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Creation of new catalysis for hydrogen isotope exchange by chemical reforming of porous adsorbent

Research Project

Project/Area Number 23561008
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nuclear fusion studies
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

KAWAMURA Yoshinori  独立行政法人日本原子力研究開発機構, 核融合研究開発部門 六ヶ所核融合研究所, 研究主幹 (10354614)

Co-Investigator(Renkei-kenkyūsha) MUNAKATA Kenzo  国立大学法人秋田大学, 工学資源学部, 教授 (70264067)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords燃料・ブランケット / 同位体交換 / 水素同位体交換反応 / トリチウム回収 / 遷移金属型モルデナイト / 交換反応触媒
Research Abstract

In this study, to evaluate tritium recovery efficiency when catalytic function is added to the dryer of tritium recovery system for solid breeder blanket of nuclear fusion reactor, application of hydrophilic catalyst instead of adsorbent is discussed. Synthetic zeolite used as a carrier of catalyst changes its property by replacing its cation to other one. In this work, influence on isotopic exchange reaction has been investigated when mordenite type zeolite (MOR) having exchanged cation is used as a carrier of catalyst. Presently, use of noble metal cannot be avoided for hydrogen isotopic exchange catalyst. Activity of Pt-catalyst became larger than Pd-catalyst. And, the tendency that the activity of the Pt-catalyst whose carrier is cation-exchanged MOR with group 1 ion becomes larger than MOR with group 2 ion has been observed. And, it seems that the catalytic activity depend on the order of BET surface area of the carrier.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (16 results)

All 2014 2013 2012 2011

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (11 results)

  • [Journal Article] Hydrogen and water vapor adsorption properties on cation-exchanged mordenite for use to a tritium recovery system2014

    • Author(s)
      Yoshinori Kawamura, Yuki Edao, Yasunori Iwai, Takumi Hayashi, Toshihiko Yamanishi
    • Journal Title

      Fusion Eng. Des.

      Volume: (in press) Issue: 7-8 Pages: 1539-1543

    • DOI

      10.1016/j.fusengdes.2014.01.064

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption rate of hydrogen isotopes on Ca-mordenite2013

    • Author(s)
      Yoshinori Kawamura, Yuki Edao, Toshihiko Yamanishi
    • Journal Title

      Fusion Engineering and Design

      Volume: 88 Issue: 9-10 Pages: 2255-2258

    • DOI

      10.1016/j.fusengdes.2013.05.021

    • NAID

      130007035260

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Cation Exchange on Hydrogen Adsorption Property of Mordenite for Isotope Separation2012

    • Author(s)
      Y. Kawamura, Y. Iwai, K. Munakata, T. Yamanishi
    • Journal Title

      Journal of Nuclear Materials

      Volume: in press. (available on line) Issue: 1-3 Pages: S455-S460

    • DOI

      10.1016/j.jnucmat.2012.11.003

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Adsorption Behavior of Hydrogen and Deuterium on Natural Mordenite Adsorbents at 77 K2012

    • Author(s)
      K. Munakata, Y. Kawamura
    • Journal Title

      Fusion Science and Technology

      Volume: 62 Pages: 71-76

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] ADSORPTION BEHAVIOR OF HYDROGEN ISOTOPES ON MORDENITE ADSORBENTS AT 77K2011

    • Author(s)
      K. Munakata, Y. Kawamura
    • Journal Title

      Fusion Science and Technology

      Volume: 60 Pages: 426-430

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] カチオン交換型モルデナイトにおける水素-水蒸気間の化学交換反応2014

    • Author(s)
      河村繕範
    • Organizer
      日本原子力学会2014年春の年会
    • Place of Presentation
      東京都市大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 水素同位体のカルシウム置換型モルデナイト吸着材に関する吸着平衡の反応性空孔溶液理論による相関2014

    • Author(s)
      宗像健三
    • Organizer
      日本原子力学会2014年春の年会
    • Place of Presentation
      東京都市大学
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] カチオン交換型モルデナイトにおける水素ー水蒸気間の化学交換反応2014

    • Author(s)
      河村繕範、林巧
    • Organizer
      日本原子力学会2014年春の年会
    • Place of Presentation
      東京都市大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Hydrogen and water vapor adsorption properties on cation-exchanged mordenite for use to a tritium recovery system2013

    • Author(s)
      Yoshinori Kawamura
    • Organizer
      11th International Symposium on Fusion Nuclear Technology (ISFNT-11)
    • Place of Presentation
      Barcelona(Spain)
    • Related Report
      2013 Final Research Report
  • [Presentation] Hydroegn and water vapor adsorption properties on cation-exchanged mordenite for use to a tritiu recovery system2013

    • Author(s)
      Yoshinori Kawamura, Yuki Edao, Yasunori Iwai, Takumi Hayashi, Toshihiko Yamanishi
    • Organizer
      11th International Symposium on Fusion Nuclear Technology (ISFNT-11)
    • Place of Presentation
      Barcelona, Spain
    • Related Report
      2013 Annual Research Report
  • [Presentation] カリウム交換型モルデナイトの水素同位体吸着速度2012

    • Author(s)
      河村繕範
    • Organizer
      日本原子力学会2012年秋の大会
    • Place of Presentation
      広島大学
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Adsorption Rate of Hydrogen Isotopes on Ca-Mordenite2012

    • Author(s)
      Yoshinori Kawamura
    • Organizer
      27th Symposium on Fusion Technology (SOFT-2012)
    • Place of Presentation
      Liege (Belgium.)
    • Related Report
      2013 Final Research Report
  • [Presentation] Adsorption Rate of Hydrogen Isotopes on Ca-Mordenite2012

    • Author(s)
      Yoshinori Kawamura, Yuki Edao, Toshihiko Yamanishi
    • Organizer
      27th Symposium on Fusion Technology (SOFT-2012)
    • Place of Presentation
      Liege, Belgium
    • Related Report
      2012 Research-status Report
  • [Presentation] カルシウム交換型モルデナイトの水素同位体吸着速度2012

    • Author(s)
      河村繕範、山西敏彦
    • Organizer
      日本原子力学会2012年春の年会
    • Place of Presentation
      福井大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Effect of Cation Exchange on Hydrogen Adsorption Property of Mordenite for Isotope Separation2011

    • Author(s)
      Y. Kawamura, Y. Iwai, K. Munakata, T. Yamanishi
    • Organizer
      15th International Conference on Fusion Reactor Materials (ICFRM-15)
    • Place of Presentation
      Charleston(U. S. A.)
    • Related Report
      2011 Research-status Report
  • [Presentation] Adsorption Characteristics of Hydrogen Isotopes on Mordenite Adsorbents at 77 K2011

    • Author(s)
      K. Munakata, K. Wada, K. Hara and Y. Kawamura
    • Organizer
      15th International Conference on Fusion Reactor Materials (ICFRM-15)
    • Place of Presentation
      Charleston(U. S. A.)
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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