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Synthesis of Two-Dimensional Polymer at the Liquid/Solid Interface

Research Project

Project/Area Number 23655040
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionOsaka University

Principal Investigator

TAHARA Kazukuni  大阪大学, 基礎工学研究科, 助教 (40432463)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords自己組織化 / 超分子化学 / 二次元ポリマー / STM / 固液界面
Research Abstract

This proposal aims at the synthesis of two-dimensional (2D) polymers using self-assembly of reactive molecules at the liquid/solid interfaces. First project is the synthesis of 2D polymer using imine forming reaction between a host network and guest molecule. Amino groups and formyl groups were introduced to the host network and guest molecule, respectively. Upon addition of acid catalyst, STM observations suggested the formation of linkages between them. Second project is the synthesis of porous 2D polymer using cross-linking of the diacetylene units in the host network. However the formation of linkages was not observed. On the basis of this result, new molecular design to achieve the synthesis of porous 2D polymer is established.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (14 results)

All 2014 2013 2012 2011 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (11 results) Remarks (1 results)

  • [Journal Article] Harnessing a Diacetylene Unit: A Molecular Design for Porous Two-Dimensional Network Formation by Self-Assembly of Alkoxy Dehydrobenzo[12]annulene Derivatives at the Liquid/Solid Interface2014

    • Author(s)
      Tahara, K.; Adisoejoso, J.; Inukai, K.; Lei, S.; Noguchi, A.; Li, B.; Vanderlinden, W.; De Feyter, S.; Tobe, Y.
    • Journal Title

      Chem. Commun.

      Volume: 50 Issue: 22 Pages: 2831-2833

    • DOI

      10.1039/c3cc47949h

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembled Air-Stable Supramolecular Porous Networks on Graphene2013

    • Author(s)
      Li, B.; Tahara, K.; Adisoejoso, J.; Vanderlinden, W.; Mali, K.; De Gendt, S.; Tobe, Y.; De Feyter, S.
    • Journal Title

      ACS Nano

      Volume: 7 Issue: 12 Pages: 10764-10772

    • DOI

      10.1021/nn4039047

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Porous Molecular Networks on Graphene Formed by Self-Assembly of Dehydrobenzo[12]annulene Derivatives2014

    • Author(s)
      Tahara, K.; Li, B.; Adisoejoso, J.; Vanderlinden, W.; De Gent, S.; De Feyter, S.; Tobe, Y.
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of Covalently Linked 2D Molecular Network Using Imine Forming Reaction at the Liquid/Solid Interfaces2013

    • Author(s)
      Kazukuni TAHARA , Kyohei KANEKO, Yoshito TOBE
    • Organizer
      11th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      Arcachon, France
    • Year and Date
      2013-06-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Approaches to Synthesis of Covalently Linked 2D Molecular Networks at Liquid/Solid Interfaces2013

    • Author(s)
      Kazukuni Tahara, Kyohei Kaneko, Koji Inukai, Jinne Adisoejoso, Steven De Feyter, Yoshito Tobe
    • Organizer
      FNANO-13 - 10th Annual Conf on Foundations of Nanoscience : Self-Assembled Architectures & Devices
    • Place of Presentation
      Snowbird, USA
    • Year and Date
      2013-04-16
    • Related Report
      2013 Final Research Report
  • [Presentation] (4) Harnessing Diacetylene Units for Formation of Porous Two-Dimensional Network of Dehydrobenzo[12]annulene Derivatives at the Liquid/Solid Interface2013

    • Author(s)
      Tahara, K.; Adisoejoso, J.; Inukai, K.; Li, B.; De Feyter, S.; Tobe, Y.
    • Organizer
      Aachen-Osaka Joint Symposium
    • Place of Presentation
      RWTH Aachen, Aachen, Germany
    • Related Report
      2013 Annual Research Report
  • [Presentation] イミン形成反応を利用した固液界面における二次元ポリマーの合成に関する研究2012

    • Author(s)
      金子恭平, 太田雄介, 田原一邦, 戸部義人
    • Organizer
      第2回CSJ 化学フェスタ
    • Place of Presentation
      東京
    • Year and Date
      2012-10-16
    • Related Report
      2013 Final Research Report
  • [Presentation] イミン形成反応を利用した固液界面における二次元ポリマーの合成に関する研究2012

    • Author(s)
      金子恭平, 太田雄介, 田原一邦, 戸部義人
    • Organizer
      第23回基礎有機化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2012-09-19
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] イミン形成反応を利用した固液界面における二次元ポリマーの合成に関する研究2012

    • Author(s)
      金子恭平
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] アルキル鎖間の相互作用を利用した固体表面上における多孔性二次元分子配列の構築と制御2012

    • Author(s)
      田原一邦
    • Organizer
      第92回日本化学会春季年会
    • Place of Presentation
      慶応大学(横浜)
    • Related Report
      2011 Research-status Report
  • [Presentation] Tailored Pores in Two-Dimensional Molecular Networks on a Surface: Light Driven Pore Size Modulation2011

    • Author(s)
      Kazukuni Tahara
    • Organizer
      10th International Symposium on Functional pi-Electron System
    • Place of Presentation
      北京(中国)
    • Related Report
      2011 Research-status Report
  • [Presentation] 表面ナノ空間におけるクリック反応に関する研究2011

    • Author(s)
      板野慎太郎
    • Organizer
      第7回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      広島大学(東広島)
    • Related Report
      2011 Research-status Report
  • [Presentation] 表面ナノ空間におけるクリック反応に関する研究2011

    • Author(s)
      板野慎太郎
    • Organizer
      第五回有機π電子系シンポジウム
    • Place of Presentation
      天王寺(大阪)
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.supra.chem.es.osaka-u.ac.jp

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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