| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
Artificial large and sophisticated molecular systems, such as artificial enzyme, artificial molecular scaffold, and artificial molecular architecture are of current interest. We have developed peptide/protein-inspired building blocks such as 1,4-bis(ethynylthienyl)arenes and 4,7-dibromobenzo[b]thiophene, for construction of linked molecular systems containing main axis and various side chains. In this research, a modified synthetic route to 4,7-dibromobenzo[b]thiophene, using 1-adamantanethiol, was developed and the dibromobenzothiophene was utilized for syntheses of oligoarenes, whose structures were inspired by folding of proteins.
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