Development of a photosynthesis-model cell

• Project/Area Number: 23655053
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Inorganic chemistry
• Research Institution: Kyushu University
• Principal Investigator: OGO Seiji 九州大学, 大学院・工学研究院, 教授 (60290904)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: 光合成 / モデル電池 / 水素 / 酸素 / ヒドロゲナーゼ / モデル錯体 / 電池

Research Abstract

New enzymes and their model catalysts have been isolated. [NiFe]hydrogenase from Citrobacter sp. S-77 and [NiFe]P(OEt) complex act as cathode catalysts. Photosystem II from Leptolyngbya sp. strain O-77 and MnTPA complex act as anode catalysts.

Research Products

• [Journal Article] A Functional [NiFe] Hydrogenase Mimic that Catalyzes Electron and Hydride T ransfer from H_2 (2013)
  • Author(s): Seiji Ogo, Koji Ichikawa, et al.
  • Journal Title: Science Volume: 339 Issue: 6120 Pages: 682-684
  • DOI: 10.1126/science.1231345
  • Peer Reviewed
• [Journal Article] Selective Redox Activation of H2 or O2 in a [NiRu] Complex by Aromatic Ligand Effects. (2013)
  • Author(s): Kim, Kyoungmok
  • Journal Title: Organometallics Volume: 32(1) Issue: 1 Pages: 79-87
  • DOI: 10.1021/om300833m
  • Peer Reviewed
• [Journal Article] Novel “H2-oxidizing” [NiFeSe]hydrogenase from Desulfovibrio vulgaris Miyazaki F. (2013)
  • Author(s): Nonaka, Kyoshiro
  • Journal Title: J. Biosci. Bioeng. Volume: 115(4) Issue: 4 Pages: 366-371
  • DOI: 10.1016/j.jbiosc.2012.10.011
  • Peer Reviewed
• [Journal Article] Organometallic Catalysts for Use in a Fuel Cell. (2013)
  • Author(s): Matsumoto, Takahiro
  • Journal Title: ChemCatChem Volume: in press Issue: 6 Pages: 1368-1373
  • DOI: 10.1002/cctc.201200595
  • Peer Reviewed
• [Journal Article] ヒドロゲナーゼをモデルとした触媒開発 (2013)
  • Author(s): 磯邉清
  • Journal Title: BIOINDUSTRY Volume: 30 No.3 Pages: 13-20
  • Peer Reviewed
• [Journal Article] 分子燃料電池 (2013)
  • Author(s): 松本崇弘
  • Journal Title: 化学と工業 Volume: 66-2 Pages: 114-116
  • Peer Reviewed
• [Journal Article] O2-stable Membrane-bound [NiFe]hydrogenase from a Newly Isolated Citrobacter sp. S-77. (2012)
  • Author(s): Eguchi, Shigenobu
  • Journal Title: J. Biosci. Bioeng. Volume: 114(5) Issue: 5 Pages: 479-484
  • DOI: 10.1016/j.jbiosc.2012.05.018
  • NAID: 110009553577
  • Peer Reviewed
• [Journal Article] A Neutral Five-coordinated Organoruthenium(0) Complex: X-ray Structure and Unique Solvatochromism. (2012)
  • Author(s): Jeong, Kihun
  • Journal Title: Chem. Lett. Volume: 41(6) Issue: 6 Pages: 650-651
  • DOI: 10.1246/cl.2012.650
  • NAID: 130004426602
  • Peer Reviewed
• [Journal Article] A mer-Triaqua Rh Complex with a Terpyridine Ligand (2012)
  • Author(s): Inoki, Daisuke; Matsumoto, Takahiro; Nakai, Hidetaka; Ogo, Seiji.*
  • Journal Title: Chem. Lett. Volume: 41(1) Issue: 1 Pages: 116-118
  • DOI: 10.1246/cl.2012.116
  • NAID: 10030222878
  • Peer Reviewed
• [Journal Article] Ru Cyclooctatetraene Precursors for MOCVD (2012)
  • Author(s): Ando, Tatsuya; Nakata, Naoki; Suzuki, Kazuharu; Matsumoto, Takahiro; Ogo, Seiji.*
  • Journal Title: Dalton Trans. Volume: 41(6) Issue: 6 Pages: 1678-1682
  • DOI: 10.1039/c1dt11454a
  • Peer Reviewed
• [Journal Article] Establishing the Mechanism of Rh-catalysed Activation of O2 by H2 (2012)
  • Author(s): Inoki, Daisuke; Matsumoto, Takahiro; Hayashii, Hideki; Takashita, Keisuke; Nakai, Hidetaka; Ogo, Seiji.*
  • Journal Title: Dalton Trans. Volume: 41(15) Issue: 15 Pages: 4328-4334
  • DOI: 10.1039/c1dt11599e
  • Peer Reviewed
• [Journal Article] Simple Ligand Effects Switch a Hydrogenase Mimic between H2 and O2 Activation (2012)
  • Author(s): Kim, Kyoungmok; Matsumoto, Takahiro; Robertson, Andrew; Nakai, Hidetaka; Ogo, Seiji.*
  • Journal Title: Chem. Asian J. Volume: in press Issue: 6 Pages: 1394-1400
  • DOI: 10.1002/asia.201101020
  • Peer Reviewed
• [Journal Article] Experimental Study of Reductive Elimination of H2 from Rhodium Hydride Species (2012)
  • Author(s): Inoki, Daisuke; Matsumoto, Takahiro; Nakai, Hidetaka; Ogo, Seiji.*
  • Journal Title: Organometallics Volume: in press Issue: 8 Pages: 2996-3001
  • DOI: 10.1021/om2009759
  • Peer Reviewed
• [Journal Article] Molecular Catalysis in a Fuel Cell (2011)
  • Author(s): Matsumoto, Takahiro; Kim, Kyoungmok; Ogo, Seiji
  • Journal Title: Angew. Chem. Int. Ed Volume: 50(47) Issue: 47 Pages: 11202-11205
  • DOI: 10.1002/anie.201104498
  • Peer Reviewed
• [Journal Article] Model Study of CO Inhibition of [NiFe]hydrogenase (2011)
  • Author(s): Matsumoto, Takahiro; Kabe, Ryota; Nonaka, Kyoshiro; Ando, Tatsuya; Yoon, Ki-Seok; Nakai, Hidetaka; Ogo, Seiji.*
  • Journal Title: Inorg. Chem. Volume: 50(18) Issue: 18 Pages: 8902-8906
  • DOI: 10.1021/ic200965t
  • Peer Reviewed
• [Journal Article] The Development of Aqueous Transfer Hydrogenation Catalysts (2011)
  • Author(s): Robertson, Andrew; Matsumoto, Takahiro; Ogo, Seiji.*
  • Journal Title: Dalton Trans. Volume: 40(40) Issue: 40 Pages: 10304-10310
  • DOI: 10.1039/c1dt10544b
  • Peer Reviewed
• [Journal Article] Preparation and Reactivity of a Nickel Dihydride Complex. (2011)
  • Author(s): T. Matsumoto, T. Nagahama, J. Cho, T. Hizume, M. Suzuki, and S. Ogo
  • Journal Title: Angew. Chem. Int. Ed Volume: 50 Issue: 45 Pages: 10578-10580
  • DOI: 10.1002/anie.201104918
  • Peer Reviewed
• [Presentation] Platinum Catalysts vs. Enzymes and their Models (2012)
  • Author(s): 小江誠司
  • Organizer: 世界トップレベル研究拠点平成24年度プログラム委員会(2012 WPI Program Committee Meeting)
  • Place of Presentation: 東京、フォーシーズンズホテル椿山荘 東京
  • Year and Date: 2012-10-24
• [Presentation] アクア触媒と界面 (2012)
  • Author(s): 小江誠司
  • Organizer: ナノ界面技術の基盤構築」研究領域 第1回公開ワークショップ
  • Place of Presentation: 東京、科学技術振興機構
• [Presentation] 九大学研都市における最先端研究 (2012)
  • Author(s): 小江誠司
  • Organizer: 九州大学学術研究都市構想促進東京会議第10回総会・交流会(招待講演)
  • Place of Presentation: 東京、ザ・プリンスタワー東京
• [Presentation] Biomimetic Fuel Cell (2012)
  • Author(s): 小江誠司
  • Organizer: 第1回 I2CNER Annual Symposium 2012, I2CNER International Workshop 2012(招待講演)
  • Place of Presentation: 福岡、九州大学
• [Presentation] 自然の知恵を技術へ (2012)
  • Author(s): 小江誠司
  • Organizer: みんなの科学広場in唐津2012(招待講演)
  • Place of Presentation: 佐賀、唐津、唐津市ふるさと会館
• [Presentation] Biomimetic Hydrogen Activation (2012)
  • Author(s): 小江誠司
  • Organizer: I2CNER Satellite Kick-Off Symposium(招待講演)
  • Place of Presentation: アメリカ、イリノイ、シャンペーン
• [Presentation] 水素からのエネルギー:生物に学ぶエネルギーのつくり方 (2011)
  • Author(s): 小江誠司
  • Organizer: 世界トップレベル研究拠点プログラム(WPI)6 拠点合同シンポジウム- 最先端の科学と君たちの未来 -
  • Place of Presentation: 福岡、福岡銀行本店大ホール
  • Year and Date: 2011-11-12
• [Presentation] Electrons from Hydrogen (2011)
  • Author(s): 小江誠司
  • Organizer: France-Japan Coordination Chemistry Symposium(招待講演)
  • Place of Presentation: フランス、レンヌ
• [Presentation] Energy from Hydrogen (2011)
  • Author(s): 小江誠司
  • Organizer: I2CNER Division Meeting
  • Place of Presentation: 福岡、福岡市産学連携交流センター
• [Presentation] 水素からのエネルギー：生物に学ぶエネルギーのつくり方 (2011)
  • Author(s): 小江誠司
  • Organizer: 世界トップレベル研究拠点プログラム（WPI）6拠点合同シンポジウム(招待講演)
  • Place of Presentation: 福岡、福岡銀行本店大ホール
• [Presentation] Energy from Hydrogen (2011)
  • Author(s): 小江誠司
  • Organizer: The 3rd Dalton Transactions International Symposium(招待講演)
  • Place of Presentation: 大阪、大阪大学・福岡、九州大学
• [Presentation] 水素からの電子抽出 (2011)
  • Author(s): 小江誠司
  • Organizer: 2011年度触媒学会北海道支部札幌講演会(招待講演)
  • Place of Presentation: 札幌、北海道大学
• [Presentation] Molecular Catalysis in a Fuel Cell
  • Author(s): 小江誠司
  • Organizer: 9th Japan-China Joint Symposium on Metal Cluster Compounds (9th JCSMCC)
  • Place of Presentation: 福岡、ヒルトン福岡シーホーク
  • Invited
• [Presentation] Platinum Catalysts vs. Enzymes and their Models
  • Author(s): 小江誠司
  • Organizer: 世界トップレベル研究拠点平成２４年度プログラム委員会（2012 WPI Program Committee Meeting）
  • Place of Presentation: 東京、フォーシーズンズホテル椿山荘 東京
  • Invited
• [Presentation] Molecular Catalysis in a Fuel Cell
  • Author(s): 小江誠司
  • Organizer: The 2nd International Conference on MEXT Project of Integrated Researchon Chemical Synthesis “Molecular Functions in Complex Systems”
  • Place of Presentation: 愛知、名古屋大学野依記念学術交流館
  • Invited
• [Presentation] From Nature to Technology-Activating Dihydrogen by Hydrogenase Model Complexes
  • Author(s): 小江誠司
  • Organizer: I2CNER International Workshop 2013 Advanced Materials Transformations
  • Place of Presentation: 福岡、I2CNER Building Hall C
  • Invited
• [Presentation] ヒドロゲナーゼ機能モデル錯体による触媒的水素活性化とエネルギー創出
  • Author(s): 小江誠司
  • Organizer: 日本化学会第９３春期年会
  • Place of Presentation: 滋賀、立命館大学、びわこ・くさつキャンパス
  • Invited
• [Presentation] Inspired by Nature-New Energy Sources from Hydrogenase Model Complexes
  • Author(s): 小江誠司
  • Organizer: The 1st International Symposium of the Advanced Graduate Program on Molecular Systems for Devices
  • Place of Presentation: 福岡、ヒルトン福岡シーホーク
  • Invited
• [Remarks]
  • URL: http://web.cstm.kyushu-u.ac.jp/ogo/
• [Patent(Industrial Property Rights)] 金属錯体及び過酸化水素の製造方法 (2012)
  • Inventor(s): 小江誠司・加藤賢治長田昌輝・
  • Industrial Property Rights Holder: 小江誠司・加藤賢治長田昌輝・
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-205229
  • Filing Date: 2012-09-19
• [Patent(Industrial Property Rights)] ヒドリド金属錯体を用いて水素分子から電子を取り出す方法、および基質を還元する方法 (2012)
  • Inventor(s): 小江誠司・松本崇弘・大島俊二・林秀樹
  • Industrial Property Rights Holder: 小江誠司・松本崇弘・大島俊二・林秀樹
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-233783
  • Filing Date: 2012-10-23