A study on Complete Spontaneous Resolution of Transition-Metal Complexes
| Project/Area Number |
23655052
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Okayama University |
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Principal Investigator |
SUZUKI Takayoshi 岡山大学, 大学院・自然科学研究科, 准教授 (80249953)
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| Co-Investigator(Renkei-kenkyūsha) |
SUNATSUKI Yukinari 岡山大学, 自然生命科学研究支援センター, 助教 (80362987)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 自然分晶 / キラリティー / 多核金属錯体 / 結晶成長 / コングロメレイト |
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| Research Abstract |
In this study a novel crystallization phenomenon, namely complete spontaneous resolution, has been studied. When some kind of metal complexes bearing organic ligands without any asymmetric centerwere crystallized in a certain condition, either of an enantiomeric pair was always obtained specifically. Trinuclear transition- metal (TM)-lanthanide (Ln)-TM complexes with two tripodal potentially nonadentate Schiff-base ligands or mononuclear TM complexes containing a tripodal imidazole-derived Schiff-base ligand exhibited such an interesting phenomenon. Also, it was found that a choice of TM and Ln metal ions and that of recrystallization solvent are critical for this phenomenon. At this moment, the origin for complete spontaneous resolution or the outbreak of optical activity of chiral compounds are still veiled, but we have established this fascinating phenomenon with finding examples of high reproducibility.
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Report
(3 results)
Research Products
(39 results)
