• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of vacuum-ultraviolet-pulse field ionization spectroscopy toward molecular understandings of water

Research Project

Project/Area Number 23655002
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

MATSUDA Yoshiyuki  東北大学, 大学院・理学研究科, 助教 (70400223)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsクラスター / 電場イオン化 / 真空紫外光 / 水 / 水クラスター / 振動分光 / 光イオン化
Research Abstract

Toward size-selective spectroscopy of the water clusters, the pulse switch system to generate a high voltage pulse was built and applied to the time-of-flight mass spectrometer. The rare gas cell and the mercury cell were made for generation of the vacuum-ultraviolet light. To demonstrate the spectroscopy, we have performed the size-selected infrared spectroscopy for clusters of hydrogen sulfide (H2S), as the model of water clusters. The proton donor ability of H2S has been revealed through the size-selective infrared spectroscopy of its clusters.With these home-made gas cell and high voltage pulse source, the vacuum-ultraviolet pulse field ionization spectroscopy was developed. These methods developed in this study will be applied to the clusters of water.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (22 results)

All 2013 2012 2011 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (19 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] The Intermolecular SH-Y (Y=S,O) Hydrogen Bond in the H2S Dimer and the H2S-MeOH Complex2013

    • Author(s)
      Aditi Bhattacherjee, Yoshiyuki Matsuda, Asuka Fujii, Sanjay Wategaonkar
    • Journal Title

      ChemPhysChem

      Volume: 14 Issue: 5 Pages: 905-914

    • DOI

      10.1002/cphc.201201012

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and theoreticalinvestigations of isomerization reactions of ionized acetone and its dimer2012

    • Author(s)
      Yoshiyuki Matsuda, Kunihito Hoki, Satoshi Maeda, Ken-ichi Hanaue, Keisuke Ohta, Keiji Morokuma, Naohiko Mikami, Asuka Fujii
    • Journal Title

      Phys. Chem.Chem.Phys

      Volume: 14 Issue: 2 Pages: 712-719

    • DOI

      10.1039/c1cp22953b

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Infrared spectroscopic investigation for ionization dynamics of molecular clusters: isomerization andproton-transfer on ionization process2013

    • Author(s)
      Yoshiyuki Matsuda
    • Organizer
      Spectroscopy and Dynamics of Molecules& Clusters
    • Place of Presentation
      Udaipur, India
    • Year and Date
      2013-02-24
    • Related Report
      2012 Final Research Report
  • [Presentation] nfrared spectroscopic investigation for ionization dynamics of molecular clusters: isomerization and proton-transfer on ionization process2013

    • Author(s)
      Yoshiyuki Matsuda
    • Organizer
      Spectroscopy and Dynamics of Molecules & Clusters
    • Place of Presentation
      Udaipur, India
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Infrared spectroscopic studies on isomerization reactions of ionized molecular clusters2012

    • Author(s)
      Yoshiyuki Matsuda、Naohiko Mikami、Asuka Fujii
    • Organizer
      19th International Mass Spectrometry Conference (IMSC2012)
    • Place of Presentation
      京都
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] ジエチルエーテルおよび硫化ジエチル正イオンの赤外分光:同族原子置換によるCH伸縮振動数の変化2012

    • Author(s)
      遠藤寛也、松田欣之、高橋開人、三上直彦、藤井朱鳥
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] ジエチルエーテル正イオンの赤外分光:内部回転によるCH結合の極性の変化2012

    • Author(s)
      松田欣之、高橋開人、遠藤寛也、三上直彦、藤井朱鳥
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-18
    • Related Report
      2012 Final Research Report
  • [Presentation] トリメチルアミンクラスター正イオンの赤外分光~異性体分離と正イオンメチル基の水素結合性~2012

    • Author(s)
      中山雄一郎、松田欣之、三上直彦、藤井朱鳥
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-18
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 真空紫外光イオン化の気相レーザー分光への応用とその展開2012

    • Author(s)
      松田欣之
    • Organizer
      次世代分子科学に向けた複合研究討論会
    • Place of Presentation
      岡崎、招待講演
    • Year and Date
      2012-03-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Infrared spectroscopic studies on isomerization reactions of ionized molecular clusters2012

    • Author(s)
      oshiyuki Matsuda, Naohiko Mikami, Asuka Fujii
    • Organizer
      19th International Mass Spectrometry Conference
    • Place of Presentation
      Kyoto
    • Related Report
      2012 Annual Research Report
  • [Presentation] ジエチルエーテル正イオンの赤外分光:内部回転によるCH結合の極性の変化2012

    • Author(s)
      松田欣之、高橋開人、遠藤寛也、三上直彦、藤井朱鳥
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] ジエチルエーテルおよび硫化ジエチル正イオンの赤外分光:同族原子置換によるCH伸縮振動数の変化2012

    • Author(s)
      遠藤寛也、松田欣之、高橋開人、三上直彦、藤井朱鳥
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Annual Research Report
  • [Presentation] 真空紫外光イオン化の気相レーザー分光への応用とその展開2012

    • Author(s)
      松田欣之
    • Organizer
      次世代分子科学に向けた複合研究討論会(招待講演)
    • Place of Presentation
      岡崎市、分子科学研究所
    • Related Report
      2011 Research-status Report
  • [Presentation] 非プロトン性分子クラスターの光イオン化誘起異性化反応-赤外分光と反応経路探索-2011

    • Author(s)
      松田欣之
    • Organizer
      化学反応経路探索のニューフロンティア
    • Place of Presentation
      札幌、招待講演
    • Year and Date
      2011-09-24
    • Related Report
      2012 Final Research Report
  • [Presentation] 真空紫外一光子イオン化により生成した(ジエチルエーテル)n+,n=1-3の赤外分光2011

    • Author(s)
      松田欣之、中山雄一郎、三上直彦、藤井朱鳥
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-22
    • Related Report
      2012 Final Research Report
  • [Presentation] 正イオン状態におけるメチル基の水素結合性 ~中性および正イオン のトリメチルアミン二量体の赤外分光~2011

    • Author(s)
      中山雄一郎、松 田欣之、藤井朱鳥
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-02
    • Related Report
      2012 Final Research Report
  • [Presentation] 非プロトン性分子クラスターの光イオン化誘起異性化反応-赤外分光と反応経路探索-2011

    • Author(s)
      松田欣之
    • Organizer
      化学反応経路探索のニューフロンティア(招待講演)
    • Place of Presentation
      北海道大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 真空紫外一光子イオン化により生成した(ジエチルエーテル)n+, n=1-3の赤外分光2011

    • Author(s)
      松田欣之、中山雄一郎、三上直彦、藤井朱鳥
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Related Report
      2011 Research-status Report
  • [Presentation] 正イオン状態におけるメチル基の水素結合性 正イオン状態におけるメチル基の水素結合性 正イオン状態におけるメチル基の水素結合性 正イオン状態におけるメチル基の水素結合性 正イオン状態におけるメチル基の水素結合性-正イオン状態におけるメチル基の水素結合性2011

    • Author(s)
      中山雄一郎、松田欣之、藤井朱鳥
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Related Report
      2011 Research-status Report
  • [Presentation] C...H...N Hydrogen bond formation in trimethylamine dimer upon one-photon ionization2011

    • Author(s)
      Yuichiro Nakayama, Yoshiyuki Matsuda, Asuka Fujii
    • Organizer
      66th International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Ohio State University, U. S. A.
    • Related Report
      2011 Research-status Report
  • [Presentation] Infrared spectroscopic study on proton-transfer reactions in ionization processes of simple binary clusters2011

    • Author(s)
      Yoshiyuki Matsuda
    • Organizer
      The 14th Asian Chemical Congress 2011(招待講演)
    • Place of Presentation
      Bangkok, Thailand
    • Related Report
      2011 Research-status Report
  • [Remarks] (1)A.Bhattacherjee,Y.Matsuda*,A.Fujii,S.Wategaonkar*,ChemPhysChem,14,905-914(2013).の論文が、ChemPhysChem誌のVolume14,Issue5のInside Coverに選ばれた。

    • URL

      http://onlinelibrary.wiley.com/doi/10.1002/cphc.v14.5/issuetoc

    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi