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Production and detection of rovibrationally cold molecular ions usinga cryogenic liear ion trap

Research Project

Project/Area Number 23654144
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Atomic/Molecular/Quantum electronics
Research InstitutionSophia University

Principal Investigator

OKADA Kunihiro  上智大学, 理工学部, 准教授 (90311993)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsイオントラップ / クーロン結晶 / 分子イオン / 共同冷却
Research Abstract

We have developed a compact cryogenic linear ion trap to producerovibrationally cold molecular ions embeded in an ion Coulomb crystal. First, the compact cryogeniclinear ion trap with double radiation shields was newly developed and was connected to a 10 Kcryocooler. Then, we performed laser cooling experiments of trapped Ca+ions. We have successfullygenerated Ca+Coulomb crystals containing more than a few thousands ions under low-temperatureenvironments of about 50 K. We also succeeded in producing cold CaH+ions, which are generated bylaser-induced reactions between Ca+*(2P1/2) and H2 molecules. A few thousands of cold CaH+ions aremaintained over one hour under the low-temperature environments. The results imply that thepopulation of the rotational ground state (J = 0) of CaH+is increased to 13%, while the roomtemperature population is only 2%. It is noted that in this condition the sum of J = 0-3 populationreaches to 90% and the vibrational ground state is attained (the vibrational constant is about 0.18 eV).This is an important achievement to perform rovibrational spectroscopy of CaH+.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (27 results)

All 2013 2012 2011

All Journal Article (7 results) (of which Peer Reviewed: 3 results) Presentation (20 results) (of which Invited: 1 results)

  • [Journal Article] Cold ion-polar-molecule reactions studiedwith a combined Stark-velocity-filter-ion-trap apparatus2013

    • Author(s)
      K. Okada, T. Suganuma, T. Furukawa, T.Takayanagi, M. Wada, H. A. Schuessler
    • Journal Title

      Physical Review A87

      Volume: 043427 Pages: 14-14

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Laser-induced reactions between a Ca+ Coulomb crystal and polar molecules2012

    • Author(s)
      K. Okada et al.
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 388 Issue: 1 Pages: 6-6

    • DOI

      10.1088/1742-6596/388/1/012025

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Laser-induced reactions between a Ca^+ Coulomb crystal and ammonia molecules2012

    • Author(s)
      N. Kimura, K. Okada, H.A. Schuessler, M.Wada
    • Journal Title

      RIKEN Accelerator Progress Report

      Volume: 45 Pages: 1-1

    • Related Report
      2012 Final Research Report
  • [Journal Article] Laser-induced reactions between a Ca+ Coulomb crystal and ammonia molecules2012

    • Author(s)
      N. Kimura, K. Okada et al.
    • Journal Title

      RIKEN Accelerator Progress Report

      Volume: 45 Pages: 178-178

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Stark velocity filter for producing slowpolar molecules2011

    • Author(s)
      T. Suganuma, K. Okada, T.Takayanagi, S. Ohtani, H. A. Schuessler, M.Wada
    • Journal Title

      RIKEN Accelerator Progress Report

      Volume: 44 Pages: 1-1

    • Related Report
      2012 Final Research Report
  • [Journal Article] Sympathetic crystallization of CaH^+ in alinear Paul trap2011

    • Author(s)
      N. Kimura, K. Okada, T.Takayanagi, S. Ohtani, H. A. Schuessler, M.Wada
    • Journal Title

      RIKEN Accelerator Progress Report

      Volume: 44 Pages: 1-1

    • Related Report
      2012 Final Research Report
  • [Journal Article] Sympathetic crystallization of CaH+ in a linear Paul trap2011

    • Author(s)
      N. Kimura, K. Okada, T. Takayanagi, S. Ohtani, H. A. Schuessler, M. Wada
    • Journal Title

      RIKEN Accelerator Progress Report

      Volume: 44

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Study of cold ion chemistryusing ion traps2013

    • Author(s)
      K. Okada
    • Organizer
      One-day symposium onE-ring based molecular science
    • Place of Presentation
      TokyoMetropolitan University (TMU), Tokyo
    • Year and Date
      2013-02-07
    • Related Report
      2012 Final Research Report
  • [Presentation] 低速極性分子と共同冷却分子イオンの反応速度測定II2013

    • Author(s)
      市川雅成, 古川貴浩, 和田道治, H. A.Schuessler, 岡田邦宏
    • Organizer
      日本物理学会 2013 年第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Final Research Report
  • [Presentation] 低速極性分子と共同冷却分子イオンの反応速度測定II2013

    • Author(s)
      市川雅成、岡田邦宏 他
    • Organizer
      日本物理学会2013年第68回年次大会
    • Place of Presentation
      広島大学、東広島
    • Related Report
      2012 Annual Research Report
  • [Presentation] シュタルク分子速度フィルタ-を用いた極低温分子イオン-極性分子反応の研究2012

    • Author(s)
      古川貴浩,市川雅成,和田道治,H. A.Schuessler, 岡田邦宏
    • Organizer
      分子分光研究会
    • Place of Presentation
      上智大学
    • Year and Date
      2012-05-18
    • Related Report
      2012 Final Research Report
  • [Presentation] Cold ion chemistry using the iontrap technique2012

    • Author(s)
      K. Okada
    • Organizer
      Workshop on InterstellarMatter (ISM2012)
    • Place of Presentation
      Hokkaido University, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] Cold chemical reactions betweensympathetically cooled molecular ions andslow polar molecules2012

    • Author(s)
      K. Okada
    • Organizer
      19th InternationalMass Spectrometry Conference (IMSC2012)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] A study of coldion-polar molecule reactions betweensympathetically cooled molecular ions andslow polar molecules2012

    • Author(s)
      K. Okada, T. Furukawa, M. Ichikawa, M.Wada, H. A. Schuessler
    • Organizer
      Mo-169, 23ndInternational Conference on Atomic Physics(ICAP2012)
    • Place of Presentation
      Ecolle Polytechnique,Palaiseau, France
    • Related Report
      2012 Final Research Report
  • [Presentation] 低速極性分子と共同冷却分子イオンの反応速度測定2012

    • Author(s)
      Palaiseau, France, 23-27 July, 2012.(8) 古川貴浩, 市川雅成, 和田道治, H. A.Schuessler, 岡田邦宏
    • Organizer
      日本物理学会2012年第67回年次大会
    • Place of Presentation
      関西学院大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Laser-induced reactions between a Ca^+ Coulomb crystal and polar molecules2012

    • Author(s)
      N. Kimura, K. Okada, K. Shiina, T.Suganuma, M. Wada, H. A. Schuessler
    • Place of Presentation
      Belfast, Northern Ireland,UK
    • Related Report
      2012 Final Research Report
  • [Presentation] Cold ion chemistry using the ion trap technique2012

    • Author(s)
      K. Okada
    • Organizer
      Workshop on Interstellar Matter (ISM2012)
    • Place of Presentation
      Hokkaido University, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Cold chemical reactions between sympathetically cooled molecular ions and slow polar molecules2012

    • Author(s)
      K. Okada
    • Organizer
      19th International Mass Spectrometry Conference (IMSC2012)(依頼講演)
    • Place of Presentation
      Kyoto International Conference Center, Kyoto, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] A study of cold ion-polar molecule reactions between sympathetically cooled molecular ions and slow polar molecules2012

    • Author(s)
      K. Okada et al.
    • Organizer
      23nd International Conference on Atomic Physics (ICAP2012)
    • Place of Presentation
      Ecolle Polytechnique, Palaiseau, France
    • Related Report
      2012 Annual Research Report
  • [Presentation] 低速極性分子と共同冷却分子イオンの反応速度測定2012

    • Author(s)
      古川貴浩、岡田邦宏 他
    • Organizer
      日本物理学会2012年第67回年次大会
    • Place of Presentation
      関西学院大学、兵庫
    • Related Report
      2012 Annual Research Report
  • [Presentation] シュタルク分子速度フィルタ-を用いた 極低温分子イオン-極性分子反応の研究2012

    • Author(s)
      岡田邦宏 他
    • Organizer
      分子分光研究会
    • Place of Presentation
      上智大学、東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] Laser-induced reactions betweena Ca+Coulomb crystal and polar molecules2011

    • Author(s)
      K. Okada
    • Organizer
      Electronic and Atomic Collisions (ICPEAC2011)
    • Place of Presentation
      Belfast,Northern Ireland, UK
    • Related Report
      2012 Final Research Report
  • [Presentation] Status and outlook: Sophia RFtrap and collisions involving coulombiccrystals2011

    • Author(s)
      K. Okada
    • Organizer
      4th International Workshop onElectrostatic Storage Devices (ESD 2011)
    • Place of Presentation
      Gatlinburg, Tennessee, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] Ca^+ クーロン結晶と極性分子のレーザー誘起反応の測定2011

    • Author(s)
      木村直樹, 椎名皓一, 高柳俊暢, 和田道治 A, H.A.SchuesslerB, 岡田邦宏
    • Organizer
      日本物理学会 2011 年秋季大会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Final Research Report
  • [Presentation] シュタルク分子速度フィルターを用いた低速極性分子とCa+クーロン結晶の反応測定2011

    • Author(s)
      古川貴浩, 菅沼拓也, 岡田邦宏, 和田道治, H. A. Schuessler
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Final Research Report
  • [Presentation] A Stark velocity filter for studying cold polarmolecule-molecular ion reactions2011

    • Author(s)
      T. Suganuma, K. Okada, N. Kimura, K.Shiina, M. Wada, H. A. Schuessler
    • Organizer
      Electronic and Atomic Collisions(ICPEAC 2011)
    • Place of Presentation
      Belfast, Northern Ireland, UK
    • Related Report
      2012 Final Research Report
  • [Presentation] Status and outlook: Sophia RF trap and collisions involving coulombic crystals2011

    • Author(s)
      K. Okada
    • Organizer
      4th International Workshop on Electrostatic Storage Device (ESD 2011)(招待講演)
    • Place of Presentation
      Gatlinburg, Tennessee, USA
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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