Synthesis of Two-Dimensional Polymer at the Liquid/Solid Interface
| Project/Area Number |
23655040
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 自己組織化 / 超分子化学 / 二次元ポリマー / STM / 固液界面 |
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| Research Abstract |
This proposal aims at the synthesis of two-dimensional (2D) polymers using self-assembly of reactive molecules at the liquid/solid interfaces. First project is the synthesis of 2D polymer using imine forming reaction between a host network and guest molecule. Amino groups and formyl groups were introduced to the host network and guest molecule, respectively. Upon addition of acid catalyst, STM observations suggested the formation of linkages between them. Second project is the synthesis of porous 2D polymer using cross-linking of the diacetylene units in the host network. However the formation of linkages was not observed. On the basis of this result, new molecular design to achieve the synthesis of porous 2D polymer is established.
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Report
(4 results)
Research Products
(14 results)
