Chiral molecular thin films prepared by vapor deposition polymerization with selective adsorption
| Project/Area Number |
23651090
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Nanostructural science
|
|---|
| Research Institution | Shizuoka University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
|---|
| Keywords | 表面 界面ナノ構造 / 薄膜 / キラル / 蒸着 / ポリアミド / 高分子 / 蒸着重合 / 選択吸着 / 配向 / 成膜機構 |
|---|
| Research Abstract |
Thin polymeric films with chirality were prepared by vapor deposition polymerization. Helix structures were formed in the polyamide films from racemic monomers. This resultindicates that the selective adsorption and reaction of a specific optical isomer occurred locally on the substrate and within the bulk. Moreover the quartz crystal microbalance technique realized the in-situ observation of the initial stage in film formation and provides important parameters for molecular adsorption and orientation.
|
Report
(3 results)
Research Products
(19 results)
