| Project/Area Number |
23580192
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Food science
|
|---|
| Research Institution | Tokai University (2013)
Toyama Institute of Health (2011-2012) |
|---|
Principal Investigator |
KODAMA Shuji 東海大学, 理学部, 教授 (70360807)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
YAMAMOTO Atsushi 中部大学, 応用生物学部, 教授 (60360806)
AIZAWA Sen-ichi 富山大学, 理工学研究部, 教授 (60231099)
TAGA Atsushi 近畿大学, 薬学部, 準教授 (20247951)
|
|---|
| Project Period (FY) |
2011 – 2013
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
|---|
| Keywords | キャピラリー電気泳動 / 配位子交換 / 光学分割 / α-ヒドロキシ酸 / ジュース / 光学異性体 / 有機酸 / 金属イオン |
|---|
| Research Abstract |
Using a singular ligand and a dual central ion in a background electrolyte, a ligand exchange CE was investigated for the simultaneous enantioseparation of malic, tartaric and isocitric acids. Tartaric acid was enantioseparated by a ligand exchange CE with 100 mM D-quinic acid as a singular ligand and 10 mM Cu(II) ion as a singular central ion, but malic and isocitric acids were not enantioseparated. Addition of 1.8 mM Sc(III) ion to the background electrolyte with 10 mM Cu(II) ion to create a dual central metal ion system permitted the simultaneous determination of these alpha-hydroxy acid enantiomers and citric acid. The proposed ligand exchange CE was thus well suited for detecting adulteration of fruit juices.
|
