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Characterization and Manipulation of Graphene Edge by Electrochemistry

Research Project

Project/Area Number 23651125
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials/Nanobioscience
Research InstitutionNTT Basic Research Laboratories

Principal Investigator

FURUKAWA Kazuaki  日本電信電話株式会社NTT物性科学基礎研究所, 機能物質科学研究部, 主任研究員 (40393748)

Co-Investigator(Kenkyū-buntansha) HIBINO Hiroki  日本電信電話株式会社NTT物性科学基礎研究所, 機能物質科学研究部, 主幹研究員 (60393740)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsグラフェン / 電気化学 / ナノ表面・界面 / エッジ修飾
Research Abstract

We aimed at distinguishing the responses from graphene basal plane and graphene edge when the graphene is used as an electrochemical electorde. Our idea is to use the interdigitated graphene electrodes with the same basal plane area but different edge lengths. We have designed such electrodes and developed the fabrication processes. We have observed the electrochemical signals assignable to the low dimensional structures from some of the electrodes. In parallel, we fabricated the interdigitated electrodes whose surface are fully covered by reduced graphene oxide. We have confirmed the difference in electrochemical responses depending on the redox species from the electrodes. The electrodes have been applied to the detection of cortisol, a stress marker.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (22 results)

All 2013 2012 2011 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (15 results) Remarks (2 results)

  • [Journal Article] Graphene-modified Interdigitated Array Electrode: Fabrication, Characterization, and Electrochemical Immunoassay Application2013

    • Author(s)
      Yuko Ueno, Kazuaki Furukawa, Katsuyoshi Hayashi, Makoto Takamura, Hiroki Hibino, Emi Tamechika
    • Journal Title

      Anal. Sci

      Volume: 29 Pages: 344-347

    • NAID

      10031147326

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Graphene-modified Interdigitated Array Electrode: Fabrication, Characterization, and Electrochemical Immunoassay Application2013

    • Author(s)
      Yuko Ueno, Kazuaki Furukawa, Katsuyoshi Hayashi, Makoto Takamura, Hiroki Hibino, Emi Tamechika
    • Journal Title

      Analytical Sciences

      Volume: 29 Issue: 1 Pages: 55-60

    • DOI

      10.2116/analsci.29.55

    • NAID

      10031147326

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self- Spreading of Supported Lipid Bilayer on SiO2 Surface Bearing Graphene Oxide2012

    • Author(s)
      Kazuaki Furukawa, Hiroki Hibino
    • Journal Title

      Chem. Lett.

      Volume: 41(accepted) Pages: 1259-1261

    • NAID

      130004426361

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Near-Infrared Photoluminescence Spectral Imaging of Chemically Oxidized Graphene Flakes2012

    • Author(s)
      Yuko Ueno, Emi Tamechika, Kazuaki Furukawa, Satoru Suzuki, Hiroki Hibino
    • Journal Title

      e-J. Surf. Sci. Nanotech.

      Volume: 10 Pages: 513-517

    • NAID

      130004933754

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Spreading of Supported Lipid Bilayer on SiO2 Surface Bearing Graphene Oxide2012

    • Author(s)
      Kazuaki Furukawa, Hiroki Hibino
    • Journal Title

      Chem. Lett.

      Volume: 41 Issue: 10 Pages: 1259-1261

    • DOI

      10.1246/cl.2012.1259

    • NAID

      130004426361

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Near-Infrared Photoluminescence Spectral Imaging of Chemically Oxidized Graphene Flakes2012

    • Author(s)
      Yuko Ueno, Kazuaki Furukawa, Satoru Suzuki, Hiroki Hibino, Emi Tamechika
    • Organizer
      6th International Symposium on Surface Science
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2012-12-12
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] Siステップ/酸化グラフェン微小段差表面における自発展開挙動2012

    • Author(s)
      古川一暁, 日比野 浩樹,
    • Organizer
      日本化学会 第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] グラフェン修飾くし形電極を用いた生体関連物質の高感度検出2012

    • Author(s)
      上野祐子, 古川一暁, 日比野浩樹, 為近恵美
    • Organizer
      日本化学会 第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 酸化グラフェンを有するSiO2表面での脂質二分子膜の自発展開挙動2012

    • Author(s)
      古川一暁, 日比野 浩樹
    • Organizer
      第59回 応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 電極表面への酸化グラフェン還元膜修飾による酵素反応生成物の高感度検出2012

    • Author(s)
      上野祐子, 林勝義, 高村真琴, 古川一暁, 日比野浩樹, 為近恵美
    • Organizer
      日本分析化学会第72回分析化学討論会
    • Place of Presentation
      鹿児島
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 酸化グラフェン還元体を修飾した金くし形マイクロ電極の電気化学特性2012

    • Author(s)
      高村真琴, 上野祐子, 林勝義, 古川一暁, 日比野浩樹, 為近恵美
    • Organizer
      化学とマイクロ・ナノシステム研究会
    • Place of Presentation
      熊本
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Self-Spreading of Supported Lipid Bilayer on SiO2 Surface Bearing Graphene Oxide2012

    • Author(s)
      K. Furukawa, H. Hibino
    • Organizer
      IACIS2012
    • Place of Presentation
      仙台
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化グラフェンを有するSiO2表面での脂質二分子膜の自発展開挙動2012

    • Author(s)
      古川一暁,日比野 浩樹
    • Organizer
      第59回 応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Siステップ/酸化グラフェン微小段差表面における自発展開挙動2012

    • Author(s)
      古川一暁,日比野 浩樹
    • Organizer
      日本化学会 第92春季年会
    • Place of Presentation
      慶応大学
    • Related Report
      2011 Research-status Report
  • [Presentation] グラフェン修飾くし形電極を用いた生体関連物質の高感度検出2012

    • Author(s)
      上野祐子,古川一暁,日比野浩樹,為近恵美
    • Organizer
      日本化学会 第92春季年会
    • Place of Presentation
      慶応大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Graphene as an Electrochemical Electrode2011

    • Author(s)
      Kazuaki Furukawa, Hiroki Hibino
    • Organizer
      220th Meeting of The Electrochemical Society
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-10-10
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] グラフェン修飾金くし形電極チップの作製法および電極特性2011

    • Author(s)
      上野祐子, 古川一暁, 日比野浩樹, 為近恵美
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-16
    • Related Report
      2012 Final Research Report 2011 Research-status Report
  • [Presentation] 電気化学における作用電極としてのグラフェンの基本特性2011

    • Author(s)
      古川一暁, 日比野浩樹
    • Organizer
      第72回 応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] 電気化学における作用電極としてのグラフェンの基本特性2011

    • Author(s)
      古川一暁,日比野浩樹
    • Organizer
      第72回 応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Self- Spreading of Supported Lipid Bilayer on SiO2 Surface Bearing Graphene Oxide

    • Author(s)
      Kazuaki Furukawa, Hiroki Hibino
    • Organizer
      IACIS2012
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.brl.ntt.co.jp/J/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks] Kazuaki Furukawa's Home Page

    • URL

      http://www.brl.ntt.co.jp/people/furukawa/top.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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