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Highly selective cryogenic reactions in solid hydrogen on pseudo cosmic dust surface

Research Project

Project/Area Number 23600005
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Quantum beam science
Research InstitutionNagoya University

Principal Investigator

KUMAGAI Jun  名古屋大学, エコトピア科学研究所, 准教授 (20303662)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordssolid parahydrogen / radical-radical reaction / cosmic dust / tunneling / distortion of lattice / ionizing radiation / electron spin resonance / ラジカル―ラジカル反応 / 原子トンネル反応 / 疑似星間塵 / トンネル拡散 / H原子 / パラ水素 / 極低温反応 / H6+水素分子イオン / Vacancy / 量子拡散 / 高選択的ラジカル-ラジカル反応 / 疑似星間塵表面 / 極低温化学反応 / 固体水素 / 電子スピン共鳴法 / 紫外線 / 放射線
Research Abstract

As a model of cosmic dust for bio-molecular growth in dark nebula at cryogenic temperature, a mixture of silica gel with solid parahydrogen was used for deterring the reactions of H atoms and other radicals at 4.2 K. We found that H atoms and methyl radicals never react in solid parahydrogen even though H atoms were diffused in solid parahydrogen. H atoms also did not react with TEMPO radicals adsorbed on the silica gels. H atoms can diffuse in solid parahydrogen only by tunneling reaction of H abstraction reaction. Solute molecules as methyl radicals or silica gels may distort the lattice structure of solid parahydrogen, to make difficult for diffusion of H atoms by the tunneling. This can be the main reason why such radical-radical reactions could not take place at 4.2 K.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (4 results)

All 2012 Other

All Presentation (2 results) Remarks (2 results)

  • [Presentation] H6+ chemistry in solid parahydrogen2012

    • Author(s)
      Jun Kumagai, Yuta Shimizu, Takayuki Kumada
    • Organizer
      The 2nd International Symposium on Electron Spin Science
    • Place of Presentation
      Matsushima, Miyagi-pref, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] 固体水素中の選択的ラジカルラジカル再結合反応

    • Author(s)
      南雅人、熊田高之、熊谷 純
    • Organizer
      第92回日本化学会春季年会
    • Place of Presentation
      横浜(慶應義塾大学日吉キャンパス・矢上キャンパス)
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://co60.nucl.nagoya-u.ac.jp/radchem/

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://co60.nucl.nagoya-u.ac.jp/radchem/

    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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