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A Molecular-Sized Tunnel-Porous Crystal with a Ratchet Gear Structure and Its One-way Guest-Molecule Transportation Property

Research Project

Project/Area Number 23651113
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials/Nanobioscience
Research InstitutionOkayama University

Principal Investigator

KATAGIRI Toshimasa  岡山大学, 大学院・自然科学研究科, 准教授 (70202009)

Project Period (FY) 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords結晶工学 / 有機フッ素化合物 / ブラウニアン・ラチェット / ブラウニアン・ポンプ / 異方性ナノ細孔 / ボトムアップ・ナノテクノロジー / 熱の高度利用 / 単結晶X線構造解析 / 異方性細孔
Research Abstract

Using the crystal engineering process, we constructed an asymmetric tunnel crystal that acted as a molecular-sized linear ratchet motor. The crystal changed the distribution of guest molecules from uniformly distributed to distributed on only one side in a macro-length tunnel. Here, the guest molecules in the tunnel should be stabilized equally by the tunnel wall. The guest molecules simply changed their locations in the tunnel. The movement of the guest molecules would be caused by thermal fluctuation of the crystal lattice.

Report

(2 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • Research Products

    (9 results)

All 2011

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (5 results)

  • [Journal Article] New strategy of storage of hydrogen molecules : utilization of mechanosorption of molecules in micropores2011

    • Author(s)
      Toshimasa Katagiri, Keisuke Kataoka
    • Journal Title

      ENEOS Technical Review

      Volume: Vol.53 Pages: 63-65

    • Related Report
      2011 Final Research Report
  • [Journal Article] A Crystal Engineering Weaving of Half-Spiral Molecules by Hydrogen Bonding Chains into Tube Structures2011

    • Author(s)
      Keisuke Kataoka, Masato Yanagi, Toshimasa Katagiri
    • Journal Title

      Cryst Eng Comm

      Volume: Vol.13 Pages: 6342-6344

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] New strategy of storage of hydrogen molecules : utilization of mechanoso rption of molecules in micropores2011

    • Author(s)
      Toshimasa Katagiri, Keisuke Kataoka
    • Journal Title

      ENEOS Technical Review

      Volume: 53 Pages: 63-65

    • Related Report
      2011 Annual Research Report
  • [Journal Article] A Crystal Engineering Weaving of Half-Spiral Molecules by Hydrogen Bonding Chains into Tube Structures2011

    • Author(s)
      Keisuke Kataoka, Masato Yanagi, Toshimasa Katagiri
    • Journal Title

      CrystEngComm (RSC)

      Volume: 13 Pages: 6342-6344

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] A Fluoroorganic Crystal Enigineering, 242nd ACS National Meeting2011

    • Author(s)
      Toshimasa Katagiri, Keisuke Kataoka
    • Organizer
      Symposium to honor Don Burton's contributions to fluorine chemistry
    • Place of Presentation
      Denver CO USA
    • Year and Date
      2011-08-29
    • Related Report
      2011 Final Research Report
  • [Presentation] A Fluoroorganic Crystal Enigineering2011

    • Author(s)
      Toshimasa Katagiri, Keisuke Katacka
    • Organizer
      242nd ACS National Meeting Symposium to honor Don Burton's contributions to fluorine chemistry
    • Place of Presentation
      Denver, CO.USA
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] フッ素トンネルの機能開発2011

    • Author(s)
      片岡啓介, 片桐利真
    • Organizer
      日本学術振興会第155委員会第86回研究集会
    • Place of Presentation
      京都大学紫蘭会館
    • Year and Date
      2011-07-29
    • Related Report
      2011 Final Research Report
  • [Presentation] フッ素トンネルの機能開発2011

    • Author(s)
      片岡啓介、片桐利真
    • Organizer
      日本学術振興会第155委員会第86回研究集会(京都)
    • Place of Presentation
      京都大学紫蘭会館
    • Year and Date
      2011-07-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機フッ素化合物の結晶工学動的細孔機能の創出に向けて2011

    • Author(s)
      片桐利真
    • Organizer
      大阪市立大学セミナー
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2011-04-27
    • Related Report
      2011 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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