Magneto-optical measurement of self-organized single-molecule membrane of lanthanide single-molecule magnets using ligand-centered excited states as a probe
| Project/Area Number |
23655014
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Physical chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
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| Keywords | 電子状態 / 単分子磁石 / 4f電子 / π電子 / 分子磁性 / 励起状態 / 希土類 / フタロシアニン / 単一イオン磁石 / スピントロニクス / ｆ電子 / ポルフィリン / ランタノイド |
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| Research Abstract |
A self-organization on glass substrate has been observed for a porphyrin-double-decker single-molecule magnet (SMM), which enabled us to study single-molecule membrane of SMM by magnetic circular dichroism spectroscopy. We also discovered presence of ferro-magnetic interaction between ligand-centered (π,π*) excited state and 4f-centered magnetic moment
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Report
(3 results)
Research Products
(31 results)
