Research on Construction of Unique and Versatile 'Side Chain Sequence-defined Linked Oligoarene Systems' and Molecular Folding
| Project/Area Number |
23655026
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Tohoku University |
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Principal Investigator |
TOYOTA Kozo 東北大学, 理学(系)研究科(研究院), 教授 (50217569)
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| Project Period (FY) |
2011-04-28 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 分子建築 / 分子足場 / 人工酵素 / スペーサー / 配位子 / 高分子 / 有機典型元素化合物 / ベンゾチオフェン / 金属錯体 / 錯体触媒 |
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| Outline of Final Research Achievements |
Artificial large and sophisticated molecular systems, such as artificial enzyme, artificial molecular scaffold, and artificial molecular architecture are of current interest. We have developed peptide/protein-inspired building blocks such as 1,4-bis(ethynylthienyl)arenes and 4,7-dibromobenzo[b]thiophene, for construction of linked molecular systems containing main axis and various side chains. In this research, a modified synthetic route to 4,7-dibromobenzo[b]thiophene, using 1-adamantanethiol, was developed and the dibromobenzothiophene was utilized for syntheses of oligoarenes, whose structures were inspired by folding of proteins.
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Report
(5 results)
Research Products
(12 results)
