catalysis
    • Place of Presentation
      France
    • Related Report
      2013 Research-status Report
  • [Presentation] 人工光合成を基盤とした二酸化炭メタノール変換反応における人工補酵素の構造相関2012

    • Author(s)
      天尾豊、伊藤裕也
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学伊都キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] ソーラー燃料生成のための色素-酵素複合型人工光合成系2012

    • Author(s)
      天尾豊
    • Organizer
      第1回有機太陽電池・人工光合成研究会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 二酸化炭素を燃料化する人工光合成2012

    • Author(s)
      天尾豊
    • Organizer
      2012年CREST 有機太陽電池シンポジウム
    • Place of Presentation
      京都大学宇治キャンパス
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Liquid Fuel Production from CO2 with Photosensitizer‐Enzyme Based Artificial Photosynthesis System2012

    • Author(s)
      Yutaka Amao
    • Organizer
      31th The International Symposium on Photocatalysis
    • Place of Presentation
      Kyoto University
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Solar Biohydrogen Production with Artificial Photosynthesis System2012

    • Author(s)
      Yutaka Amao
    • Organizer
      日仏セミナー水素エネルギー
    • Place of Presentation
      在日フランス大使館
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 二酸化炭素をメタノールに変換する人工光合成系の構築2012

    • Author(s)
      天尾 豊
    • Organizer
      第1回「フォーラム:人工光合成」
    • Place of Presentation
      科学技術振興機構東京本部地階ホール
    • Related Report
      2011 Research-status Report
  • [Presentation] Development of artificial leaf device for solar fuel production2012

    • Author(s)
      天尾 豊
    • Organizer
      243rd American Chemical Society National Meeting & Exposition(招待講演)
    • Place of Presentation
      San Diego Convention Center, USA
    • Related Report
      2011 Research-status Report
  • [Book] 光合成研究と産業応用最前線(第2節 光合成器官・触媒複合型人工光合成システムの開発を執筆)2014

    • Author(s)
      天尾豊
    • Total Pages
      446
    • Publisher
      NTS
    • Related Report
      2014 Annual Research Report
  • [Book] 化学便覧 応用化学編 第7版(6.6.6バイオ触媒を執筆)2014

    • Author(s)
      天尾豊
    • Total Pages
      1788
    • Publisher
      丸善
    • Related Report
      2014 Annual Research Report
  • [Book] 人工光合成実用化に向けた最新技術2013

    • Author(s)
      天尾豊
    • Total Pages
      278
    • Publisher
      情報機構
    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 酸化還元酵素反応の制御及びその応用2012

    • Inventor(s)
      天尾豊、池山秀作、中西雄二、高橋哲也、荻野幹治
    • Industrial Property Rights Holder
      天尾豊、池山秀作、中西雄二、高橋哲也、荻野幹治
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-139887
    • Filing Date
      2012-06-21
    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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