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Development of an innovativetechnique for byproduct-glycerin separation in the production of biodiesel fuel

Research Project

Project/Area Number 23651073
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Environmental technology/Environmental materials
Research InstitutionOsaka Prefecture University

Principal Investigator

BANDOW Hiroshi  大阪府立大学, 工学研究科, 教授 (80124353)

Co-Investigator(Kenkyū-buntansha) TOKUMOTO Hayato  大阪府立大学, 工学研究科, 助教 (70405348)
Research Collaborator KURAHASHI Kensuke  大阪府立大学工業高等専門学校, 講師 (60516821)
WAKAMATSU Takahiko  大阪ガスエンジニアリング株式会社, エネルギー環境本部・エネルギー営業技術部, 課長 (30716270)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords再生可能エネルギー / バイオ燃料 / ディーゼル代替燃料 / 製造プロセス / グリセリン分離 / 廃食用油 / 超音波技術 / 廃棄物資源化 / 循環型社会 / 地球温暖化
Research Abstract

New findings that introduction of granular charcoals or those coated with hydrophilic substances, such as titanium-oxides- or methyl-silicates-coating reagents, into the reaction mixtures of trans-esterification reaction between waste-cooking oils and methanol stimulates the abrupt formation of floating foams on the reaction mixture surface. In addition, it is found that the composition of the floating foams consists almost exclusively of glycerin, demonstrating that these substances act as accelerating agents for the separation of by-product glycerin from the product of the trans-esterification reaction, that is, free fatty acid methyl esters. The glycerin floating on the surface of the reaction mixture as foams can be easily wiped out from the surface physically, and therefore, this phenomenon could be a potential candidate for a new technique of glycerin separation with simple and less-energy consuming process.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (24 results)

All 2013 2012 2011 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (9 results) (of which Invited: 3 results) Book (4 results)

  • [Journal Article] 学内メタン発酵プラントを用いた食品厨芥のエネルギー化実証試験2013

    • Author(s)
      倉橋健介, 木村知恵, 柏木麻衣, 野村俊之, 若松孝彦, 小手川勉, 永吉勝明, 坂東博, 徳本勇人
    • Journal Title

      環境技術

      Volume: 42巻 Pages: 355-361

    • NAID

      10031174473

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A new co-solvent method for the green production of biodiesel fuel-optimization and practical application2013

    • Author(s)
      T. Le Tu, K. Okitsu, Y. Sadanaga, N. Takenaka, Y. Maeda, H. Bandow
    • Journal Title

      Fuel

      Volume: Vol. 103 Pages: 742-748

    • URL

      http://dx.doi.org/10.1016/j.fuel.2012.09.029

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 半回分培養によるグリセリンの嫌気発酵分解・資源化2013

    • Author(s)
      柏木麻衣,倉橋健介,野村俊之,徳本勇人
    • Journal Title

      環境技術

      Volume: 42巻 Pages: 94-100

    • NAID

      10031154960

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A new co-solvent method for the green production of biodiesel fuel ― optimization and practical application2013

    • Author(s)
      T. Le Tu, K. Okitsu, Y. Sadanaga, N. Takenaka, Y. Maeda, H. Bandow
    • Journal Title

      Fuel

      Volume: 103 Pages: 742-748

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 半回分培養によるグリセリンの嫌気発酵分解・資源化2013

    • Author(s)
      柏木麻衣,倉橋健介,野村俊之,徳本勇人
    • Journal Title

      環境技術

      Volume: 42 Pages: 94-100

    • NAID

      10031154960

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Changes in dominant fermentation type during anaerobic digestion of high-loading glycerol with slight glucose content2012

    • Author(s)
      H. Tokumoto, M. Kashiwagi
    • Journal Title

      Bioresource Technol

      Volume: Vol. 126 Pages: 13-17

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anaerobic bioconversion to value-added byproducts from two promising biomass in the future, crude glycerol and sewage sludge2012

    • Author(s)
      H. Tokumoto, C. Kimura
    • Journal Title

      J. Environ. Biotechnol

      Volume: Vol. 12 Pages: 141-146

    • NAID

      40019972042

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Novel anaerobic digestion induced by bacterial components for value- added byproducts from high loading glycerol2012

    • Author(s)
      H. Tokumoto
    • Journal Title

      Bioresource Technol

      Volume: Vol. 107 Pages: 327-332

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Changes in dominant fermentation type during anaerobic digestion of high-loadingglycerol with slight glucose content2012

    • Author(s)
      H. Tokumoto, M. Kashiwagi
    • Journal Title

      Bioresource Technology

      Volume: 126 Pages: 13-17

    • DOI

      10.1016/j.biortech.2012.09.028

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anaerobic bioconversion to value-added byproducts from two promising biomass in the future, crude glycerol and sewage sludge2012

    • Author(s)
      H. Tokumoto, C. Kimura
    • Journal Title

      Journal of Environmental Biotechnology

      Volume: 12 Pages: 141-146

    • NAID

      40019972042

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel anaerobic digestion induced by bacterial components for value-added byproducts from high-loading glycerol2012

    • Author(s)
      H. Tokumoto
    • Journal Title

      Bioresource Technology

      Volume: 107 Pages: 327-332

    • DOI

      10.1016/j.biortech.2011.12.051

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 超音波を使って家庭の廃食用油から高品質バイオディーゼル燃料を省エネ製造2013

    • Author(s)
      坂東博
    • Organizer
      関東経産局・(財)日本立地センター知的財産フォーラム
    • Place of Presentation
      東京
    • Year and Date
      2013-02-20
    • Related Report
      2012 Final Research Report
  • [Presentation] "生協発"資源循環プロセスの構築~食品厨芥のエネルギー化とその活用~2013

    • Author(s)
      徳本勇人
    • Organizer
      生協総研賞・第9回助成事業論文報告会
    • Place of Presentation
      東京
    • Year and Date
      2013-02-15
    • Related Report
      2012 Final Research Report
  • [Presentation] BDF 製造時に副生する廃グリセリンの資源・エネルギー化2012

    • Author(s)
      徳本勇人
    • Organizer
      第2回化学工学会関西支部技術シーズフォーラム
    • Place of Presentation
      豊中
    • Year and Date
      2012-10-31
    • Related Report
      2012 Final Research Report
  • [Presentation] 廃グリセリンと下水汚泥を同時に処理する新規嫌気発酵プロセスの構築2011

    • Author(s)
      木村知恵
    • Organizer
      廃棄物資源循環学会
    • Place of Presentation
      東京
    • Year and Date
      2011-11-05
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] 嫌気発酵を用いた過負荷グリセリン分解の促進と制御技術の開発2011

    • Author(s)
      柏木麻衣
    • Organizer
      日本生物工学会
    • Place of Presentation
      東京
    • Year and Date
      2011-09-28
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] 下水汚泥と廃グリセリンを同時に処理する新規嫌気発酵プロセスの構築2011

    • Author(s)
      木村知恵
    • Organizer
      環境バイテクノロジー学会
    • Place of Presentation
      東京
    • Year and Date
      2011-06-20
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] 超音波を使って家庭の廃食用油から高品質バイオディーゼル燃料を省エネ製造

    • Author(s)
      坂東 博
    • Organizer
      関東経産局、(財)日本立地センター 知的財産フォーラム
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] “生協発”資源循環プロセスの構築~食品厨芥のエネルギー化とその活用~

    • Author(s)
      徳本勇人
    • Organizer
      生協総研賞・第9回助成事業論文報告会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] BDF製造時に副生する廃グリセリンの資源・エネルギー化

    • Author(s)
      徳本勇人
    • Organizer
      第2回化学工学会関西支部技術シーズフォーラム
    • Place of Presentation
      豊中
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Book] 中小企業のための技術宝箱 大学・高等専門学校の特許30選解説集 「超音波を使って家庭の廃食用油から高品質バイオディーゼル燃料を省エネ製造」2013

    • Author(s)
      坂東 博
    • Total Pages
      6
    • Publisher
      経済産業省関東経済産業局編
    • Related Report
      2012 Annual Research Report
  • [Book] Biodiesel - Feedstocks, Production and applica- tions2012

    • Author(s)
      H. Tokumoto, H. Bandow, K. Kurahashi, T. Wakamatsu
    • Total Pages
      21
    • Publisher
      InTech
    • Related Report
      2012 Final Research Report
  • [Book] Biodiesel - Feedstocks, Production and Applications, Edited by Zhen Fang, Chapter 13, "Utilization of Crude Glycerin from Biodiesel Production: A Field Test of a Crude Glycerin Recycling Process"2012

    • Author(s)
      H. Tokumoto, H. Bandow, K. Kurahashi, T. Wakamatsu
    • Total Pages
      21
    • Publisher
      InTech
    • Related Report
      2012 Annual Research Report
  • [Book] 社会との垣根を越える大学の挑戦2011

    • Author(s)
      徳本勇人(分担)
    • Total Pages
      343
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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