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Magnetophoretic Detection of Electron Spin Resonance in a Single Micro-Particle

Research Project

Project/Area Number 23655066
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionOsaka University

Principal Investigator

SUWA Masayori  大阪大学, 理学研究科, 助教 (90403097)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords微粒子分析 / 磁気泳動 / 電子スピン共鳴 / 常磁性磁化率 / 微小作用力 / マイクロ微粒子 / 磁気泳動法 / 磁化率 / 常磁性イオン / ラジカル / マイクロ粒子 / 常磁性
Research Abstract

We have examined to detect electron spin resonance (ESR) in a micro-particle by using magnetophoresis, which is migration phenomenon under an inhomogeneous magnetic field. Magnetophoretic velocity of micro-droplets of manganese dichloride aqueous solution dispersed in an organic liquid was measured with irradiation of microwave, whose frequency was from 0.1 GHz to 20 GHz. As a result, slight decrease of magnetophoretic velocity only at the position where the magnetic field met the condition of ESR was observed. Therefore, it was suggested that ESR in micro-particle could be detected from the decrease of the magnetic susceptibility. However, the region where the velocity decreased was broader than that expected. More detailed discussion about the spatial distribution of microwave power should be discussed, and more effective method for irradiation is essential for clear observation of ESR by magnetophoresis.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (8 results)

All 2013 2012 2011

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (7 results)

  • [Journal Article] Magnetoanalysis of micro/nanoparticles: A review2011

    • Author(s)
      Masayori Suwa, Hitoshi Watarai
    • Journal Title

      Analytica Chimica Acta

      Volume: 690 Issue: 2 Pages: 137-147

    • DOI

      10.1016/j.aca.2011.02.019

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] 磁気泳動法によるマイクロ液滴中常磁性イオンの電子スピン共鳴観測の検討2013

    • Author(s)
      諏訪雅頼、渡部隼平、塚原 聡、渡會 仁
    • Organizer
      日本分析化学会第61 年会
    • Place of Presentation
      金沢大学
    • Year and Date
      2013-09-21
    • Related Report
      2012 Final Research Report
  • [Presentation] 磁気泳動法によるマイクロ液滴中常磁性イオンの電子スピン共鳴観測の検討2012

    • Author(s)
      諏訪雅頼、渡部隼平、塚原 聡、渡會 仁
    • Organizer
      日本分析化学会 第61年会
    • Place of Presentation
      金沢大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Magnetic Characterization of Micro-Particles by Magnetophoretic Velocimetry2011

    • Author(s)
      Masayori Suwa, Hitoshi Watarai
    • Organizer
      International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center
    • Related Report
      2011 Research-status Report
  • [Presentation] Simultaneous Acquisition of the Faraday Rotation and the Natural Optical Rotation Images under Pulsed Magnetic Field2011

    • Author(s)
      Masayori Suwa, Kayoko Miyamoto, Yusuke Nakano, Hitoshi Watarai
    • Organizer
      International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center
    • Related Report
      2011 Research-status Report
  • [Presentation] ファラデー回転イメージング法による弱磁性マイクロ粒子のキャラクタリゼーション2011

    • Author(s)
      諏訪雅頼、塚原聡、渡會仁
    • Organizer
      日本分析化学会 第60年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2011 Research-status Report
  • [Presentation] パルス磁場を利用したファラデー回転観測とイメージングへの展開2011

    • Author(s)
      諏訪雅頼、仲野祐輔、宮本佳代子、以西健人、渡會仁
    • Organizer
      日本磁気科学会 無機金属分科会 研究会(招待講演)
    • Place of Presentation
      東京大学
    • Related Report
      2011 Research-status Report
  • [Presentation] 弱磁性マイクロ粒子のファラデー回転イメージ観測2011

    • Author(s)
      諏訪雅頼、塚原聡、渡會仁
    • Organizer
      日本磁気科学会 第6回年次大会
    • Place of Presentation
      東京大学
    • Related Report
      2011 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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