Development of hydrophosphination of unsaturated hydrocarbons catalyzed by iron complex

• Project/Area Number: 23655056
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Inorganic chemistry
• Research Institution: Osaka City University
• Principal Investigator: NAKAZAWA Hiroshi 大阪市立大学, 大学院・理学研究科, 教授 (00172297)
• Co-Investigator(Kenkyū-buntansha): ITAZAKI Masumi 大阪市立大学, 大学院・理学研究科, 講師 (60382032) ; KAMEO Hajime 大阪市立大学, 大学院・理学研究科, 特任講師 (50597218)
• Project Period (FY): 2011 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: ヒドロリン化反応 / 触媒反応 / 鉄錯体 / ダブル付加反応

Research Abstract

The first catalytic double hydrophosphination of alkynes was achieved by reaction with diarylphosphines in the presence of an iron catalyst. The double hydrophosphination proceeded regioselectively and effectively for various secondary aryl pho

Research Products

• [Journal Article] Regioselective Double Hydrophosphination ofTerminal Arylacetylenes Catalyzed by an Iron Complex (2012)
  • Author(s): M. Kamitani, M. Itazaki, C. Tamiya, and H. Nakazawa
  • Journal Title: J. Am. Chem. Soc Volume: 134 Pages: 11932-11935
  • Peer Reviewed
• [Journal Article] Synthesis of Iridaboratranes BearingPhosphine-Tethered Borane: Reversible CO/PR_3(R = Me, Ome, and Oet) Substitution Reaction Induced by σ-Electron Acceptor Borane Ligand. (2012)
  • Author(s): H. Kameo, Y. Hashimoto, and H. Nakazawa
  • Journal Title: Organometallics Volume: 31 Issue: 11 Pages: 4251-4258
  • DOI: 10.1021/om300216g
  • Peer Reviewed
• [Journal Article] Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands (2012)
  • Author(s): K. Kamata, A. Suzuki, Y.Nakai, and H. Nakazawa
  • Journal Title: Organometallics Volume: 31 Issue: 10 Pages: 3825-3828
  • DOI: 10.1021/om300279t
  • Peer Reviewed
• [Journal Article] Catalytic Synthesis of Cyclic and Linear Germoxanes Mediated by Iron Complex (2012)
  • Author(s): M.Kamitani, K.Fukumoto, R.Tada, M.Itazaki, H.Nakazawa
  • Journal Title: Organometallics Volume: 31 Issue: 8 Pages: 2957-2960
  • DOI: 10.1021/om3001845
  • Peer Reviewed
• [Journal Article] Desulfurization of N, N-dimethylthioformamide by Hydrosilane with the Help of an Iron Complex. Isolation and Characterization of an Iron-carbene Complex as an Intermediate of C=S Double Bond Cleavage (2012)
  • Author(s): K.Fukumoto, A.Sakai, T.Oya, H.Nakazawa
  • Journal Title: Chem.Commun. Volume: 48 Issue: 32 Pages: 3809-3811
  • DOI: 10.1039/c2cc17163e
  • Peer Reviewed
• [Journal Article] O-CN Bond Cleavage of Cyanates by a Transition-Metal Complex (2012)
  • Author(s): K.Fukumoto, A.A.Dahy, T.Oya, K.Hayasaka, M.Itazaki, N.Koga, H, Nakazawa
  • Journal Title: Organometallics Volume: 31 Issue: 3 Pages: 787-790
  • DOI: 10.1021/om201257h
  • Peer Reviewed
• [Journal Article] Selective Dehydrogenative Silylation-Hydrogenation Reaction of Divinyldisiloxane with Hydrosilane Catalyzed by an Iron Complex (2012)
  • Author(s): R.Naumov, M.Itazaki, M.Kamitani, H.Nakazawa
  • Journal Title: J.Am.Chem.Soc. Volume: 134 Issue: 2 Pages: 804-807
  • DOI: 10.1021/ja209436s
  • Peer Reviewed
• [Journal Article] A DFT Study on Geometric Preference of Non-bridging Form to Bridging Form in Molybdenum Complexes with Phosphenium Ligand (2012)
  • Author(s): N.Tsuchida, M.Isoi, H.Nakazawa, K.Takano
  • Journal Title: J.Organomet.Chem. Volume: 697 Issue: 1 Pages: 41-50
  • DOI: 10.1016/j.jorganchem.2011.10.014
  • Peer Reviewed
• [Journal Article] Synthesis and Reactivity of Rhodium Complexes Bearing [E(o-C6H4PPh2)3] Type Tetradentate Ligands (E = Si, Ge, and Sn) (2012)
  • Author(s): H. Kameo, S. Ishii, and H. Nakazaw
  • Journal Title: Organometallics Volume: 31 Pages: 2212-2218
  • Peer Reviewed
• [Journal Article] Synthesis of Rhodaboratranes Bearing Phosphine-Tethered Boranes : Evaluation of the Metal-borone Interaction (2012)
  • Author(s): H.Kameo, Y.Hashimoto, H.Nakazawa
  • Journal Title: Organometallics Volume: 31 Issue: 8 Pages: 3155-3162
  • DOI: 10.1021/om3000423
  • Peer Reviewed
• [Journal Article] Density Functional Theory Study of N-CN and O-CN Bond Cleavage by an Iron Silyl Complex (2012)
  • Author(s): A. A. Dahy, N. Koga, and H. Nakazawa
  • Journal Title: Organometallics Volume: 31 Issue: 10 Pages: 3995-4005
  • DOI: 10.1021/om300232h
  • Peer Reviewed
• [Journal Article] Synthesis of Iridium Complexes Bearing {(o-Ph2PC6H4)}3E Type (E = Si, Ge, and Sn) Ligand and Evaluation of Electron Donating Ability of Group 14 Elements (2012)
  • Author(s): H. Kameo, S. Ishii, and H. Nakazawa
  • Journal Title: Dalton Trans. Volume: 41 Issue: 27 Pages: 8290-8296
  • DOI: 10.1039/c2dt30546a
  • Peer Reviewed
• [Journal Article] Regioselective Double Hydrophosphination of Terminal Arylacetylenes Catalyzed by an Iron Complex (2012)
  • Author(s): 神谷昌宏、板崎真澄、田宮千裕、中沢浩
  • Journal Title: Journal of American Chemical Society Volume: 134 Issue: 29 Pages: 11932-11935
  • DOI: 10.1021/ja304818c
  • Peer Reviewed
• [Journal Article] Facile Synthesis of Rhodium and Iridium Complexes Bearing a [PEP]-type Ligand (E = Ge or Sn) via E-C Bond Cleavage (2012)
  • Author(s): H. Kameo, S. Ishii, and H. Nakazawa
  • Journal Title: Dalton Trans. Volume: 41 Issue: 37 Pages: 11386-11392
  • DOI: 10.1039/c2dt30996c
  • Peer Reviewed
• [Journal Article] Synthesis of a Rhodium Complex Featuring the Rh-H-B Linkage via a Hydride Migration from Rh to Borane: A Study on the Electronic Deviation Induced by the presence of the Boron Moiety (2012)
  • Author(s): H. Kameo and H. Nakazawa
  • Journal Title: Organometallics Volume: 31 Issue: 21 Pages: 7476-7484
  • DOI: 10.1021/om300762u
  • Peer Reviewed
• [Journal Article] Dehydrogenative Coupling of Thiol with Hydrosilane Catalyzed by an Iron Complex (2011)
  • Author(s): K.Fukumoto, M.Kasa, T, Oya, M.Itazaki, H.Nakazawa
  • Journal Title: Organometallics Volume: 30 Issue: 13 Pages: 3461-3463
  • DOI: 10.1021/om200377e
  • Peer Reviewed
• [Journal Article] Trans-Selective Hydrogermylation of Alkynes Promoted by Methyliron andBis(germyl)hydridoiron Complexes as a Catalyst Precursor. (2011)
  • Author(s): M. Itazaki, M. Kamitani, and H. Nakazawa
  • Journal Title: Chem. Commun Volume: 47 Issue: 27 Pages: 7854-7856
  • DOI: 10.1039/c1cc12530c
  • Peer Reviewed
• [Journal Article] Synthesis of Silyl-molybdenium Complexes Connected by a 1,1'-Metal locenylene Unit and Their Electrochemical Properties (2011)
  • Author(s): M.Itazaki, A.Ichimura, H.Nakazawa
  • Journal Title: Eur.J.Inorg.Chem. Volume: 2011 Issue: 36 Pages: 5496-5501
  • DOI: 10.1002/ejic.201100867
  • Peer Reviewed
• [Journal Article] Characterization, and Crystal Structure of cis-[Pt(Me)2{PPh2(OMe)}2] and the Conversion into cis-[Pt(OH2)2{PPh2(OMe)}2] [OTf]2 (2011)
  • Author(s): M. Itazaki, Y. Shigesato, and H. Nakazawa
  • Journal Title: Heteroatom Chem. Volume: 22 Pages: 371-376
  • Peer Reviewed
• [Journal Article] Fac-mer Isomerization of Mo(CO)_3(phosphite)_3 Caused by Interaction between Phosphite Oxygen and Silane Silicon (2011)
  • Author(s): K.Fukumoto, H.Nakazawa
  • Journal Title: Phosphorus, Sulfur, and Silicon, and the Related Elements Volume: 186 Issue: 4 Pages: 660-663
  • DOI: 10.1080/10426507.2010.520290
  • Peer Reviewed
• [Journal Article] Trans-Selective Hydrogermylation of Alkynes Promoted by Methyliron and Bis(germyl)hydridoiron Complexes as a Catalyst Precursor (2011)
  • Author(s): M.Itazaki, M.Kamitani, H.Nakazawa
  • Journal Title: Chem.Commun. Volume: 47 Issue: 3 Pages: 7854-7856
  • DOI: 10.1021/cr100347k
  • Peer Reviewed
• [Presentation] Electrochemical Properties of Transition-metal Complexes connected by 1,1'-Ferrocenedichalcogenato Ligand and Their Structures (2013)
  • Author(s): M. Ito, M. Itazaki, H. Nakazawa
  • Organizer: The 17th Osaka City University International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] Conversion of Thiourea Derivatives into Carbodiimides by Using an Iron Complex (2013)
  • Author(s): K. Hayasaka, K. Fukumoto, H. Nakazawa
  • Organizer: The 17th Osaka City University International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] Reaction of Imine with Hydrosilane Mediated by an Iron Complex (2013)
  • Author(s): J. Nishimuki, K. Hayasaka, K. Fukumoto, H. Nakazawa
  • Organizer: The 17th Osaka City University International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] ハロゲン化イオンを配位とする鉄およびルテニウム錯体の合成と構造 (2013)
  • Author(s): 伊藤昌輝、板崎真澄、中沢 浩
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学
• [Presentation] ロジウムおよびイリジウムヒドリド錯体によるSi-E (E = C, O)結合活性化 (2013)
  • Author(s): 亀尾 肇、石井 翔、中沢 浩
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学
• [Presentation] フェロセニルシリル配位子を２つ有するルテニウム(IV)ヒドリド錯体の合成と電気化学的性質 (2013)
  • Author(s): 板崎真澄、重里有香、南方牧子、石井 翔、市村彰男、中沢 浩
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学
• [Presentation] 1,1'-フェロセンジカルコゲナト配位子を有する白金鉄錯体の合成と反応性 (2013)
  • Author(s): 板崎真澄、井関柾登、伊藤昌輝、中沢 浩
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学
• [Presentation] σ電子受容性ゲルマン配位子を有する金属錯体の合成 (2013)
  • Author(s): 亀尾 肇、川本達也、中沢 浩
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学
• [Presentation] 鉄錯体を用いたチオ尿素の脱水素脱硫反応によりカルボジイミド形成 (2012)
  • Author(s): 早坂和将、福本晃造、中沢 浩
  • Organizer: 第39回有機典型元素化学討論会
  • Place of Presentation: 盛岡
• [Presentation] Hydrosilylation of Alkenes Catalyzed by Iron Complexes Bearing a Terpyridine Derivative (2012)
  • Author(s): H. Nakazawa, K. Kamata, A. Suzuki.
  • Organizer: 4th Asian Silicon Symposiu
  • Place of Presentation: Tsukuba, Japan
• [Presentation] 新規ヒドリド/ヒドロシリル二官能性鉄触媒の合成およびアルコールとの反応性 (2012)
  • Author(s): 神谷昌宏、板崎真澄、中沢 浩
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山
• [Presentation] Exclusive Si-C Bond Cleavage Induced by a Rhodium Hydride: Comparison of Si-C(sp^2) and Si-C(sp^3) Activation. (2012)
  • Author(s): 亀尾 肇、石井 翔、中沢 浩
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪
• [Presentation] Silyl-Migration-Induced Reaction in Coordination Sphere: RO-CN Bond Cleavage (2012)
  • Author(s): H. Nakazawa, K. Fukumoto, K. Hayasaka, M. Itazaki, N. Koga
  • Organizer: 40 International Conference on Coordination Chemistry
  • Place of Presentation: Valencia, Spain
• [Presentation] Desulfurization of Thioamide with Hydrosilane Catalyzed by an Iron Complex (2012)
  • Author(s): K. Fukimoto, A. Kakai, H. Nakazawa.
  • Organizer: 40 International Conference on Coordination Chemistry
  • Place of Presentation: Valencia, Spain
• [Presentation] Dehydrogenative Desulfurization of Thioureas to Give Carbodiimides Using Silane and Transition-Metal Complex (2012)
  • Author(s): K. Hayasaka, K. Fukimoto, H. Nakazawa.
  • Organizer: International Conference on Coordination Chemistry
  • Place of Presentation: Valencia, Spain
• [Presentation] A New Type of Hydrosilylation of Divinyldisiloxane Caused by an Iron Catalyst (2012)
  • Author(s): H. Nakazawa.
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon,Portugal
• [Presentation] Hydrogermylation of Alkyne Promoted by an Iron Catalyst. (2012)
  • Author(s): M. Kamitani, M. Itazaki, H. Nakazawa
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon,Portugal
• [Presentation] Molybdenum-Catalyzed C=E (E = O, S) Bond Cleavage of Isocyanates and Isothiocyanates with Hydrosilanes. (2012)
  • Author(s): M. Hayasaka, K. Fukumoto, H. Nakazawa
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon,Portugal
• [Presentation] Synthesis of Rhodium and Iridium Complexes Bearing Phosphine-Tethered Borane. (2012)
  • Author(s): H. Kameo, Y. Hashimoto, H. Nakazawa
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon,Portugal
• [Presentation] Double Hydrophosphination of Alkynes with Secondary Phosphones Promoted by Iron Catalyst. (2012)
  • Author(s): H. Nakazawa, M. Kamitani, M. Itazaki, C. Tamiya.
  • Organizer: 19th International Conference on Phosphorus Chemistry
  • Place of Presentation: Rotterdam, The Netherlands
• [Presentation] Reactivity of Molybdenum Complexes Bearing both Acyl and Phosphite Ligands with a Lewis Acid (2012)
  • Author(s): K. Fukumoto, K. Nito, K. Hayasaka, H. Nakazawa.
  • Organizer: 19th International Conference on Phosphorus Chemistry
  • Place of Presentation: Rotterdam, The Netherlands
• [Presentation] Selective Synthesis of Cyclic and Linear Germoxanes Catalyzed by an Iron Complex (2012)
  • Author(s): H. Nakazawa, M. Kamitani, R. Tada, K. Fukumoto, and M. Itazaki
  • Organizer: The 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Uji
• [Presentation] Synthesis of Rhodaboratrans Bearing Phosphine-Tethered Boranes: Evaluation of the Metal-Boron Interaction. (2012)
  • Author(s): H. Kameo, Y. Hashimoto, and H. Nakazawa
  • Organizer: The 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Uji
• [Presentation] Conversion of Isothiocyanates (R-NCS) into Isocyanides (R-NC) with C=S Bond Cleavage Mediated by a Molybdenum Complex (2012)
  • Author(s): K. Hayasaka, K. Fukumoto, and H. Nakazawa
  • Organizer: The 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Uji
• [Presentation] Selective Synthesis of Cyclic and Linear Germoxanes Catalyzed by an Iron Complex (2012)
  • Author(s): H. Nakazawa, M. Kamitani, R. Tada, K. Fukumoto, and M. Itazaki
  • Organizer: The 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Uji, Japan
• [Presentation] Synthesis of Rhodaboratrans Bearing Phosphine-Tethered Boranes: Evaluation of the Metal-Boron Interaction (2012)
  • Author(s): H. Kameo, Y. Hashimoto, and H. Nakazawa
  • Organizer: The 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Uji, Japan
• [Presentation] Conversion of Isothiocyanates (R-NCS) into Isocyanides (R-NC) with C=S Bond Cleavage Mediated by a Molybdenum Complex (2012)
  • Author(s): K. Hayasaka, K. Fukumoto, and H. Nakazawa
  • Organizer: The 10th International Conference on Heteroatom Chemistry
  • Place of Presentation: Uji, Japan
• [Presentation] Double Hydrophosphination of Alkynes with Secondary Phosphones Promoted by Iron Catalyst (2012)
  • Author(s): H. Nakazawa, M. Kamitani, M. Itazaki, C. Tamiya
  • Organizer: 19th International Conference on Phosphorus Chemistry
  • Place of Presentation: Lotterdam, Netherlands
• [Presentation] Reactivity of Molybdenum Complexes Bearing both Acyl and Phosphite Ligands with a Lewis Acid (2012)
  • Author(s): K. Fukumoto, K. Nito, K. Hayasaka, H. Nakazawa
  • Organizer: 19th International Conference on Phosphorus Chemistry
  • Place of Presentation: Lotterdam, Netherlands
• [Presentation] A New Type of Hydrosilylation of Divinyldisiloxane Caused by an Iron Catalyst (2012)
  • Author(s): H. Nakazawa
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon, Portugal
• [Presentation] Hydrogermylation of Alkyne Promoted by an Iron Catalyst (2012)
  • Author(s): M. Kamitani, M. Itazaki, H. Nakazawa
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon, Portgal
• [Presentation] Molybdenum-Catalyzed C=E (E = O, S) Bond Cleavage of Isocyanates and Isothiocyanates with Hydrosilanes (2012)
  • Author(s): M. Hayasaka, K. Fukumoto, H. Nakazawa
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon, Portgal
• [Presentation] Synthesis of Rhodium and Iridium Complexes Bearing Phosphine-Tethered Borane (2012)
  • Author(s): H. Kameo, Y. Hashimoto, H. Nakazawa
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon, Portgal
• [Presentation] Dehydrogenative Desulfurization of Thioureas to Give Carbodiimides Using Silane and Transition-Metal Complex (2012)
  • Author(s): K. Hayasaka, K. Fukimoto, H. Nakazawa
  • Organizer: 40 International Conference on Coordination Chemistry
  • Place of Presentation: Valencia, Spain
• [Presentation] A DFT Study of RnX-CN 'X = C, N, and O) Bond Cleavage by an Iron Silyl Complex (2012)
  • Author(s): N. Koga, A. Dahy, H. Nakazawa
  • Organizer: 40 International Conference on Coordination Chemistry
  • Place of Presentation: Valencia, Spain
• [Presentation] Hydrosilylation of Alkenes Catalyzed by Iron Complexes Bearing a Terpyridine Derivative (2012)
  • Author(s): H. Nakazawa, K. Kamata, A. Suzuki
  • Organizer: 4th Asian Silicon Symposium
  • Place of Presentation: Tsukuba, Japan
• [Presentation] Synthesis of Group 9 Transition Metal Complexes Bearing an EP3-type Ligand (E = Si, Ge, Sn): Evaluation of Electron Donor Ability of E (2012)
  • Author(s): S. Ishii. H. Kameo, H. Nakazawa
  • Organizer: 4th Asian Silicon Symposium
  • Place of Presentation: Tsukuba, Japan
• [Presentation] Si-C(sp2) and Si-C(sp3) Activation Induced by Hydride Complexes of Rhodium and Iridium (2012)
  • Author(s): H. Kameo, S. Ishii, H. Nakazawa
  • Organizer: 4th Asian Silicon Symposium
  • Place of Presentation: Tsukuba, Japan
• [Presentation] Hydrogen Production from Alcohols Promoted by an Iron Complex (2012)
  • Author(s): 神谷昌宏、板崎真澄、中沢 浩
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学
• [Presentation] Exclusive Si-C Bond Cleavage Induced by a Rhodium Hydride: Comparison of Si-C(sp2) and Si-C(sp3) Activation (2012)
  • Author(s): 亀尾 肇、石井 翔、中沢 浩
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学
• [Presentation] EP3 型配位子(E = Si, Ge, Sn)を有する９族遷移金属錯体の合成とＥの電子供与能およびトランス影響の評価 (2012)
  • Author(s): 石井 翔、亀尾 肇、中沢 浩
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学
• [Presentation] 新規ヒドリド/ヒドロシリル二官能性鉄触媒の合成およびアルコールとの反応性 (2012)
  • Author(s): 神谷昌宏、板崎真澄、中沢 浩
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学
• [Presentation] Property and Reactivity of Rhodium and Iridium Complexes Bearing a Sigma-acceptor (Z-type) Borane Ligand (2012)
  • Author(s): 亀尾 肇、中沢 浩
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学
• [Presentation] 1,1'-フェロセンジカルコゲナト基を配位子とする遷移金属多核錯体の合成と性質 (2012)
  • Author(s): 伊藤昌輝、板崎真澄、山本健弥、中沢 浩
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学
• [Presentation] ホスフィンテザー型ボランを有するロジウムおよびイリジウム錯体の合成とホウ素配位子の配位圏での挙動 (2012)
  • Author(s): 亀尾 肇、濱口智行、中沢 浩
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス
• [Presentation] [E(o-C6H4PPh2)3] (E = Si, Ge, Sn)型４座配位子を有するロジウム錯体の合成 (2012)
  • Author(s): 石井 翔、亀尾 肇、中沢 浩
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス
• [Presentation] 遷移金属錯体を用いたチオ尿素の脱硫反応 (2012)
  • Author(s): 早坂和将、福本晃造、中沢 浩
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス
• [Presentation] ターピリジン誘導体を配位子とする鉄錯体のヒドロシリル化触媒能 (2012)
  • Author(s): 鈴木敦子、中井悠太、鎌田幸司、中沢 浩
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス
• [Presentation] 鉄触媒によるチオアミドからのイミン合成 (2012)
  • Author(s): 酒井 茜、福本晃造、大矢 創、中沢 浩
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス
• [Presentation] ニトロニルニトリキシドが直接連結した単核および二核白金錯体の合成と性質 (2012)
  • Author(s): 張 珣、鈴木修一、小嵜正敏、神谷昌宏、中沢 浩、岡田惠次
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス
• [Presentation] ジアミノ置換ホスフィンを丹治する白金錯体上のアルキル/ハロゲン交換反応に関する量子化学的研究 (2012)
  • Author(s): 高島麻里、土田敦子、重里有香、板崎真澄、中沢 浩、鷹野景子
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学日吉キャンパス
• [Presentation] C-CN and N-CN Bond Breaking Promoted by Silyl Migration in Coordination Sphere (2011)
  • Author(s): H. Nakazawa.
  • Organizer: 3rd Asian Conference on Coordination Chemistry
  • Place of Presentation: New Delhi, India
• [Presentation] Synthesis and Catalytic Reactivity of Iron(IV) Complex Bearing Two Heavier Group 14 Element Ligands (2011)
  • Author(s): M. Kamitani, M. Itazaki, K. Ueda, and H. Nakazawa.
  • Organizer: 3rd Asian Conference on Coordination Chemistry
  • Place of Presentation: New Delhi, India
• [Presentation] Selective Formation of Cyclic and Linear Germoxanes from Hydrogermane and Amide Catalyzed by an Iron Complex (2011)
  • Author(s): H. Nakazawa, M. Kamitani, R. Tada, and M. Itazaki
  • Organizer: The 3nd Latinoamerican Symposium on Coordination and Organometallic Chemistry
  • Place of Presentation: La Serena, Chile
• [Presentation] Strong Bond Cleavage Promoted by Silyl Group Migration in a Coordination Sphere (2011)
  • Author(s): H. Nakazawa
  • Organizer: First International Conference on Sustainable Chemistry.
  • Place of Presentation: Antwerp, Belgium.
• [Presentation] Strong Bond Cleavage Promoted by Silyl Group Migration in a Coordination Sphere (2011)
  • Author(s): H. Nakazawa
  • Organizer: First International Conference on Sustainable Chemistry(招待講演)
  • Place of Presentation: Antwerp, Belgium
• [Presentation] Selective Formation of Cyclic and Linear Germoxanes from Hydrogermane and Amide Catalyzed by an Iron Complex (2011)
  • Author(s): H. Nakazawa, M. Kamitani, R. Tada, and M. Itazaki
  • Organizer: The 3nd Latinoamerican Symposium on Coordination and Organometallic Chemistry(招待講演)
  • Place of Presentation: La Serena, Chile
• [Presentation] C-CN and N-CN Bond Breaking Promoted by Silyl Migration in Coordination Sphere (2011)
  • Author(s): H. Nakazawa
  • Organizer: 3rd Asian Conference on Coordination Chemistry(招待講演)
  • Place of Presentation: New Delhi, India
• [Presentation] Structure and Reactivity of Rhodium Complexes Bearing [E(o-C6H4PPh2)3] Type Tetradentate Ligand (E = Si, Ge, Sn) (2011)
  • Author(s): S. Ishii, H. Kameo, and H. Nakazawa
  • Organizer: The 16th Osaka City University International Symposium
  • Place of Presentation: Osaka
• [Presentation] Selective Synthesis of Linear Germoxanes Catalyzed by an Iron Complex (2011)
  • Author(s): R. Tada, M. Kamitani, M. Itazaki, and H. Nakazawa
  • Organizer: The 16th Osaka City University International Symposium
  • Place of Presentation: Osaka
• [Presentation] Synthesis of Transition-metal Complexes Containing 1,1'-Ferrocenedithiolate or 1,1'-Ferrocenediserenate Ligand and Their Electrochiemical Properties (2011)
  • Author(s): M. Ito, M. Itazaki, K. Yamamoto, and H. Nakazawa
  • Organizer: The 16th Osaka City University International Symposium
  • Place of Presentation: Osaka
• [Presentation] Double Hydrophosphination of Alkyne Promoted by Iron Catlyst (2011)
  • Author(s): C. Tamiya, M. Kamitani, M. Itazaki, and H. Nakazawa
  • Organizer: The 16th Osaka City University International Symposium
  • Place of Presentation: Osaka
• [Presentation] C=O Bond Cleavage Reaction of Isocyanates Catalyzed by a Transition Metal Complex (2011)
  • Author(s): K. Hayasaka, K. Fukumoto, and H. Nakazawa
  • Organizer: The 16th Osaka City University International Symposium
  • Place of Presentation: Osaka
• [Presentation] Synthesis of Iron Complexes with Terpyridine Derivatives and Their Catalytic Activity for Hydrosilylation (2011)
  • Author(s): A. Suzuki, Y. Nakai, K. Kamata, and H. Nakazawa
  • Organizer: The 16th Osaka City University International Symposium
  • Place of Presentation: Osaka
• [Presentation] シリル基転位反応を引き金とする触媒反応 (2011)
  • Author(s): 中沢 浩
  • Organizer: 第38回有機反応懇談会(招待講演)
  • Place of Presentation: 大阪府立大学
• [Presentation] Synthesis of Rhodium and Iridoum Complexes Bearing Phosphine-Tetherd Borane: Evaluation of Metal-Borane Interaction (2011)
  • Author(s): 亀尾 肇、橋本康弘、中沢 浩
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学東山キャンパス
• [Presentation] Regioselective Synthesis of Vinyl Germanes Catalyzed by an Iron Complex (2011)
  • Author(s): 神谷昌宏、板崎真澄、中沢 浩
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学東山キャンパス
• [Presentation] Theoretical Study of Alkyl/Halogen Exchange Reaction on Pt Complexes with Phosphine Ligand (2011)
  • Author(s): 高島麻里、土田敦子、重里有香、板崎真澄、中沢 浩、鷹野景子
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学東山キャンパス
• [Presentation] ハロゲン化ホスフィンを担持する白金錯体のX/Me (X = Ci, Br) 交換反応に関する量子化学的研究 (2011)
  • Author(s): 土田敦子、高島麻里、重里有香、板崎真澄、中沢 浩、鷹野景子
  • Organizer: 錯体化学第61回討論会
  • Place of Presentation: 岡山理科大学
• [Presentation] Hydrosilylation of Terminal Olefins with Hydrosilanes Catalyzed by CpFe(CO)2(CH3) (2011)
  • Author(s): Roman Naumov and Hiroshi Nakazawa
  • Organizer: 錯体化学第61回討論会
  • Place of Presentation: 岡山理科大学
• [Presentation] ジアミノ置換ホスファイトあよびアシル基を配位子とするモリブデン錯体とルイス酸との反応 (2011)
  • Author(s): 福本晃造、二藤久美子、早坂和将、中沢 浩
  • Organizer: 錯体化学第61回討論会
  • Place of Presentation: 岡山理科大学
• [Presentation] モリブデン錯体触媒によるイソチオシアネートのC=S結合切断反応 (2011)
  • Author(s): 早坂和将、福本晃造、小谷研悟、中沢 浩
  • Organizer: 錯体化学第61回討論会
  • Place of Presentation: 岡山理科大学
• [Presentation] A New Method for the Synthesis of Silylcyanides by an Iron Complex (2011)
  • Author(s): Andrea Renzetti and Hiroshi Nakazawa
  • Organizer: 錯体化学第61回討論会
  • Place of Presentation: 岡山理科大学
• [Presentation] ４座配位子 [(E(o-C6H4PPh2)3]- (E = Si, Ge, Sn) を有するロジウム錯体の合成とEの電子供与能の評価 (2011)
  • Author(s): 石井 翔、亀尾 肇、中沢 浩
  • Organizer: 錯体化学第61回討論会
  • Place of Presentation: 岡山理科大学
• [Presentation] 1,1'-ビスシリルメタロセンを配位子とする白金ヒドリド二核錯体の合成と反応 (2011)
  • Author(s): 仲間幸俊、南方牧子、板崎真澄、中沢 浩
  • Organizer: 第15回ケイ素化学協会シンポジウム
  • Place of Presentation: シ―パル須磨
• [Presentation] 遷移金属錯体を用いたR-N=C=E (E = O, S) の選択的C=E結合切断反応 (2011)
  • Author(s): 早坂和将、福本晃造、中沢 浩
  • Organizer: 第38回有機典型元素化学討論会
  • Place of Presentation: 石川県立音楽堂
• [Presentation] 鉄錯体を用いたチオアミドの脱硫反応 (2011)
  • Author(s): 酒井 茜、福本晃造、中沢 浩
  • Organizer: 第38回有機典型元素化学討論会
  • Place of Presentation: 石川県立音楽堂
• [Book] 高校生・化学宣言PART5～高校化学グランドコンテストドキュメンタリー～ (2012)
  • Author(s): 中沢 浩、松坂裕之
  • Total Pages: 221
  • Publisher: 遊タイム出版
• [Book] Fe-H Complexes in Catalysis、Topics in Organometallic Chemistry Vol. 33 "Iron Catalysis: Fundamentals and Applications" (2011)
  • Author(s): H. Nakazawaand M. Itazaki, Ed. by B. Plietker
  • Publisher: Springer
• [Book] Strong Bond Cleavage Promoted by Silyl Group Migration in a Coordination Sphere、WIT Transaction on Ecology and the Environment, Vol. 154, "Sustainable Chemistry" (2011)
  • Author(s): H. Nakazawa、Ed. by G. Reniers and C. A. Brebbia
  • Publisher: WIT Press
• [Book] Topics in Organometallic Chemistry Vol. 33 (2011)
  • Author(s): H. Nakazawa and M. Itazaki
  • Total Pages: 55
  • Publisher: Springer
• [Book] WIT Transaction on Ecology and the Environment, Vol. 154 (2011)
  • Author(s): H. Nakazawa
  • Total Pages: 12
  • Publisher: WIT Press
• [Remarks]
  • URL: http://www.sci.osaka-cu.ac.jp/chem/cc/index.html
• [Remarks] Coordination Chemistry Lab
  • URL: http://www.sci.osaka-cu.ac.jp/chem/cc/index.html