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Synthesis and functionalization of discrete porphyrin tube

Research Project

Project/Area Number 23655034
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionKyoto University

Principal Investigator

OSUKA Atsuhiro  京都大学, 大学院・理学研究科, 教授 (80127886)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsポルフィリン / 二光子吸収 / クロスカップリング / ポルフィリンベルト / ポルフィリンチューブ / ニッケル錯体 / 亜鉛錯体 / 局面π化合物 / ナノカーボン / 電子ワイヤー
Research Abstract

We’ve achieved the synthesis of pyridine-bridgedβ,β-doubly linked porphyrin cyclic tetramer by means of Suzuki-coupling that can encapsulate C60. We’ve developed an efficient method to synthesize 3mer and studied a variety of metal complexes.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (82 results)

All 2013 2012 2011 Other

All Journal Article (54 results) (of which Peer Reviewed: 54 results) Presentation (27 results) (of which Invited: 5 results) Remarks (1 results)

  • [Journal Article] Preferential Formation of Cyclic Trimers by Palladium-Catalyzed Oxidative Coupling Reactions of 2,18-Diethynylporphyrins2012

    • Author(s)
      S. Tokuji, H. Yorimitsu, A. Osuka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 49 Pages: 12357-12361

    • DOI

      10.1002/anie.201207763

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hexaphyrin Fused to Two Anthracenes2012

    • Author(s)
      Naoda, K. ; Mori, H. ; Aratani, N. ; Lee, B. S. ; Kim, D. Osuka, A
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 51 Issue: 39 Pages: 9856-9859

    • DOI

      10.1002/anie.201204446

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A meso-Spiro[Cyclopentadiene-Isoporphyrin] from a Phenylethynyl Porphyrin Platinum(II) Pincer Complex2012

    • Author(s)
      Anabuki, S.; Shinokubo, H.; Aratani, N.: Osuka, A
    • Journal Title

      Angew. Chem.

      Volume: 51 Issue: 1 Pages: 3174-3177

    • DOI

      10.1002/ange.19380510103

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct meso-Alkynylation of Porphyrins Doubly Assisted by Pyridyl Coordination2012

    • Author(s)
      S. Anabuki, S. Tokuji, N. Aratani, and A. Osuka
    • Journal Title

      Org. Lett.

      Volume: 14 Issue: 11 Pages: 2778-2781

    • DOI

      10.1021/ol301005b

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Directly Linked Corrole Oligomers via Facile Oxidative 3-3' Coupling Reaction2012

    • Author(s)
      Hirabayashi, S.; Omote, M.; Aratani, N.; Osuka, A.
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 85 Pages: 558-562

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Directly Linked Corrole Oligomers via Facile Oxidative 3-3' Coupling Reaction2012

    • Author(s)
      S. Hirabayashi, M. Omote, N. Aratani, and A. Osuka
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 85 Issue: 5 Pages: 2694-2697

    • DOI

      10.1246/bcsj.20110373

    • NAID

      130004153068

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Mobius Antiaromatic Complex as a Kinetically Controlled Product in Phosphorus Insertion to a [32] Heptaphyrin2012

    • Author(s)
      Tomohiro Higashino, Byung Sun Lee, Jong
    • Journal Title

      Angewandte Chemie, International Edition

      Volume: 51 Issue: 52 Pages: 13105-13108

    • DOI

      10.1002/anie.201208147

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Antiaromatic Hexaphyrins and Octaphyrins Stabilized by the Hydrogen-Bonding Interactions of meso-Imidazolyl Groups2012

    • Author(s)
      Mori, H. ; Sung, Y. M. ; Lee, B. S. ; Kim, D. ; Osuka, A.
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 51 Issue: 50 Pages: 12459-12463

    • DOI

      10.1002/anie.201207212

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Reaction of Homopropargyl-Substituted Dicarbonyl Compounds2012

    • Author(s)
      藤野大士、依光英樹、大須賀篤弘
    • Journal Title

      Organic Letters

      Volume: 14 Issue: 11 Pages: 2914-2917

    • DOI

      10.1021/ol301257m

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of A2B6-Type [36]Octaphyrins: Copper(II)-Metalation-Induced Fragmentation Reactions to Porphyrins and N-Fusion Reactions of meso-(3-Thienyl) Substituents2012

    • Author(s)
      H. Mori, N. Aratani, and A. Osuka
    • Journal Title

      Chem. Asian J

      Volume: 7 Issue: 6 Pages: 1340-1346

    • DOI

      10.1002/asia.201100919

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effective meso Fabrications of Subporphyrins2012

    • Author(s)
      Kitano, M.; Hayashi, S.; Tanaka, T.; Yorimitsu, H.; Aratani, N.; Osuka, A
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 23 Pages: 5593-5597

    • DOI

      10.1002/anie.201201853

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Palladation of a Moebius Aromatic [28]Hexaphyrin(1.1.1.1.1.1) PdII Complex2012

    • Author(s)
      T. Tanaka and A. Osuka
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Issue: 23 Pages: 7036-7040

    • DOI

      10.1002/chem.201200762

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Electron-Deficient Porphyrin Tape2012

    • Author(s)
      H. Mori, T. Tanaka, N. Aratani, B. S. Lee, P. Kim, D. Kim, and A. Osuka
    • Journal Title

      Chem. Asian. J.

      Volume: 7 Issue: 8 Pages: 1811-1816

    • DOI

      10.1002/asia.201200247

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Toward Ultralow-Bandgap Liquid Crystalline Semiconductors: Use of Triply Fused Metalloporphyrin Trimer-Pentamer as Extra-large π-Extended Mesogenic Motifs2012

    • Author(s)
      S. Tanaka, T. Sakurai, Y. Honsho, S. Seki, K. Kato, M. Takata, A. Osuka, and T. Aida
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Issue: 34 Pages: 10554-10561

    • DOI

      10.1002/chem.201201101

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetically Blocked Stable Heptazethrene and Octazethrene: Closed-Shell or Open-Shell in the Ground State?2012

    • Author(s)
      Y. Li, W.-K. Heng, B. S. Lee, N. Aratani, J. L. Zafra, N. Bao, R. Lee, Y. M. Sung, Z. Sun, K.-W. Huang, R. D. Webster, J. T. Lopez Navarrete, D. Kim, A. Osuka, J. Casada, J. Ding, and J. Wu
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 36 Pages: 14913-14922

    • DOI

      10.1021/ja304618v

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deprotonation-Induced Aromaticity Enhancement and New Conjugated Networks in meso-Hexakis(pentafluorophenyl)[26]hexaphyrin2012

    • Author(s)
      W.-Y. Cha, J. M. Lim, M.-C. Yoon, Y. M. Sung, B. S. Lee, S. Katsumata, M. Suzuki, H. Mori, A. Osuka, Y. Ikawa, H. Furuta, and D. Kim
    • Journal Title

      Chem. Eur. J

      Volume: 18 Issue: 49 Pages: 15838-15844

    • DOI

      10.1002/chem.201200991

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Calix[4]pyrroles bearing proximally meso-meso linking straps: synthesis and anion binding properties2012

    • Author(s)
      J.-Y. Park, K. Skonieczny, N. Aratani, A. Osuka, D. T. Gryko, and C.-H. Lee
    • Journal Title

      Chem. Commun

      Volume: 48 Issue: 65 Pages: 8060-8062

    • DOI

      10.1039/c2cc33537a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a Library of Fluorescent 2-Aryl-3-trifluoromethylnaphthofurans from Naphthols by Using a Sequential Pummerer-Annulation/Cross-Coupling Strategy and their Photophysical Properties2012

    • Author(s)
      Y. Ookubo, A. Wakamiya, H. Yorimitsu, and A. Osuka
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Issue: 40 Pages: 12690-12697

    • DOI

      10.1002/chem.201201261

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of meso-Arylamino- and Alkylaminosubporphyrins2012

    • Author(s)
      M. Kitano, S. Hayashi, T. Tanaka, N. Aratani, and A. Osuka
    • Journal Title

      Chem. Eur. J

      Volume: 18 Issue: 29 Pages: 8929-8933

    • DOI

      10.1002/chem.201201256

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A non-fused mono-meso-free pentaphyrin and its rhodium(I) complex2012

    • Author(s)
      Tomoki Yoneda, Hirotaka Mori, Byung Sun Lee, Min-Chul Yoon, Dongho Kim, Atsuhiro Osuka
    • Journal Title

      Chemical Communications

      Volume: 48 Issue: 54 Pages: 6785-6787

    • DOI

      10.1039/c2cc32054a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational Synthesis of A2B-type meso-Triarylsubporphyrins2012

    • Author(s)
      T. Tanaka, M. Kitano, S. Hayashi, N. Aratani, and A. Osuk
    • Journal Title

      Org. Lett.

      Volume: 14 Issue: 11 Pages: 2694-2697

    • DOI

      10.1021/ol300865s

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular engineering and solvent dependence of excitation energy hopping in self-assembled porphyrin boxes2012

    • Author(s)
      H. W. Bahng, P. Kim, Y. M. Sung, C. Maeda, A. Osuka, and D. Kim
    • Journal Title

      Chem. Commun.

      Volume: 48 Issue: 35 Pages: 4181-4183

    • DOI

      10.1039/c2cc30834g

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Benzylic modifications of meso-alkyl-substituted porphyrins via oxidation with DDQ2012

    • Author(s)
      X. Peng, C. Gao, Y. Huang, J. Peng, N. Aratani, and A. Osuka
    • Journal Title

      Tetrahedron Lett.

      Volume: 53 Issue: 9 Pages: 1156-1159

    • DOI

      10.1016/j.tetlet.2011.12.101

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A meso-Spiro[Cyclopentadiene-Isoporphyrin] from a Phenylethynyl Porphyrin Platinum(II) Pincer Complex2012

    • Author(s)
      S. Anabuki, H. Shinokubo, N. Aratani, and A. Osuka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 13 Pages: 3174-3177

    • DOI

      10.1002/anie.201109091

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 1,4-Phenylene-Bridged Hexaphyrin Dimers2012

    • Author(s)
      H. Mori, N. Aratani, and A. Osuka
    • Journal Title

      Eur. J. Org. Chem

      Volume: 10 Issue: 10 Pages: 1913-1919

    • DOI

      10.1002/ejoc.201200080

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aromatic-to-Antiaromatic Switching in Triply Linked Porphyrin Bis (rhodium(I)) Hexaphyrin Hybrids2012

    • Author(s)
      Takayuki Tanaka, Naoki Aratani, Atsuhiro Osuka
    • Journal Title

      Chemistry-An Asian Journal

      Volume: 7 Issue: 5 Pages: 889-893

    • DOI

      10.1002/asia.201101039

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ensemble and Single-Molecule Spectroscopic Study on Excitation Energy Transfer Processes in 1,3-Phenylene-Linked Perylenebisimide Oligomers2012

    • Author(s)
      H. W. Bahng, M.-C. Yoon, J.-E. Lee, Y. Murase, T. Yoneda, H. Shinokubo, A. Osuka, and D. Kim
    • Journal Title

      J. Phys. Chem. B

      Volume: 116 Issue: 4 Pages: 1244-1255

    • DOI

      10.1021/jp208855u

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-coupling Reaction2011

    • Author(s)
      Song, J.; Anabuki, S.; Aratani, N.; Shinokubo, H.; Osuka, A
    • Journal Title

      Chem. Lett.

      Volume: 40 Pages: 902-902

    • URL

      http://dx.doi.org/10.1246/cl.2011.902

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Song, J.; Aratani, N.; Shinokubo, H.; Osuka, A.2011

    • Author(s)
      A β-to-β 2,5-Thienylene-bridged Cyclic Porphyrin Tetramer: Its Rational Synthesis and Binding of C60
    • Journal Title

      Chem. Sci.

      Volume: 2 Pages: 748-751

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A β-to-β 2,5-Thienylene-bridged Cyclic Porphyrin Tetramer : Its Rational Synthesis and Binding of C_<60>2011

    • Author(s)
      Song, J., Aratani, N., Shinokubo, H., Osuka, A.
    • Journal Title

      Chem.Sci.

      Volume: 2 Issue: 4 Pages: 748-751

    • DOI

      10.1039/c0sc00605j

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed β-Selective Direct Arylation of Porphyrins2011

    • Author(s)
      Y.Kawamata, S.Tokuji, H.Yorimitsu, A.Osuka
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50 Issue: 38 Pages: 8867-8870

    • DOI

      10.1002/anie.201102318

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rearrangements of a [36] Octaphyrin Triggered by Nickel (II) Metalation : Metamorphosis to a Directly meso-β-Linked Diporphyrin2011

    • Author(s)
      Yasuo Tanaka, Hirotaka Mori, Taro Koide, Hideki Yorimitsu, Naoki Aratani, Atsuhiro Osuka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 50 Issue: 48 Pages: 11460-11464

    • DOI

      10.1002/anie.201105809

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] New Synthetic Strategy for Diporphyrins : Pinacol Coupling-Rearrangement2011

    • Author(s)
      S.Tokuji, C.Maeda, H.Yorimitsu, A.Osuka
    • Journal Title

      Chem.Eur.J.

      Volume: 17 Issue: 26 Pages: 7154-7157

    • DOI

      10.1002/chem.201100872

    • Related Report
      2012 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Phosphorus complexes of a triplyfused [24]pentaphyrin2011

    • Author(s)
      Higashino, T., Osuka, A.
    • Journal Title

      Chem.Sci.

      Volume: 3 Issue: 1 Pages: 103-107

    • DOI

      10.1039/c1sc00653c

    • Related Report
      2012 Annual Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electron- or Hole-Transporting Nature Selected by Side-Chain-Directed π-stacking Geometry : Liquid Crystalline Fused Metalloporphyrin Dimers2011

    • Author(s)
      Tsuneaki Sakurai, Kentaro Tashiro, Yoshihito Honsho, Akinori Saeki, Shu Seki, Atsuhiro Osuka, Atsuya Muranaka, Masanobu Uchiyama, Jungeun Kim, Sunyeo Ha, Kenichi Kato, Masaki Takata, Takuzo Aida
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Issue: 17 Pages: 6537-6540

    • DOI

      10.1021/ja201272t

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Peripherally cyclometalated iridium complexes of dipyridylporphyrin2011

    • Author(s)
      Yoshida, K., Nakashima, T., Yamaguchi, S., Osuka, A., Shinokubo, H.
    • Journal Title

      Dalton Trans.

      Volume: 40 Issue: 35 Pages: 8773-8775

    • DOI

      10.1039/c1dt10246j

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a diimidazolylporphyrin pincer palladium complex2011

    • Author(s)
      Yamamoto, J., Shimizu, T., Yamaguchi, S., Aratani, N., Shinokubo, H., Osuka, A.
    • Journal Title

      J.Porphyrins Phthalocyanines

      Volume: 15 Issue: 07n08 Pages: 534-538

    • DOI

      10.1142/s1088424611002908

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-coupling Reaction2011

    • Author(s)
      Song, J., Anabuki, S., Aratani, N., Shinokubo, H., Osuka, A.
    • Journal Title

      Chem.Lett.

      Volume: 43 Issue: 2 Pages: 902-902

    • DOI

      10.1002/chin.201202114

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Solvent- and Temperature-Dependent Conformational Changes between Huckel Antiaromatic and Mobius Aromatic Species in meso-Trifluoromethyl Substituted [28] Hexaphyrins2011

    • Author(s)
      Min-Chul Yoon, Pyosang Kim, Hyejin Yoo, Soji Shimizu, Taro Koide, Sumito Tokuji, Shohei Saito, Atsuhiro Osuka, Dongho Kim
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 115 Issue: 50 Pages: 14928-14937

    • DOI

      10.1021/jp207731k

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of BODIPY-Appended Subporphyrins2011

    • Author(s)
      Sugimoto, H., Muto, M., Tanaka, T., Osuka, A.
    • Journal Title

      Eur.J.Org.Chem.

      Volume: 2011 Issue: 1 Pages: 71-77

    • DOI

      10.1002/ejoc.201001188

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Oxocyclohexadienylidene-Substituted Subporphyrins2011

    • Author(s)
      Hayashi, S., Sung, J., Sung, Y., Sung, Y.M., Inokuma, Y., Kim, D., Osuka, A.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50 Issue: 14 Pages: 3253-3256

    • DOI

      10.1002/anie.201006449

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Conformation dynamics of non-, singly- and doubly-N-fused [28]hexaphyrins revealed by photophysical studies2011

    • Author(s)
      Lim, J.M., Inoue, M., Suzuki, M., Higashino, T., Sung, Y.M., Osuka, A., Kim, D.
    • Journal Title

      Chem.Commun.

      Volume: 47 Issue: 13 Pages: 3960-3962

    • DOI

      10.1039/c0cc05822j

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Excited-state energy relaxation dynamics of triply linked Zn(II) porphyrin arrays2011

    • Author(s)
      Kim, P., Ikeda, T., Lim, J.M., Park, J., Kim, M., Aratani, N., Osuka, A., Kim, D.
    • Journal Title

      Chem.Commun.

      Volume: 47 Issue: 15 Pages: 4433-4435

    • DOI

      10.1039/c1cc10521c

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Boron(III)-Coordinated Subbacteriochlorins2011

    • Author(s)
      Hayashi, S., Tsurumaki, E., Inokuma, Y., Kim, P., Sung, Y.M., Kim, D., Osuka, A.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 12 Pages: 4254-4256

    • DOI

      10.1021/ja200669a

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] The Role of Electronic Couplings in Linear Porphyrin Arrays Probed by Single-Molecule Fluorescence Spectroscopy2011

    • Author(s)
      Yang, J., Lee, J-E., Lee, C.Y., Aratani, N., Osuka, A., Hupp, J.T., Kim, D.
    • Journal Title

      Chem.Euro.J.

      Volume: 17 Issue: 33 Pages: 9219-9225

    • DOI

      10.1002/chem.201100236

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Moebius Aromatic [28]Hexaphyrin Phosphonium Adducts2011

    • Author(s)
      Inoue, M., Yoneda, T., Youfu, K., Aratani, N., Osuka, A.
    • Journal Title

      Chem.Eur.J.

      Volume: 17 Issue: 33 Pages: 9028-9031

    • DOI

      10.1002/chem.201100757

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Neutral Radical and Singlet Biradical Forms of Meso-Free,-Keto, and -Diketo Hexaphyrins (1.1.1.1.1.1) : Effects on Aromaticity and Photophysical Properties2011

    • Author(s)
      Masatoshi Ishida, Jae-Yoon Shin, Jong Min Lim, Byung Sun Lee, Min-Chul Yoon, Taro Koide, Jonathan L.Sessler, Atsuhiro Osuka, Dongho Kim
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Issue: 39 Pages: 15533-15544

    • DOI

      10.1021/ja204626t

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C-H arylation and their photophysical and electrochemical properties2011

    • Author(s)
      Mitamura, Y., Yorimitsu, H., Oshima, K., Osuka, A.
    • Journal Title

      Chem.Sci.

      Volume: 2 Issue: 10 Pages: 2017-2021

    • DOI

      10.1039/c1sc00372k

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Carbazole-Containing Porphyrinoids by a Multiple Annulation Strategy : A Core-Modified and π-Expanded Porphyrin2011

    • Author(s)
      Maeda, C., Yoneda, T., Aratani, N., Yoon, M-C., Lim, J.M., Kim, D., Yoshioka, N., Osuka, A.
    • Journal Title

      Angew.Chem., Int.Ed.

      Volume: 50 Issue: 25 Pages: 5691-5694

    • DOI

      10.1002/anie.201101864

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Porphyrin-hexaphyrin hybrid tapes2011

    • Author(s)
      Tanaka, T., Aratani, N., Lim, J.M., Kim, K.S., Kim, D., Osuka, A.
    • Journal Title

      Chem.Sci.

      Volume: 2 Issue: 7 Pages: 1414-1418

    • DOI

      10.1039/c1sc00228g

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Solvent-Dependent Aromatic versus Antiaromatic Conformational Switching in meso-(Heptakis)pentafluorophenyl [32]Heptaphyrin2011

    • Author(s)
      Yoon, M-C., Shin, J-Y., Lim, J.M., Saito, A., Yoneda, T., Osuka, A., Kim, D.
    • Journal Title

      Chem.Eur.J.

      Volume: 17 Issue: 24 Pages: 6707-6715

    • DOI

      10.1002/chem.201003736

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ferrocene-appended Subporphyrins2011

    • Author(s)
      Sugimoto, H., Tanaka, T., Osuka, A.
    • Journal Title

      Chem.Lett.

      Volume: 42 Issue: 44 Pages: 629-631

    • DOI

      10.1002/chin.201144178

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Moebius Aromatic Pd(II) Complex of [28]Hexaphyrin(2.1.1.0.1.1)2011

    • Author(s)
      Moriya, K., Yoneda, T., Saito, S., Osuka, A.
    • Journal Title

      Chem.Lett.

      Volume: 40 Issue: 5 Pages: 455-457

    • DOI

      10.1246/cl.2011.455

    • NAID

      10028242335

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Palladium(II)-Triggered Rearrangement of Heptaphyrins to N-Confused Porphyrins2011

    • Author(s)
      Yoneda, T., Saito, S., Yorimitsu, H., Osuka, A.
    • Journal Title

      Angew.Chem., Int.Ed.

      Volume: 50 Issue: 15 Pages: 3475-3478

    • DOI

      10.1002/anie.201100243

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] メゾ位にイミダゾール基を有するヒュッケル反芳香族性環拡張ポルフィリンの合成と物性2013

    • Author(s)
      森 裕貴・ 大須賀 篤弘
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] メビウス反芳香族性を示す環拡張ポルフィリン-リン錯体2013

    • Author(s)
      東野智洋・大須賀篤弘
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] [26]ヘキサフィリンパラジウム錯体のメチル化反応2013

    • Author(s)
      米田友貴、大須賀篤弘
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 縮環ヘキサフィリンの合成と光物性2012

    • Author(s)
      荒谷直樹・直田耕治・田中隆行・森裕貴・Dongho Kim・大須賀篤弘
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Catalytic Selective Direct Arylation of Porphyrin Periphery2012

    • Author(s)
      Hideki Yorimitsu, Atsuhiro Osuka
    • Organizer
      7th International Conference on Porphyrins and Phthalocyanines
    • Place of Presentation
      韓国 済州島
    • Related Report
      2012 Final Research Report
  • [Presentation] Subporphyrins as a Promising Functional Pigment2012

    • Author(s)
      Atsuhiro Osuka
    • Organizer
      The Third Molecular Assemblies Workshop of FUNMOLS
    • Place of Presentation
      Adelsdorf (Erlangen), Germany
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Synthetic Chemistry of Subporphyrins2012

    • Author(s)
      Atsuhiro Osuka
    • Organizer
      7th International Conference on Porphyrins and Phthalocyanines
    • Place of Presentation
      Jeju Island, Korea
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Subporphyrins as a Promising Functional Pigment2012

    • Author(s)
      Atsuhiro Osuka
    • Organizer
      The Second symposium on “Carbon Nanoforms”
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Moebius Aromatic Expanded Porphyrins2012

    • Author(s)
      Atsuhiro Osuka
    • Organizer
      21st IUPAC International Conference on Physical Organic Chemistry (ICPOC 21)
    • Place of Presentation
      Durham, UK
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Catalytic Selective Direct Arylation of Porphyrin Periphery2012

    • Author(s)
      Hideki Yorimitsu, Atsuhiro Osuka
    • Organizer
      7th International Conference on Porphyrins and Phthalocyanines
    • Place of Presentation
      Jeju Island, Korea
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Efficient Access to Multiarylated Tetrathiafulvalenes by Palladium-Catalyzed C-H Direct Arylation and Their Photophysical and Electrochemical Properties2012

    • Author(s)
      Ryota Ueno, Yukihiro Mitamura, Daishi Fujino, Hideki Yorimitsu, Atsuhiro Osuka
    • Organizer
      10th International Conference on Heteroatom Chemistry
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] サブポルフィリンの化学2012

    • Author(s)
      鶴巻英治・林慎也・北野匡章・荒谷直樹・大須賀篤弘
    • Organizer
      新学術領域研究「高次π空間の創発と機能開発」第8回公開シンポジウム
    • Place of Presentation
      ホテル アローレ(石川県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 縮環ヘキサフィリンの合成と光物性2012

    • Author(s)
      荒谷直樹・直田耕治・田中隆行・森裕貴・Dongho Kim・大須賀篤弘
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] メビウス反芳香族性を示す環拡張ポルフィリン-リン錯体2012

    • Author(s)
      東野智洋・大須賀篤弘
    • Organizer
      第23回基礎有機化学討論会
    • Place of Presentation
      京都テルサ(京都府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 新奇なポルフィリンピンサー白金錯体の合成と物性2012

    • Author(s)
      穴吹翔馬・忍久保 洋・荒谷 直樹・大須賀 篤弘
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学(横浜市)
    • Related Report
      2011 Research-status Report
  • [Presentation] 合成前駆体としてのメゾフリーサブポルフィリンの合成2012

    • Author(s)
      北野匡章・林慎也・大須賀 篤弘
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学(横浜市)
    • Related Report
      2011 Research-status Report
  • [Presentation] アントラセン置換ヘキサフィリンの合成と物性2012

    • Author(s)
      直田耕治・森裕貴・大須賀 篤弘
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学(横浜市)
    • Related Report
      2011 Research-status Report
  • [Presentation] パラジウム架橋ポルフィリン多量体の合成と光物性2011

    • Author(s)
      荒谷直樹・宋建新・穴吹翔馬・忍久保洋・大須賀篤弘
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Novel Fullerene Receptors based on Multi-Porphyrin Arrays2011

    • Author(s)
      Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
    • Organizer
      The first symposium on "Carbon Nanoforms"
    • Place of Presentation
      Toledo, Spain
    • Related Report
      2012 Final Research Report
  • [Presentation] Construction of Multi-porphyrin Arrays via Pd-catalyzed Coupling Reactions2011

    • Author(s)
      Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
    • Organizer
      219th ECS meeting
    • Place of Presentation
      Montreal, Canada
    • Related Report
      2012 Final Research Report
  • [Presentation] Construction of Multi-porphyrin Arrays via Pd-catalyzed Coupling Reactions2011

    • Author(s)
      Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
    • Organizer
      219th ECS meeting(招待講演)
    • Place of Presentation
      Montreal(Canada)
    • Related Report
      2011 Research-status Report
  • [Presentation] Novel Fullerene Receptors based on Multi-Porphyrin Arrays2011

    • Author(s)
      Naoki Aratani, Jianxin Song, Hiroshi Shinokubo, Atsuhiro Osuka
    • Organizer
      The first symposium on "Carbon Nanoforms"(招待講演)
    • Place of Presentation
      Toledo(Spain)
    • Related Report
      2011 Research-status Report
  • [Presentation] パラジウム架橋ポルフィリン多量体の合成と光物性2011

    • Author(s)
      荒谷直樹・宋建新・穴吹翔馬・忍久保洋・大須賀篤弘
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎大学(宮崎市)
    • Related Report
      2011 Research-status Report
  • [Presentation] ハイブリッド型ポルフィリンテープの合成と物性2011

    • Author(s)
      田中隆行・荒谷直樹・大須賀篤弘
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学(岡山市)
    • Related Report
      2011 Research-status Report
  • [Presentation] パラジウム(II)錯化によるヘプタフィリンのN-混乱ポルフィリン骨格を有する錯体への転位反応2011

    • Author(s)
      米田友貴・斎藤尚平・依光英樹・大須賀篤弘
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場(つくば市)
    • Related Report
      2011 Research-status Report
  • [Presentation] 巨大ポルフィリンアレイの合成と光物性2011

    • Author(s)
      荒谷直樹・宋建新・穴吹翔馬・忍久保洋・大須賀篤弘
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山市)
    • Related Report
      2011 Research-status Report
  • [Presentation] Palladium-Catalyzed Direct Arylation of Porphyrins2011

    • Author(s)
      Yu Kawamata, Sumito Tokuji, Hideki Yorimitsu, Atsuhiro Osuka
    • Organizer
      7th International Symposium on Integrated Synthesis
    • Place of Presentation
      シーサイドホテル舞子ビラ神戸(神戸市)
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://kuchem.kyoto-u.ac.jp/shuyu

    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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