Synthesis and functionalization of discrete porphyrin tube

• Project/Area Number: 23655034
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Organic chemistry
• Research Institution: Kyoto University
• Principal Investigator: OSUKA Atsuhiro 京都大学, 大学院・理学研究科, 教授 (80127886)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
• Keywords: ポルフィリン / 二光子吸収 / クロスカップリング / ポルフィリンベルト / ポルフィリンチューブ / ニッケル錯体 / 亜鉛錯体 / 局面π化合物 / ナノカーボン / 電子ワイヤー

Research Abstract

We’ve achieved the synthesis of pyridine-bridgedβ,β-doubly linked porphyrin cyclic tetramer by means of Suzuki-coupling that can encapsulate C60. We’ve developed an efficient method to synthesize 3mer and studied a variety of metal complexes.

Research Products

• [Journal Article] Preferential Formation of Cyclic Trimers by Palladium-Catalyzed Oxidative Coupling Reactions of 2,18-Diethynylporphyrins (2012)
  • Author(s): S. Tokuji, H. Yorimitsu, A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 51 Issue: 49 Pages: 12357-12361
  • DOI: 10.1002/anie.201207763
  • Peer Reviewed
• [Journal Article] Hexaphyrin Fused to Two Anthracenes (2012)
  • Author(s): Naoda, K. ; Mori, H. ; Aratani, N. ; Lee, B. S. ; Kim, D. Osuka, A
  • Journal Title: Angew. Chem. Int. Ed Volume: 51 Issue: 39 Pages: 9856-9859
  • DOI: 10.1002/anie.201204446
  • Peer Reviewed
• [Journal Article] A meso-Spiro[Cyclopentadiene-Isoporphyrin] from a Phenylethynyl Porphyrin Platinum(II) Pincer Complex (2012)
  • Author(s): Anabuki, S.; Shinokubo, H.; Aratani, N.: Osuka, A
  • Journal Title: Angew. Chem. Volume: 51 Issue: 1 Pages: 3174-3177
  • DOI: 10.1002/ange.19380510103
  • Peer Reviewed
• [Journal Article] Direct meso-Alkynylation of Porphyrins Doubly Assisted by Pyridyl Coordination (2012)
  • Author(s): S. Anabuki, S. Tokuji, N. Aratani, and A. Osuka
  • Journal Title: Org. Lett. Volume: 14 Issue: 11 Pages: 2778-2781
  • DOI: 10.1021/ol301005b
  • Peer Reviewed
• [Journal Article] Directly Linked Corrole Oligomers via Facile Oxidative 3-3' Coupling Reaction (2012)
  • Author(s): Hirabayashi, S.; Omote, M.; Aratani, N.; Osuka, A.
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 85 Pages: 558-562
  • Peer Reviewed
• [Journal Article] Directly Linked Corrole Oligomers via Facile Oxidative 3-3' Coupling Reaction (2012)
  • Author(s): S. Hirabayashi, M. Omote, N. Aratani, and A. Osuka
  • Journal Title: Bull. Chem. Soc. Jpn Volume: 85 Issue: 5 Pages: 2694-2697
  • DOI: 10.1246/bcsj.20110373
  • NAID: 130004153068
  • Peer Reviewed
• [Journal Article] A Mobius Antiaromatic Complex as a Kinetically Controlled Product in Phosphorus Insertion to a [32] Heptaphyrin (2012)
  • Author(s): Tomohiro Higashino, Byung Sun Lee, Jong
  • Journal Title: Angewandte Chemie, International Edition Volume: 51 Issue: 52 Pages: 13105-13108
  • DOI: 10.1002/anie.201208147
  • Peer Reviewed
• [Journal Article] Antiaromatic Hexaphyrins and Octaphyrins Stabilized by the Hydrogen-Bonding Interactions of meso-Imidazolyl Groups (2012)
  • Author(s): Mori, H. ; Sung, Y. M. ; Lee, B. S. ; Kim, D. ; Osuka, A.
  • Journal Title: Angew. Chem. Int. Ed Volume: 51 Issue: 50 Pages: 12459-12463
  • DOI: 10.1002/anie.201207212
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed Reaction of Homopropargyl-Substituted Dicarbonyl Compounds (2012)
  • Author(s): 藤野大士、依光英樹、大須賀篤弘
  • Journal Title: Organic Letters Volume: 14 Issue: 11 Pages: 2914-2917
  • DOI: 10.1021/ol301257m
  • Peer Reviewed
• [Journal Article] Synthesis of A2B6-Type [36]Octaphyrins: Copper(II)-Metalation-Induced Fragmentation Reactions to Porphyrins and N-Fusion Reactions of meso-(3-Thienyl) Substituents (2012)
  • Author(s): H. Mori, N. Aratani, and A. Osuka
  • Journal Title: Chem. Asian J Volume: 7 Issue: 6 Pages: 1340-1346
  • DOI: 10.1002/asia.201100919
  • Peer Reviewed
• [Journal Article] Effective meso Fabrications of Subporphyrins (2012)
  • Author(s): Kitano, M.; Hayashi, S.; Tanaka, T.; Yorimitsu, H.; Aratani, N.; Osuka, A
  • Journal Title: Angew. Chem. Int. Ed. Volume: 51 Issue: 23 Pages: 5593-5597
  • DOI: 10.1002/anie.201201853
  • Peer Reviewed
• [Journal Article] Regioselective Palladation of a Moebius Aromatic [28]Hexaphyrin(1.1.1.1.1.1) PdII Complex (2012)
  • Author(s): T. Tanaka and A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 18 Issue: 23 Pages: 7036-7040
  • DOI: 10.1002/chem.201200762
  • Peer Reviewed
• [Journal Article] An Electron-Deficient Porphyrin Tape (2012)
  • Author(s): H. Mori, T. Tanaka, N. Aratani, B. S. Lee, P. Kim, D. Kim, and A. Osuka
  • Journal Title: Chem. Asian. J. Volume: 7 Issue: 8 Pages: 1811-1816
  • DOI: 10.1002/asia.201200247
  • Peer Reviewed
• [Journal Article] Toward Ultralow-Bandgap Liquid Crystalline Semiconductors: Use of Triply Fused Metalloporphyrin Trimer-Pentamer as Extra-large π-Extended Mesogenic Motifs (2012)
  • Author(s): S. Tanaka, T. Sakurai, Y. Honsho, S. Seki, K. Kato, M. Takata, A. Osuka, and T. Aida
  • Journal Title: Chem. Eur. J. Volume: 18 Issue: 34 Pages: 10554-10561
  • DOI: 10.1002/chem.201201101
  • Peer Reviewed
• [Journal Article] Kinetically Blocked Stable Heptazethrene and Octazethrene: Closed-Shell or Open-Shell in the Ground State? (2012)
  • Author(s): Y. Li, W.-K. Heng, B. S. Lee, N. Aratani, J. L. Zafra, N. Bao, R. Lee, Y. M. Sung, Z. Sun, K.-W. Huang, R. D. Webster, J. T. Lopez Navarrete, D. Kim, A. Osuka, J. Casada, J. Ding, and J. Wu
  • Journal Title: J. Am. Chem. Soc. Volume: 134 Issue: 36 Pages: 14913-14922
  • DOI: 10.1021/ja304618v
  • Peer Reviewed
• [Journal Article] Deprotonation-Induced Aromaticity Enhancement and New Conjugated Networks in meso-Hexakis(pentafluorophenyl)[26]hexaphyrin (2012)
  • Author(s): W.-Y. Cha, J. M. Lim, M.-C. Yoon, Y. M. Sung, B. S. Lee, S. Katsumata, M. Suzuki, H. Mori, A. Osuka, Y. Ikawa, H. Furuta, and D. Kim
  • Journal Title: Chem. Eur. J Volume: 18 Issue: 49 Pages: 15838-15844
  • DOI: 10.1002/chem.201200991
  • Peer Reviewed
• [Journal Article] Calix[4]pyrroles bearing proximally meso-meso linking straps: synthesis and anion binding properties (2012)
  • Author(s): J.-Y. Park, K. Skonieczny, N. Aratani, A. Osuka, D. T. Gryko, and C.-H. Lee
  • Journal Title: Chem. Commun Volume: 48 Issue: 65 Pages: 8060-8062
  • DOI: 10.1039/c2cc33537a
  • Peer Reviewed
• [Journal Article] Synthesis of a Library of Fluorescent 2-Aryl-3-trifluoromethylnaphthofurans from Naphthols by Using a Sequential Pummerer-Annulation/Cross-Coupling Strategy and their Photophysical Properties (2012)
  • Author(s): Y. Ookubo, A. Wakamiya, H. Yorimitsu, and A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 18 Issue: 40 Pages: 12690-12697
  • DOI: 10.1002/chem.201201261
  • Peer Reviewed
• [Journal Article] Facile Synthesis of meso-Arylamino- and Alkylaminosubporphyrins (2012)
  • Author(s): M. Kitano, S. Hayashi, T. Tanaka, N. Aratani, and A. Osuka
  • Journal Title: Chem. Eur. J Volume: 18 Issue: 29 Pages: 8929-8933
  • DOI: 10.1002/chem.201201256
  • Peer Reviewed
• [Journal Article] A non-fused mono-meso-free pentaphyrin and its rhodium(I) complex (2012)
  • Author(s): Tomoki Yoneda, Hirotaka Mori, Byung Sun Lee, Min-Chul Yoon, Dongho Kim, Atsuhiro Osuka
  • Journal Title: Chemical Communications Volume: 48 Issue: 54 Pages: 6785-6787
  • DOI: 10.1039/c2cc32054a
  • Peer Reviewed
• [Journal Article] Rational Synthesis of A2B-type meso-Triarylsubporphyrins (2012)
  • Author(s): T. Tanaka, M. Kitano, S. Hayashi, N. Aratani, and A. Osuk
  • Journal Title: Org. Lett. Volume: 14 Issue: 11 Pages: 2694-2697
  • DOI: 10.1021/ol300865s
  • Peer Reviewed
• [Journal Article] Molecular engineering and solvent dependence of excitation energy hopping in self-assembled porphyrin boxes (2012)
  • Author(s): H. W. Bahng, P. Kim, Y. M. Sung, C. Maeda, A. Osuka, and D. Kim
  • Journal Title: Chem. Commun. Volume: 48 Issue: 35 Pages: 4181-4183
  • DOI: 10.1039/c2cc30834g
  • Peer Reviewed
• [Journal Article] Benzylic modifications of meso-alkyl-substituted porphyrins via oxidation with DDQ (2012)
  • Author(s): X. Peng, C. Gao, Y. Huang, J. Peng, N. Aratani, and A. Osuka
  • Journal Title: Tetrahedron Lett. Volume: 53 Issue: 9 Pages: 1156-1159
  • DOI: 10.1016/j.tetlet.2011.12.101
  • Peer Reviewed
• [Journal Article] A meso-Spiro[Cyclopentadiene-Isoporphyrin] from a Phenylethynyl Porphyrin Platinum(II) Pincer Complex (2012)
  • Author(s): S. Anabuki, H. Shinokubo, N. Aratani, and A. Osuka
  • Journal Title: Angew. Chem. Int. Ed. Volume: 51 Issue: 13 Pages: 3174-3177
  • DOI: 10.1002/anie.201109091
  • Peer Reviewed
• [Journal Article] 1,4-Phenylene-Bridged Hexaphyrin Dimers (2012)
  • Author(s): H. Mori, N. Aratani, and A. Osuka
  • Journal Title: Eur. J. Org. Chem Volume: 10 Issue: 10 Pages: 1913-1919
  • DOI: 10.1002/ejoc.201200080
  • Peer Reviewed
• [Journal Article] Aromatic-to-Antiaromatic Switching in Triply Linked Porphyrin Bis (rhodium(I)) Hexaphyrin Hybrids (2012)
  • Author(s): Takayuki Tanaka, Naoki Aratani, Atsuhiro Osuka
  • Journal Title: Chemistry-An Asian Journal Volume: 7 Issue: 5 Pages: 889-893
  • DOI: 10.1002/asia.201101039
  • Peer Reviewed
• [Journal Article] Ensemble and Single-Molecule Spectroscopic Study on Excitation Energy Transfer Processes in 1,3-Phenylene-Linked Perylenebisimide Oligomers (2012)
  • Author(s): H. W. Bahng, M.-C. Yoon, J.-E. Lee, Y. Murase, T. Yoneda, H. Shinokubo, A. Osuka, and D. Kim
  • Journal Title: J. Phys. Chem. B Volume: 116 Issue: 4 Pages: 1244-1255
  • DOI: 10.1021/jp208855u
  • Peer Reviewed
• [Journal Article] A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-coupling Reaction (2011)
  • Author(s): Song, J.; Anabuki, S.; Aratani, N.; Shinokubo, H.; Osuka, A
  • Journal Title: Chem. Lett. Volume: 40 Pages: 902-902
  • URL: http://dx.doi.org/10.1246/cl.2011.902
  • Peer Reviewed
• [Journal Article] Song, J.; Aratani, N.; Shinokubo, H.; Osuka, A. (2011)
  • Author(s): A β-to-β 2,5-Thienylene-bridged Cyclic Porphyrin Tetramer: Its Rational Synthesis and Binding of C60
  • Journal Title: Chem. Sci. Volume: 2 Pages: 748-751
  • Peer Reviewed
• [Journal Article] A β-to-β 2,5-Thienylene-bridged Cyclic Porphyrin Tetramer : Its Rational Synthesis and Binding of C_<60> (2011)
  • Author(s): Song, J., Aratani, N., Shinokubo, H., Osuka, A.
  • Journal Title: Chem.Sci. Volume: 2 Issue: 4 Pages: 748-751
  • DOI: 10.1039/c0sc00605j
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed β-Selective Direct Arylation of Porphyrins (2011)
  • Author(s): Y.Kawamata, S.Tokuji, H.Yorimitsu, A.Osuka
  • Journal Title: Angew.Chem.Int.Ed. Volume: 50 Issue: 38 Pages: 8867-8870
  • DOI: 10.1002/anie.201102318
  • Peer Reviewed
• [Journal Article] Rearrangements of a [36] Octaphyrin Triggered by Nickel (II) Metalation : Metamorphosis to a Directly meso-β-Linked Diporphyrin (2011)
  • Author(s): Yasuo Tanaka, Hirotaka Mori, Taro Koide, Hideki Yorimitsu, Naoki Aratani, Atsuhiro Osuka
  • Journal Title: Angewandte Chemie International Edition Volume: 50 Issue: 48 Pages: 11460-11464
  • DOI: 10.1002/anie.201105809
  • Peer Reviewed
• [Journal Article] New Synthetic Strategy for Diporphyrins : Pinacol Coupling-Rearrangement (2011)
  • Author(s): S.Tokuji, C.Maeda, H.Yorimitsu, A.Osuka
  • Journal Title: Chem.Eur.J. Volume: 17 Issue: 26 Pages: 7154-7157
  • DOI: 10.1002/chem.201100872
  • Peer Reviewed
• [Journal Article] Phosphorus complexes of a triplyfused [24]pentaphyrin (2011)
  • Author(s): Higashino, T., Osuka, A.
  • Journal Title: Chem.Sci. Volume: 3 Issue: 1 Pages: 103-107
  • DOI: 10.1039/c1sc00653c
  • Peer Reviewed
• [Journal Article] Electron- or Hole-Transporting Nature Selected by Side-Chain-Directed π-stacking Geometry : Liquid Crystalline Fused Metalloporphyrin Dimers (2011)
  • Author(s): Tsuneaki Sakurai, Kentaro Tashiro, Yoshihito Honsho, Akinori Saeki, Shu Seki, Atsuhiro Osuka, Atsuya Muranaka, Masanobu Uchiyama, Jungeun Kim, Sunyeo Ha, Kenichi Kato, Masaki Takata, Takuzo Aida
  • Journal Title: Journal of the American Chemical Society Volume: 133 Issue: 17 Pages: 6537-6540
  • DOI: 10.1021/ja201272t
  • Peer Reviewed
• [Journal Article] Peripherally cyclometalated iridium complexes of dipyridylporphyrin (2011)
  • Author(s): Yoshida, K., Nakashima, T., Yamaguchi, S., Osuka, A., Shinokubo, H.
  • Journal Title: Dalton Trans. Volume: 40 Issue: 35 Pages: 8773-8775
  • DOI: 10.1039/c1dt10246j
  • Peer Reviewed
• [Journal Article] Synthesis of a diimidazolylporphyrin pincer palladium complex (2011)
  • Author(s): Yamamoto, J., Shimizu, T., Yamaguchi, S., Aratani, N., Shinokubo, H., Osuka, A.
  • Journal Title: J.Porphyrins Phthalocyanines Volume: 15 Issue: 07n08 Pages: 534-538
  • DOI: 10.1142/s1088424611002908
  • Peer Reviewed
• [Journal Article] A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-coupling Reaction (2011)
  • Author(s): Song, J., Anabuki, S., Aratani, N., Shinokubo, H., Osuka, A.
  • Journal Title: Chem.Lett. Volume: 43 Issue: 2 Pages: 902-902
  • DOI: 10.1002/chin.201202114
  • Peer Reviewed
• [Journal Article] Solvent- and Temperature-Dependent Conformational Changes between Huckel Antiaromatic and Mobius Aromatic Species in meso-Trifluoromethyl Substituted [28] Hexaphyrins (2011)
  • Author(s): Min-Chul Yoon, Pyosang Kim, Hyejin Yoo, Soji Shimizu, Taro Koide, Sumito Tokuji, Shohei Saito, Atsuhiro Osuka, Dongho Kim
  • Journal Title: The Journal of Physical Chemistry B Volume: 115 Issue: 50 Pages: 14928-14937
  • DOI: 10.1021/jp207731k
  • Peer Reviewed
• [Journal Article] Synthesis of BODIPY-Appended Subporphyrins (2011)
  • Author(s): Sugimoto, H., Muto, M., Tanaka, T., Osuka, A.
  • Journal Title: Eur.J.Org.Chem. Volume: 2011 Issue: 1 Pages: 71-77
  • DOI: 10.1002/ejoc.201001188
  • Peer Reviewed
• [Journal Article] Oxocyclohexadienylidene-Substituted Subporphyrins (2011)
  • Author(s): Hayashi, S., Sung, J., Sung, Y., Sung, Y.M., Inokuma, Y., Kim, D., Osuka, A.
  • Journal Title: Angew.Chem.Int.Ed. Volume: 50 Issue: 14 Pages: 3253-3256
  • DOI: 10.1002/anie.201006449
  • Peer Reviewed
• [Journal Article] Conformation dynamics of non-, singly- and doubly-N-fused [28]hexaphyrins revealed by photophysical studies (2011)
  • Author(s): Lim, J.M., Inoue, M., Suzuki, M., Higashino, T., Sung, Y.M., Osuka, A., Kim, D.
  • Journal Title: Chem.Commun. Volume: 47 Issue: 13 Pages: 3960-3962
  • DOI: 10.1039/c0cc05822j
  • Peer Reviewed
• [Journal Article] Excited-state energy relaxation dynamics of triply linked Zn(II) porphyrin arrays (2011)
  • Author(s): Kim, P., Ikeda, T., Lim, J.M., Park, J., Kim, M., Aratani, N., Osuka, A., Kim, D.
  • Journal Title: Chem.Commun. Volume: 47 Issue: 15 Pages: 4433-4435
  • DOI: 10.1039/c1cc10521c
  • Peer Reviewed
• [Journal Article] Synthesis and Properties of Boron(III)-Coordinated Subbacteriochlorins (2011)
  • Author(s): Hayashi, S., Tsurumaki, E., Inokuma, Y., Kim, P., Sung, Y.M., Kim, D., Osuka, A.
  • Journal Title: J.Am.Chem.Soc. Volume: 133 Issue: 12 Pages: 4254-4256
  • DOI: 10.1021/ja200669a
  • Peer Reviewed
• [Journal Article] The Role of Electronic Couplings in Linear Porphyrin Arrays Probed by Single-Molecule Fluorescence Spectroscopy (2011)
  • Author(s): Yang, J., Lee, J-E., Lee, C.Y., Aratani, N., Osuka, A., Hupp, J.T., Kim, D.
  • Journal Title: Chem.Euro.J. Volume: 17 Issue: 33 Pages: 9219-9225
  • DOI: 10.1002/chem.201100236
  • Peer Reviewed
• [Journal Article] Moebius Aromatic [28]Hexaphyrin Phosphonium Adducts (2011)
  • Author(s): Inoue, M., Yoneda, T., Youfu, K., Aratani, N., Osuka, A.
  • Journal Title: Chem.Eur.J. Volume: 17 Issue: 33 Pages: 9028-9031
  • DOI: 10.1002/chem.201100757
  • Peer Reviewed
• [Journal Article] Neutral Radical and Singlet Biradical Forms of Meso-Free,-Keto, and -Diketo Hexaphyrins (1.1.1.1.1.1) : Effects on Aromaticity and Photophysical Properties (2011)
  • Author(s): Masatoshi Ishida, Jae-Yoon Shin, Jong Min Lim, Byung Sun Lee, Min-Chul Yoon, Taro Koide, Jonathan L.Sessler, Atsuhiro Osuka, Dongho Kim
  • Journal Title: Journal of the American Chemical Society Volume: 133 Issue: 39 Pages: 15533-15544
  • DOI: 10.1021/ja204626t
  • Peer Reviewed
• [Journal Article] Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C-H arylation and their photophysical and electrochemical properties (2011)
  • Author(s): Mitamura, Y., Yorimitsu, H., Oshima, K., Osuka, A.
  • Journal Title: Chem.Sci. Volume: 2 Issue: 10 Pages: 2017-2021
  • DOI: 10.1039/c1sc00372k
  • Peer Reviewed
• [Journal Article] Synthesis of Carbazole-Containing Porphyrinoids by a Multiple Annulation Strategy : A Core-Modified and π-Expanded Porphyrin (2011)
  • Author(s): Maeda, C., Yoneda, T., Aratani, N., Yoon, M-C., Lim, J.M., Kim, D., Yoshioka, N., Osuka, A.
  • Journal Title: Angew.Chem., Int.Ed. Volume: 50 Issue: 25 Pages: 5691-5694
  • DOI: 10.1002/anie.201101864
  • Peer Reviewed
• [Journal Article] Porphyrin-hexaphyrin hybrid tapes (2011)
  • Author(s): Tanaka, T., Aratani, N., Lim, J.M., Kim, K.S., Kim, D., Osuka, A.
  • Journal Title: Chem.Sci. Volume: 2 Issue: 7 Pages: 1414-1418
  • DOI: 10.1039/c1sc00228g
  • Peer Reviewed
• [Journal Article] Solvent-Dependent Aromatic versus Antiaromatic Conformational Switching in meso-(Heptakis)pentafluorophenyl [32]Heptaphyrin (2011)
  • Author(s): Yoon, M-C., Shin, J-Y., Lim, J.M., Saito, A., Yoneda, T., Osuka, A., Kim, D.
  • Journal Title: Chem.Eur.J. Volume: 17 Issue: 24 Pages: 6707-6715
  • DOI: 10.1002/chem.201003736
  • Peer Reviewed
• [Journal Article] Ferrocene-appended Subporphyrins (2011)
  • Author(s): Sugimoto, H., Tanaka, T., Osuka, A.
  • Journal Title: Chem.Lett. Volume: 42 Issue: 44 Pages: 629-631
  • DOI: 10.1002/chin.201144178
  • Peer Reviewed
• [Journal Article] A Moebius Aromatic Pd(II) Complex of [28]Hexaphyrin(2.1.1.0.1.1) (2011)
  • Author(s): Moriya, K., Yoneda, T., Saito, S., Osuka, A.
  • Journal Title: Chem.Lett. Volume: 40 Issue: 5 Pages: 455-457
  • DOI: 10.1246/cl.2011.455
  • NAID: 10028242335
  • Peer Reviewed
• [Journal Article] Palladium(II)-Triggered Rearrangement of Heptaphyrins to N-Confused Porphyrins (2011)
  • Author(s): Yoneda, T., Saito, S., Yorimitsu, H., Osuka, A.
  • Journal Title: Angew.Chem., Int.Ed. Volume: 50 Issue: 15 Pages: 3475-3478
  • DOI: 10.1002/anie.201100243
  • Peer Reviewed
• [Presentation] メゾ位にイミダゾール基を有するヒュッケル反芳香族性環拡張ポルフィリンの合成と物性 (2013)
  • Author(s): 森 裕貴・ 大須賀 篤弘
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学(滋賀県)
• [Presentation] メビウス反芳香族性を示す環拡張ポルフィリン-リン錯体 (2013)
  • Author(s): 東野智洋・大須賀篤弘
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学(滋賀県)
• [Presentation] [26]ヘキサフィリンパラジウム錯体のメチル化反応 (2013)
  • Author(s): 米田友貴、大須賀篤弘
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学(滋賀県)
• [Presentation] 縮環ヘキサフィリンの合成と光物性 (2012)
  • Author(s): 荒谷直樹・直田耕治・田中隆行・森裕貴・Dongho Kim・大須賀篤弘
  • Organizer: 2012年光化学討論会
  • Place of Presentation: 東京工業大学
• [Presentation] Catalytic Selective Direct Arylation of Porphyrin Periphery (2012)
  • Author(s): Hideki Yorimitsu, Atsuhiro Osuka
  • Organizer: 7th International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: 韓国 済州島
• [Presentation] Subporphyrins as a Promising Functional Pigment (2012)
  • Author(s): Atsuhiro Osuka
  • Organizer: The Third Molecular Assemblies Workshop of FUNMOLS
  • Place of Presentation: Adelsdorf (Erlangen), Germany
  • Invited
• [Presentation] Synthetic Chemistry of Subporphyrins (2012)
  • Author(s): Atsuhiro Osuka
  • Organizer: 7th International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Jeju Island, Korea
  • Invited
• [Presentation] Subporphyrins as a Promising Functional Pigment (2012)
  • Author(s): Atsuhiro Osuka
  • Organizer: The Second symposium on “Carbon Nanoforms”
  • Place of Presentation: Tsukuba, Japan
  • Invited
• [Presentation] Moebius Aromatic Expanded Porphyrins (2012)
  • Author(s): Atsuhiro Osuka
  • Organizer: 21st IUPAC International Conference on Physical Organic Chemistry (ICPOC 21)
  • Place of Presentation: Durham, UK
  • Invited
• [Presentation] Catalytic Selective Direct Arylation of Porphyrin Periphery (2012)
  • Author(s): Hideki Yorimitsu, Atsuhiro Osuka
  • Organizer: 7th International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Jeju Island, Korea
  • Invited
• [Presentation] Efficient Access to Multiarylated Tetrathiafulvalenes by Palladium-Catalyzed C-H Direct Arylation and Their Photophysical and Electrochemical Properties (2012)
  • Author(s): Ryota Ueno, Yukihiro Mitamura, Daishi Fujino, Hideki Yorimitsu, Atsuhiro Osuka
  • Organizer: 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Kyoto, Japan
• [Presentation] サブポルフィリンの化学 (2012)
  • Author(s): 鶴巻英治・林慎也・北野匡章・荒谷直樹・大須賀篤弘
  • Organizer: 新学術領域研究「高次π空間の創発と機能開発」第８回公開シンポジウム
  • Place of Presentation: ホテル アローレ(石川県)
• [Presentation] 縮環ヘキサフィリンの合成と光物性 (2012)
  • Author(s): 荒谷直樹・直田耕治・田中隆行・森裕貴・Dongho Kim・大須賀篤弘
  • Organizer: 2012年光化学討論会
  • Place of Presentation: 東京工業大学(東京都)
• [Presentation] メビウス反芳香族性を示す環拡張ポルフィリン-リン錯体 (2012)
  • Author(s): 東野智洋・大須賀篤弘
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テルサ(京都府)
• [Presentation] 新奇なポルフィリンピンサー白金錯体の合成と物性 (2012)
  • Author(s): 穴吹翔馬・忍久保 洋・荒谷 直樹・大須賀 篤弘
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応大学（横浜市）
• [Presentation] 合成前駆体としてのメゾフリーサブポルフィリンの合成 (2012)
  • Author(s): 北野匡章・林慎也・大須賀 篤弘
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応大学（横浜市）
• [Presentation] アントラセン置換ヘキサフィリンの合成と物性 (2012)
  • Author(s): 直田耕治・森裕貴・大須賀 篤弘
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応大学（横浜市）
• [Presentation] パラジウム架橋ポルフィリン多量体の合成と光物性 (2011)
  • Author(s): 荒谷直樹・宋建新・穴吹翔馬・忍久保洋・大須賀篤弘
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎大学
• [Presentation] Novel Fullerene Receptors based on Multi-Porphyrin Arrays (2011)
  • Author(s): Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
  • Organizer: The first symposium on "Carbon Nanoforms"
  • Place of Presentation: Toledo, Spain
• [Presentation] Construction of Multi-porphyrin Arrays via Pd-catalyzed Coupling Reactions (2011)
  • Author(s): Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
  • Organizer: 219th ECS meeting
  • Place of Presentation: Montreal, Canada
• [Presentation] Construction of Multi-porphyrin Arrays via Pd-catalyzed Coupling Reactions (2011)
  • Author(s): Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
  • Organizer: 219th ECS meeting(招待講演)
  • Place of Presentation: Montreal（Canada）
• [Presentation] Novel Fullerene Receptors based on Multi-Porphyrin Arrays (2011)
  • Author(s): Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
  • Organizer: The first symposium on "Carbon Nanoforms"(招待講演)
  • Place of Presentation: Toledo（Spain）
• [Presentation] パラジウム架橋ポルフィリン多量体の合成と光物性 (2011)
  • Author(s): 荒谷直樹・宋建新・穴吹翔馬・忍久保洋・大須賀篤弘
  • Organizer: 2011年光化学討論会
  • Place of Presentation: 宮崎大学（宮崎市）
• [Presentation] ハイブリッド型ポルフィリンテープの合成と物性 (2011)
  • Author(s): 田中隆行・荒谷直樹・大須賀篤弘
  • Organizer: 錯体化学会第61回討論会
  • Place of Presentation: 岡山理科大学（岡山市）
• [Presentation] パラジウム(II)錯化によるヘプタフィリンのN-混乱ポルフィリン骨格を有する錯体への転位反応 (2011)
  • Author(s): 米田友貴・斎藤尚平・依光英樹・大須賀篤弘
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場（つくば市）
• [Presentation] 巨大ポルフィリンアレイの合成と光物性 (2011)
  • Author(s): 荒谷直樹・宋建新・穴吹翔馬・忍久保洋・大須賀篤弘
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学（岡山市）
• [Presentation] Palladium-Catalyzed Direct Arylation of Porphyrins (2011)
  • Author(s): Yu Kawamata, Sumito Tokuji, Hideki Yorimitsu, Atsuhiro Osuka
  • Organizer: 7th International Symposium on Integrated Synthesis
  • Place of Presentation: シーサイドホテル舞子ビラ神戸（神戸市）
• [Remarks]
  • URL: http://kuchem.kyoto-u.ac.jp/shuyu