Development of Chemical Reduction of Sugars
Project/Area Number |
23655057
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
|
Research Institution | Kinki University (2012) The Institute of Physical and Chemical Research (2011) |
Principal Investigator |
|
Project Period (FY) |
2011 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
Keywords | 糖 / 化学的還元 / ヒドロシラン / ルイス酸 / 二酸化炭素 / 還元 / 炭化水素 / アルコール / シロキサン |
Research Abstract |
We have examined the chemical reduction of glucose with hydrosilanes using B(C6F5)3 as a homogeneous catalyst. NMR tube reactions indicate the formation of dihydrogen and siloxane materials, together with a mixture of reduced carbon compounds. We have synthesized new cationic zirconium species supported by the bulky aryloxide ligands, which show excellent catalytic activities toward CO2 reduction using various hydrosilanes as reducing agents under mild conditions.
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Report
(3 results)
Research Products
(4 results)