Creation of photofunctional lanthanide complexes: Challenge to photo-induced nitrogen-nitrogen triple bond cleavage
| Project/Area Number |
23655054
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
NAKAI Hidetaka 九州大学, 工学(系)研究科(研究院), 准教授 (70377399)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 合成化学 / 光物性 / ランタニド / 窒素固定 / 有機金属錯体 |
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| Research Abstract |
In order to challenge the construction of new photo-induced material transformation system, the research has been focused on the synthesis of highly reactive lanthanide complexes by using photofuncitional ligands that contain polycyclic aromatic groups with high absorption coefficient. The obtained results are as follows: (1) A THF-free samarium(II) complex which is expected to interact with dinitrogen has been successfully synthesized. (2) A photoresponsive gadolinium(III) complex leading to the construction photo-induced reaction system has been successfully synthesized.
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Report
(4 results)
Research Products
(18 results)
