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Development of Novel Cathode-supported Solid Oxide Fuel Cell (SOFC) withLow-cost and Low Environmental Burden

Research Project

Project/Area Number 23651060
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Environmental technology/Environmental materials
Research InstitutionHirosaki University

Principal Investigator

ABULITI Abudula  弘前大学, 教授 (70565374)

Co-Investigator(Kenkyū-buntansha) GUAN Guoqing  弘前大学, 学内共同利用施設等, 准教授 (90573618)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords省エネルギー技術 / SOFC / SDC / CGO / 炭化水素燃料 / 電極反応 / 空気極支持膜 / 中国
Research Abstract

The electrical performances of cathode-supported SOFCs, fabricated in this study by a dual drying pressing method, reached to a high level in comparison with those from corresponding references. The degradation mechanism of Ni-based anode at low concentrations of CH_4 and H_2 was studied. The results show: (1)Degradation is due to the re-oxidation of Ni at high water vapor concentration; (2)Degraded anode could get recovered by burning it in O_2 followed by reduction in H_2, (3)The corresponding mechanism of the recovery was preliminary proposed. This study provides a new technique to evaluate the degradation phenomenon in methane fueled SOFCs using a simple method.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (20 results)

All 2012 2011

All Journal Article (13 results) (of which Peer Reviewed: 7 results) Presentation (7 results)

  • [Journal Article] Nickel volatilization phenomenon on the Ni-CGO anode in a cathode-supported SOFC operated at low concentrations of H_22012

    • Author(s)
      Gang Chen, Guoqing Guan, Yutaka Kasai,Abuliti Abudula
    • Journal Title

      International Journal ofHydrogen Energy

      Volume: 37(1) Pages: 477-483

    • Related Report
      2012 Final Research Report
  • [Journal Article] Performances of cathode-supported SOFC with Ni_0.5Cu_0.5-CGO anode operated in humidified hydrogen and in low concentration dry methane2012

    • Author(s)
      Gang Chen, Guoqing Guan, Yutaka Kasai, Hong-Xin You, Abuliti Abudula
    • Journal Title

      Journal of Solid State Electrochemistry

      Volume: 16(6) Pages: 2071-2077

    • Related Report
      2012 Final Research Report
  • [Journal Article] Performances of cathode-supported SOFC with Ni0.5Cu0.5-CGO anode operated in humidified hydrogen and in low concentration dry methane2012

    • Author(s)
      Gang Chen, Guoqing Guan, Yutaka Kasai, Hong-Xin You, Abuliti Abudula
    • Journal Title

      Journal of Solid State Electrochemistry

      Volume: 16(6) Issue: 6 Pages: 2071-2077

    • DOI

      10.1007/s10008-011-1615-1

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nickel volatilization phenomenon on the Ni-CGO anode in a cathode supported SOFC operated at low concentrations of H22012

    • Author(s)
      Gang Chen, Guoqing Guan, Yutaka Kasai, Abuliti Abudula
    • Journal Title

      International Journal of hydrogen energy

      Volume: 37(1) Issue: 1 Pages: 477-483

    • DOI

      10.1016/j.ijhydene.2011.09.007

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of planer cathode- supported SOFC prepared by a dual dry pressing method2011

    • Author(s)
      Gang Chen, Hong-Xin You,Yutaka Kasai, Hiroyuki Sato, Abuliti Abudula
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 509(16) Pages: 5159-5162

    • Related Report
      2012 Final Research Report
  • [Journal Article] Rapid degradation mechanism of Ni-CGO anode in low concentrations of H_2 at a high current density2011

    • Author(s)
      Gang Chen, Guoqing Guan, Shawket Abliz, Yutaka Kasai, Abuliti Abudula
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36(14) Pages: 8461-8467

    • Related Report
      2012 Final Research Report
  • [Journal Article] Degradation mechanism of Ni-based anode in low concentrations of dry methane2011

    • Author(s)
      Gang Chen, Guoqing Guan,Yutaka Kasai, Hong-Xin You
    • Journal Title

      Abuliti Abudula, Journal of Power Sources

      Volume: 196(15) Pages: 6022-6028

    • Related Report
      2012 Final Research Report
  • [Journal Article] Rapid degradation phenomenon of NiCu-Ce_0.8Gd_0.2O_1.9 anode at high p(H_2O) in different concentrations of dry methane2011

    • Author(s)
      Gang Chen, Guoqing Guan, Shawket Abliz, Yutaka Kasai, Abuliti Abudula
    • Journal Title

      Electrochimica Acta

      Volume: 56(27) Pages: 9868-9874

    • Related Report
      2012 Final Research Report
  • [Journal Article] Characterization of planer cathode-supported SOFC prepared by a dual dry pressing method2011

    • Author(s)
      Gang Chen, Hong-Xin You, Yutaka Kasai, Hiroyuki Sato,Abuliti Abudula
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 509 Pages: 5159-5162

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rapid degradation mechanism of Ni-CGO anode in low concentrations of H2 at a high current density2011

    • Author(s)
      Gang Chen, Guoqing Guan, Shawket Abliz, Yutaka Kasai, Abuliti Abudula
    • Journal Title

      International Journal of hydrogen

      Volume: 36 Pages: 8461-8467

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Degradation mechanism of Ni-based anode in low concentrations of dry methane2011

    • Author(s)
      Gang Chen, Guoqing Guan, Yutaka Kasai, HongXin You, Abuliti Abudula
    • Journal Title

      Journal of Power Sources

      Volume: 196 Pages: 6022-6028

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Review of anode catalyst development of direct methane SOFC2011

    • Author(s)
      You Hongxin, Liu Ruirui, Liu Ruijie, Abuliti Abudula
    • Journal Title

      Chinese Journal of Power Sources

      Volume: 35 Pages: 455-457

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rapid degradation phenomenon of NiCu-Ce0.8Gd0.2O1.9 anode at high p(H2O) in different concentrations of dry methane2011

    • Author(s)
      Gang Chen, Guoqing Guan, Shawket Abliz, Yutaka Kasai,Abuliti Abudula
    • Journal Title

      Electrochimica Acta

      Volume: 56 Pages: 9868-9874

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Rapid degradation phenomena of Ni_0.5Cu_0.5-GDC anode at high current density in different concentrations of dry CH_42012

    • Author(s)
      陳剛,官国清,阿布里提,葛西裕
    • Organizer
      電気化学会第79回大会講演要旨集
    • Related Report
      2012 Final Research Report
  • [Presentation] Rapid degradation phenomena of Ni0.5Cu0.5-GDC anode at high current density in different concentrations of dry CH42012

    • Author(s)
      陳剛,官国清,葛西裕,阿布里提
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松市
    • Related Report
      2011 Research-status Report
  • [Presentation] 低水素濃度領域におけるNi-CGOアノードの急速劣化現象の解明2011

    • Author(s)
      陳剛,官国清,阿布里提,葛西裕
    • Organizer
      第20回日本エネルギー学会大会講演要旨集
    • Related Report
      2012 Final Research Report
  • [Presentation] Rapid degradation phenomenon of Ni-CGO anode at a high current density with high fuel utilization2011

    • Author(s)
      G.Chen, G.Q. Guan, Y.Kasai, A. Abudula
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Niigata Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Degradation phenomenon of Ni-CGO anode in low concentrations of H22011

    • Author(s)
      G.Chen, G.Q.Guan, S.Abliz, Y. Kasai, A.Abudula
    • Organizer
      The 20th Symposium on Energy in Japan
    • Place of Presentation
      Osaka Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] 低水素濃度領域におけるNi-CGOアノードの急速劣化現象の解明2011

    • Author(s)
      陳剛,官国清,葛西裕,阿布里提
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      関西大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Rapid degradation phenomenon of Ni-CGO anode at a high current density with high fuel utilization2011

    • Author(s)
      Chen, G.Q.Guan, Y. Kasai, A.Abuliti
    • Organizer
      62nd Annual Meeting of the Inter-national Society of Electrochemistry
    • Place of Presentation
      新潟市
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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