Synthetic application of acid activated diazonium carbon species
Project/Area Number |
23655036
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Organic chemistry
|
Research Institution | Kyoto University |
Principal Investigator |
HASHIMOTO Takuya 京都大学, 理学(系)研究科(研究院), 助教 (20437198)
|
Project Period (FY) |
2011 – 2013
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
|
Keywords | ジアゾカルボニル化合物 / 酸触媒 / 不斉合成 / キラルブレンステッド酸 / ジアゾ化合物 / 酸 / 触媒 |
Research Abstract |
One main focus of organic chemistry is to develop a catalysis with which a complex molecule can be synthesized starting from simple substrates. In this regard, use of transition metal such as palladium, rhodium and copper has been widely studied. This is also true for the reactions using diazo carbonyl compounds as substrate. In this research project, use of environmentally benign, non-metallic Bronsted acid was chosen as a catalyst for the activation of diazocarbonyl compounds and successfully developed a couple of useful transformations.
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Report
(4 results)
Research Products
(8 results)