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Fabrication of optically and electrically functional materials based on industrially available cellulose derivatives via mild chemical modification and orientation control

Research Project

Project/Area Number 23580228
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Wood science
Research InstitutionGifu University (2013-2014)
Kyoto University (2011-2012)

Principal Investigator

TERAMOTO Yoshikuni  岐阜大学, 応用生物科学部, 准教授 (40415716)

Project Period (FY) 2011-04-28 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsセルロース / 誘導体 / 分子修飾 / 配向制御 / 光学異方性 / 誘電性 / 機能材料
Outline of Final Research Achievements

We accomplished the fabrication of optically and electrically functional materials based on industrially available cellulose derivatives (cellulose acetate (CA) and cyanoethyl cellulose (CyEC)), by controlling the orientation state of polymer chains and segments via combination of mild chemical modification and thermal processing. With regard to optical functionality, we synthesized CA-based graft copolymers by atom transfer radical polymerization; their optical anisotropy was delicately controllable by changing the copolymer composition, which is of great significance for designing optical retardant films including a specialty that shows a zero-birefringence nature irrespective of the elongation and ensuring molecular orientation growth. As electrically functional materials, we successfully obtained thermally-stable highly dielectric derivatives of CyEC.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (23 results)

All 2015 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 8 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Material Functionalization and Its Expanding Bioscientific Perspective for Structural Polysaccharides <i>via</i> Nanoscopic Multicomposition, Orientation Control, and Processing Development2015

    • Author(s)
      Yoshikuni Teramoto
    • Journal Title

      Trends in Glycoscience and Glycotechnology

      Volume: 27 Issue: 155 Pages: 111-123

    • DOI

      10.4052/tigg.1424.1

    • NAID

      130005072349

    • ISSN
      0915-7352, 1883-2113
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Functional Thermoplastic Materials from Derivatives of Cellulose and Related Structural Polysaccharides2015

    • Author(s)
      Yoshikuni Teramoto
    • Journal Title

      Molecules

      Volume: 20 Issue: 4 Pages: 5487-5527

    • DOI

      10.3390/molecules20045487

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis of O-(2,3-Dihydroxypropyl) Cellulose in NaOI-UUrea Aqueous Solution : As a Precursor for Introducing Necklace-Like Structure2013

    • Author(s)
      C. Chang, Y. Teramoto, and Y. Nishio
    • Journal Title

      J. Polym. Sci., Part A, Polym. Chem.

      Volume: 51 Issue: 17 Pages: 3590-3597

    • DOI

      10.1002/pola.26773

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Blend miscibility of cellulose propionate with poly(N-vinyl pyrrolidone-co-methyl methacrylate)2013

    • Author(s)
      K. Sugimura, Y. Teramoto, and Y. Nishio
    • Journal Title

      Carbohydrate Polymers

      Volume: 98 Issue: 1 Pages: 532-541

    • DOI

      10.1016/j.carbpol.2013.06.045

    • NAID

      120005343929

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Orientation and Birefringence Compensation of Trunk and Graft Chains in Drawn Films of Cellulose Acetate-graft-PMMA Synthesized by ATRP2013

    • Author(s)
      H. Yamanaka, Y. Teramoto, and Y. Nishio
    • Journal Title

      Macromolecules

      Volume: 46 Issue: 8 Pages: 3074-3083

    • DOI

      10.1021/ma400155f

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] セルロースエステルのポリマーブレンドならびにグラフト共重合体 ~配向特性と光学機能の制御~2013

    • Author(s)
      寺本好邦, 杉村和紀, 西尾嘉之
    • Journal Title

      日本接着学会誌

      Volume: 49 Pages: 32-39

    • NAID

      10031170025

    • Related Report
      2012 Research-status Report
  • [Journal Article] Structural characterization of poly(ε-caprolactone)-grafted cellulose acetate and butyrate by solid-state 13C NMR, dynamic mechanical, and dielectric relaxation analyses2011

    • Author(s)
      R. Kusumi, Y. Teramoto, and Y. Nishio
    • Journal Title

      Polymer

      Volume: 52 Issue: 25 Pages: 5912-5921

    • DOI

      10.1016/j.polymer.2011.10.032

    • NAID

      120003644372

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 機能性セルロース誘導体 -分子凝集構造の制御と複合化による機能設計-2011

    • Author(s)
      寺本好邦, 青木 弾, 西尾嘉之
    • Journal Title

      バイオプラジャーナル

      Volume: 11 Pages: 18-23

    • Related Report
      2011 Research-status Report
  • [Journal Article] Cellulose acetate/poly(methylmethacrylate) interpenetratingnetworks : synthesis and estimation ofthermal and mechanical properties2011

    • Author(s)
      D. Aoki, Y. Teramoto, and Y. Nishio
    • Journal Title

      Cellulose

      Volume: 18 Issue: 6 Pages: 1441-1454

    • DOI

      10.1007/s10570-011-9580-5

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Molecular orientation and optical anisotropy in drawn films of cellulose diacetate-graft-PLLA : comparative investigation with poly(vinyl acetate-co-vinyl alcohol)-graft-PLLA2011

    • Author(s)
      T. Unohara, Y. Teramoto, and Y. Nishio
    • Journal Title

      Cellulose

      Volume: 18 Issue: 3 Pages: 539-553

    • DOI

      10.1007/s10570-011-9508-0

    • NAID

      120003072123

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Molecular orientation and optical anisotropy in drawn films of cellulosic graft copolymers2012

    • Author(s)
      Y. Teramoto and Y. Nishio
    • Organizer
      243rd ACS National Meeting(招待講演)
    • Place of Presentation
      San Diego (California, USA)
    • Related Report
      2011 Research-status Report
  • [Presentation] セルロースアセテート系マクロ開始剤を用いたメタクリル酸メチルの原子移動ラジカル重合と生成グラフトコポリマーの分子配向の評価2011

    • Author(s)
      山中博文, 寺本好邦, 西尾嘉之
    • Organizer
      セルロース学会第18回年次大会
    • Place of Presentation
      信州大学工学部 (長野市)
    • Related Report
      2011 Research-status Report
  • [Presentation] シアノエチルセルロースエステル誘導体の分子凝集構造および誘電特性の評価2011

    • Author(s)
      武知慎吾, 佐藤 恵, 寺本好邦, 西尾嘉之
    • Organizer
      セルロース学会第18回年次大会
    • Place of Presentation
      信州大学工学部 (長野市)
    • Related Report
      2011 Research-status Report
  • [Presentation] セルロースアセテート系マクロ開始剤を用いたメタクリル酸メチルの原子移動ラジカル重合と生成グラフトポリマーの特性解析2011

    • Author(s)
      山中博文, 寺本好邦, 西尾嘉之
    • Organizer
      高分子学会第60回年次大会
    • Place of Presentation
      大阪国際会議場 (大阪市)
    • Related Report
      2011 Research-status Report
  • [Presentation] シアノエチルセルロース誘導体の誘電特性:エステル化と分子・セグメント配向に伴う高次構造および誘電ダイナミクスの変化

    • Author(s)
      武知慎吾,寺本好邦,西尾嘉之
    • Organizer
      セルロース学会第20回年次大会
    • Place of Presentation
      京都大学宇治キャンパスおおばくプラザ(宇治市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis and characterization of cellulose butyral derivatives with "necklace-like" side chains

    • Author(s)
      C. Chang, Y. Teramoto, Y. Nishio
    • Organizer
      セルロース学会第20回年次大会
    • Place of Presentation
      京都大学宇治キャンパスおおばくプラザ(宇治市)
    • Related Report
      2013 Research-status Report
  • [Presentation] アシルキチン/ポリ(ε-カプロラクトン)ブレンドの選択的加水分解による微多孔材料の作製と細胞接着性評価

    • Author(s)
      橋脇弘樹,寺本好邦,西尾嘉之
    • Organizer
      高分子学会第62回年次大会
    • Place of Presentation
      京都国際会館(京都市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Molecular orientation and optical anisotropy in drawn films of cellulosic graft copolymers

    • Author(s)
      Teramoto, Y., Nishio, Y.
    • Organizer
      3rd International Cellulose Conference (ICC2012)
    • Place of Presentation
      Sapporo
    • Related Report
      2012 Research-status Report
  • [Presentation] シアノエチルセルロースエステル誘導体の分子・セグメント配向制御と誘電ダイナミクス

    • Author(s)
      武知慎吾, 寺本好邦, 西尾嘉之
    • Organizer
      第63回日本木材学会大会
    • Place of Presentation
      盛岡
    • Related Report
      2012 Research-status Report
  • [Presentation] シアノエチルセルロース誘導体の誘電特性:側鎖種と一軸熱延伸の効果

    • Author(s)
      武知慎吾, 寺本好邦, 西尾嘉之
    • Organizer
      セルロース学会第19回年次大会
    • Place of Presentation
      名古屋
    • Related Report
      2012 Research-status Report
  • [Book] 機能性セルロース次元材料の開発と応用2013

    • Author(s)
      西尾嘉之,杉村和紀,寺本好邦
    • Total Pages
      239
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Research-status Report
  • [Book] セルロースのおもしろ科学とびっくり活用2012

    • Author(s)
      寺本好邦(共著)
    • Total Pages
      223
    • Publisher
      講談社
    • Related Report
      2012 Research-status Report
  • [Remarks] バイオマス変換学研究室

    • URL

      http://www.abios.gifu-u.ac.jp/biomass/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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